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http://dx.doi.org/10.4191/KCERS.2006.43.3.162

Electrical Properties of the Lanthanum Ferrite-Based Cathode Materials for Low-Temperature SOFCs  

Kang, Ju-Hyun (Department of Materials Science and Engineering, University of Seoul)
Choi, Jung-Woon (Department of Materials Science and Engineering, University of Seoul)
Shim, Han-Byel (Department of Materials Science and Engineering, University of Seoul)
Yoo, Kwang-Soo (Department of Materials Science and Engineering, University of Seoul)
Publication Information
Abstract
The perovskites with nominal compositions $La_{0.8}Sr_{0.2}Fe_{1-x}M_xO_3$ (M=Co, Mn, Ni, x=0.1-0.3) were fabricated by a solid-state reaction method as cathode materials of low-temperature operating Solid Oxide Fuel Cells (SOFCs). X-ray diffraction analysis and microstructure observation for the sintered samples were performed. The ac complex impedance were measured in the temperature range $600-900^{\circ}C$ in air and fitted with a Solatron ZView program. The electrical conductivity and polarization resistance of $La_{0.8}Sr_{0.2}Fe_{1-x}M_xO_3$ (M=Co, Mn, Ni, x=0.1-0.3) were characterized systematically. The porosities of the sintered samples were in the range of 25% to 38%. The polarization resistance of $La_{0.8}Sr_{0.2}Fe_{0.7}M_{0.3}O_3$ was $0.291{\Omega}cm^2\;at\;700^{\circ}C$.
Keywords
SOFC; Perovskite; LSF; Polarization resistance; Impedance;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 M. D. Anderson, J. W. Stevenson, and S. P. Simner, 'Reactivity of Lanthanide Ferrite SOFC Cathodes with YSZ Electrolyte,' J. Power Sources, 129 188-92 (2004)   DOI   ScienceOn
2 J. M. Ralph, C. Rossignol, and R. Kumar, 'Cathode Mate- rials for Reduced-Temperature SOFCs,' J. Electrochem. Soc., 150 1518-22 (2003)   DOI   ScienceOn
3 K. S. Yoo, 'R&D Trend of Thin-Film SOFCs,' Ceramist, 3 [5] 29-33 (2000)
4 J. Will, A. Mitterdorfer, C. Kleinloged, D. Perednis, and L. J. Gauckler, 'Fabrication of Thin Electrolyte for Secondgeneration Solid Oxide Fuel Cells,' Solid State Ionics, 131 79-96 (2002)   DOI   ScienceOn
5 J. D. Kim, G. D. Kim, J. W. Moon, Y. I. Park, W. H. Lee, K. Kobayashi, M. Nagai, and C. E. Kim, 'Characterization of LSM-YSZ Composite Electrode by AC Impedance Spectroscopy,' Solid State Ionics, 143 379-89 (2001)   DOI   ScienceOn
6 B. C. H. Steels, 'Survey of Materials Selection for Ceramic Fuel Cells; II. Cathodes and Anodes,' Solid State Ionics, 86- 88 1233-34 (1996)
7 J. Fleig, 'On the Width of the Electrochemically Active Region in Mixed Conducting Solid Oxide Fuel Cell Cathodes,' J. Power Sources, 105 228-38 (2002)   DOI   ScienceOn
8 G. Hsieh, T. O. Mason, E. J. Garboczi, and L. R. Pederson, 'Experimental Limitations in Impedance Spectroscopy : Part 3-Effect of Reference Electrode Geometry/Position,' Solid State Ionics, 96 153-72 (1997)   DOI   ScienceOn
9 J. M. Ralph, A. C. Schoeler, and M. Krimplet, 'Materials for Lower Temperature Solid Oxide Fuel Cells,' J. Mater. Sci., 36 1161-72 (2001)   DOI   ScienceOn
10 A. Esquirol, N. P. Brandon, J. A. Kilner, and M. Mogensen, 'Electrochemical Characterization of $La_{0.6}Sr_{0.2}Co_{0.2}Fe_{0.8}O_3$ Cathodes for Intermediate-Temperature SOFCs,' J. Electrochemical Soc., 151 A1847-55 (2004)   DOI   ScienceOn
11 F. Zhao and A. V. Virker, 'Dependence of Polarization in Anode-Supported Solid Oxide Fuel Cells on various Cell Parameters,' J. Power Sources, 141 79-95 (2005)   DOI   ScienceOn
12 J. C. Yun, W. S. Kim, H. C. Kim, J. H. Lee, J. S. Kim, H. W. Lee, and B. H. Kim, 'Effect of Cathode Porosity of Mixed Conducting $La_{0.6}Sr_{0.2}Co_{0.2}Fe_{0.8}O_3$ on the Power Generating Characteristics of Anode Supported SOFCs(in Korean),' J. Kor. Ceram. Soc., 42 [4] 269-75 (2005)   과학기술학회마을   DOI   ScienceOn