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http://dx.doi.org/10.4191/KCERS.2006.43.7.389

Electric Field-Induced Phase Transition Behavior in Tetragonal Pb(Zn1/3Nb2/3)O3-PbTiO3 Single Crystals  

Jeong, Dae-Yong (Thin Film Materials Research Center, Korea Institute of Science and Technology)
Kim, Jin-Sang (Thin Film Materials Research Center, Korea Institute of Science and Technology)
Kim, Hyun-Jai (Thin Film Materials Research Center, Korea Institute of Science and Technology)
Yoon, Seok-Jin (Thin Film Materials Research Center, Korea Institute of Science and Technology)
Publication Information
Journal of the Korean Ceramic Society / v.43, no.7, 2006 , pp. 389-392 More about this Journal
Abstract
Electric field-induced phase transition from the tetragonal to rhombohedral phase was investigated for the <111> direction in tetragonal PZN-PT single crystals, which have spontaneous polarization along the <001> direction. From the strain and dielectric data, it was confirmed that the samples followed a tetragonal-orthorhombic-rhombohedral phase transition sequence with application of an electric field. This transition is different from the rhombohedral-tetragonal phase transition of <001> rhombohedral composition single crystals, in which a phase transition occurred without showing the intermediate orthorhombic phase.
Keywords
Phase transition; Tetragonal; Ferroelectric; Single crystal;
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1 S.-F. Liu, S.-E. Park, T. R. Shrout, and L. E. Cross, 'Electric Field Dependence of Piezoelectric Properties for Rhombohedral $0.955Pb(Zn_{1/3}Nb_{2/3})O_3-0.045PbTiO_3$ Single Crystals,' J. Appl. Phys., 85 2810-14 (1999)   DOI   ScienceOn
2 B. Noheda, 'Structure and High-Piezoelectricity in Lead Oxide Solid Solutions,' Curr. Opin. Solid State Mater. Sci., 6 27-34 (2002)   DOI   ScienceOn
3 B. Noheda, D. E. Cox, G. Shirane, J. Gonzalo, L. Cross, and S. Park, 'A Monoclinic Ferroelectric Phase in the $Pb(Zr_{1-x} Ti_x)O_3$ Solid Solution,' Appl. Phys. Lett., 74 2059-61 (1999)   DOI   ScienceOn
4 R. Guo, L. Cross, S. Park, B. Noheda, D. Cox, and G. Shirane, 'Origin of the High Piezoelectric Response in $PbZr_{1-x}Ti_xO_3$,' Phys. Rev. Lett., 84 5423-26 (2000)   DOI   ScienceOn
5 S. J. Zhang, L. Lebrun, S. Liu, S. Rhee, C. A. Randall, and T. R. Shrout, 'Piezoelectric Shear Coefficients of $Pb(Zn_{1/3} Nb_{2/3})O_3-PbTiO_3$ Single Crystals,' Jpn. J. Appl. Phys., 41 L1099-102 (2002)   DOI
6 H. Fu and R. Cohen, 'Polarization Rotation Mechanism for Ultrahigh Electromechanical Response in Single-Crystal Piezoelectrics,' Nature(London), 403 281-83 (2000)   DOI   ScienceOn
7 M. L. Mulvihill, S. E. Park, G. Risch, Z. Li, K. Uchino, and T. R. Shrout, 'The Role of Processing Variables in the Flux Growth of Lead Zinc Niobate-Lead Titanate Relaxor Ferroelectric Single Crystals,' Jpn. J. Appl. Phys., 35 3984-90 (1996)   DOI
8 B. Jaffe, W. Cook, Jr., and H. Jaffe, 'Piezoelectric Ceramics,' Academic Press, New York, 1971
9 J. Kuwata, K. Uchino, and S. Nomura, 'Phase Transitions in the $Pb(Zn_{1/3}Nb_{2/3})O_3-PbTiO_3$ System,' Ferroelectrics, 37 579-82 (1981)   DOI   ScienceOn
10 S.-E. Park and T. Shrout, 'Ultrahigh Strain and Piezoelec-tric Behavior in Relaxor Based Ferroelectric Single Crystals,' J. Appl. Phys., 82 1804-11 (1997)   DOI   ScienceOn
11 L. Yu, D.-Y. Jeong, Z.-Y. Cheng, T. Shrout, and Q. M. Zhang, 'Phase Stabilities of 'Morphotropic' Phases in $Pb(Zn_{1/3}Nb_{2/3})O_3-PbTiO_3$ Single Crystals,' Appl. Phys. Lett., 80 1918-20 (2002)   DOI   ScienceOn
12 Y. Lu, Z.-Y. Cheng, S.-E. Park, S.-F. Liu, and Q. M. Zhang, 'Linear Electro-Optic Effect of $0.88Pb(Zn_{1/3}Nb_{2/3})O_3-0.12 PbTiO_3$ Single Crystal,' Jpn. J. Appl. Phys., 39 141-44 (2000)   DOI
13 Y. Barad, Y. Lu, Z.-Y. Cheng, S.-E. Park, and Q. M. Zhang, 'Composition, Temperature, and Crystal Orientation Dependence of the Linear Electro-Optic Properties of $Pb(Zn_{1/3}Nb_{2/3})O_3-PbTiO_3$ Single Crystals,' Appl. Phys. Lett., 77 1247-49 (2000)   DOI   ScienceOn
14 D.-Y. Jeong, Y. Lu, V. Sharma, Q. Zhang, and H.-S. Luo, 'Linear Electrooptic Properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ Single Crystals at Compositions Near the Morphotropic Phase Boundary,' Jpn. J. Appl. Phys., 42 4387-88 (2003)   DOI
15 Q. M. Zhang, S. J. Jang, and L. E. Cross, 'High-Frequency Strain Response in Ferroelectrics and Its Measurement Using a Modified Mach-Zehnder Interferometer,' J. Appl. Phys., 65 2807-13 (1989)   DOI
16 D.-Y. Jeong, S. J. Zhang, and H. B. Hwang, 'Dependence of Domain Stability on the Thickness of the Tetragonal $0.88Pb(Zn_{1/3}Nb_{2/3})O_3-0.12PbTiO_3$ Single Crystal,' J. Kor. Phys. Soc., 44 1531-33 (2004)
17 S. Wada, S. Suzuki, T. Noma, T. Suzuki, M. Osada, M. Kakihana, S.-E. Park, L. E. Cross, and T. R. Shrout, 'Enhanced Piezoelectric Property of Barium Titanate Single Crystals with Engineered Domain Configurations,' Jpn. J. Appl. Phys., 38 5505-11 (1999)   DOI
18 B. Noheda, D. E. Cox, G. Shirane, S.-E. Park, L. E. Cross, and Z. Zhong, 'Polarization Rotation via a Monoclinic Phase in the Piezoelectric 92% $PbZn_{1/3}Nb_{2/3}O_3$-8% $PbTiO_3$,' Phys. Rev. Lett., 86 3891-94 (2001)   DOI   ScienceOn
19 Y. Lu, D.-Y. Jeong, Z.-Y. Cheng, Q. M. Zhang, H. Luo, Z. Yin, and D. Viehland, 'Phase Transitional Behavior and Piezoelectric Properties of the Orthorhombic Phase of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ Single Crystals,' Appl. Phys. Lett., 78 3109-11 (2001)   DOI   ScienceOn