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http://dx.doi.org/10.4191/KCERS.2006.43.1.033

Dissolution Phenomenon in BaO-B2O3-ZnO Glass System by Acid Etching  

Kim, Jae-Myung (School of Materials Engineering, Inha University)
Hong, Kyung-Jun (R&D Center, Phoenix PDE)
Kim, Nam-Suk (School of Materials Engineering, Inha University)
Kim, Hyung-Sun (School of Materials Engineering, Inha University)
Publication Information
Journal of the Korean Ceramic Society / v.43, no.1, 2006 , pp. 33-37 More about this Journal
Abstract
For producing the fine ribs structure of plasma display panel, the metal ions of barrier materials during the etching process should be understood on the etching mechanism with etching conditions. Etching was done on bulk glasses of the $BaO_B_2O_3-ZnO$ system with $HNO_3$ solution at $40^{\circ}C$. The surface structure of glasses and ion dissolution were analyzed by ICP (Inductive Coupled Plasma measurement). The structure and surface of the etched bulk glass were investigated by using scanning electron microscopy and nanoindenter. As a result, Ba (3-35 ppm/min) and Zn (2-27 ppm/min) ions as major components were leached in the solution and the leached layers were found to be phosphor-rich surface layers. A decrease of the bridge oxygen and relative increase of non bridge oxygen in the etched glass were found by X-ray photoelectron spectroscopy.
Keywords
Etching glass; Dissolution; Glass; Metal ion; Leaching;
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Times Cited By KSCI : 2  (Citation Analysis)
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