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http://dx.doi.org/10.4191/KCERS.2005.42.9.624

The Effect of the Heat Treatment of the ZrO2 Buffer Layer and SBT Thin Film on Interfacial Conditions and Ferroelectric Properties of the SrBi2Ta2O9/ZrO2/Si Structure  

Oh, Young-Hun (School of Materials Science and Engineering, Busan National University)
Park, Chul-Ho (School of Materials Science and Engineering, Busan National University)
Son, Young-Guk (School of Materials Science and Engineering, Busan National University)
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Abstract
To investigate the possibility of the $ZrO_2$ buffer layer as the insulator for the Metal-Ferroelectric-Insulator-semiconductor (MFIS) structure, $ZrO_2$ and $SrBi_2Ta_2O_9$ (SBT) thin films were deposited on the P-type Si(111) wafer by the R.F. magnetron-sputtering method. According to the process with and without the post-annealing of the $ZrO_2$ buffer layer and SBT thin film, the diffusion amount of Sr, Bi, Ta elements show slight difference through the Glow Discharge Spectrometer (GDS) analysis. From X-ray Photoelectron Spectroscopy (XPS) results, we could confirm that the post-annealing process affects the chemical binding condition of the interface between the $ZrO_2$ thin film and the Si substrate. Compared to the MFIS structure without the post-annealing of the $ZrO_2$ buffer layer, memory window value of MFlS structure with post-annealing of the $ZrO_2$ buffer layer were considerably improved. The window memory of the Pt/SBT (260 nm, $800^{\circ}C)/ZrO_2$ (20 nm) structure increases from 0.75 to 2.2 V under the applied voltage of 9 V after post-annealing.
Keywords
buffer layer; thin film; MFIS structure ferroelectric random access memory;
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1 G. P. Choi, J. H. Ann, W. J. Lee, T. H. Sung, and H. G Kim, 'Phase Formations and Electrical Properties of doped-PZT/ $PbTiO_3$ Films Deposited by Reactive Sputtering Using Multi-Targets,' Muter: Sci. and Eng. B, 41 [1] 16-22 (1996)   DOI   ScienceOn
2 P. Tejedor, C. Ocal, E. Barrena, R. Jimenez, C. Alemany, and J. Mendiola, 'Composition-Related Effects of Microstructure on the Ferroelectric Behavior of SBT Thin Films,' Appl. Surf. Sci., 175/176 759-63 (2001)   DOI   ScienceOn
3 T. Hirai, K. Teramoto, T. Goto, and Y. Tarui, 'Formation of Metal/Ferroelectric!InsulatorlSemiconductor Structure with a $CeO_2$ Buffer Layer,' Jpn. J. Appl. Phys., 33 Part 1 [9b] 5219-22 (1994)   DOI
4 J. H. Kim, S. G Kang, and H. T. Eun, 'Effects of $Y_2O_3$ Buffer Layer on Ferroelectric Properties of $YMnO_3$ Thin Films Fabricated on $Pt/TiO_2/SiO_2/Si$ Substrate(in Korean),' J. Kor. Ceram. Soc., 37 [11] 1097-104 (2000)
5 D. R. Lampe, D. A. Adams, M. Austin, M. polinsky, J. Dzimianski, S. Sinharoy, H. Buhay, P. Brabant, and Y. M. Liu, 'Process Integration of the Ferroelectric Memory FETs for NDRO FERAM,' Ferroelectrics, 133 61-72 (1992)   DOI
6 B. Cheng, M. Cao, R. Rao, A. Inani, P. V. Voorde, W. M. Green, J. M. C. Stork, Z. Yu, P. M. Zeizoff, and J. C. S. Woo, 'The Impact of High-K Gate Dielectrics and Metal Gate Electrodes on Sub-100 nm MOSFETs,' IEEE Trans. Electron Devises, 46 [7] 1537-42 (1999)   DOI   ScienceOn
7 A. Mehner, H. Klumper-Westkamp, F. Hoffmann, and P. Mayr, 'Crystallization and Residual Stress Formation of Sol-Gel-Derived Zirconia Films,' Thin Solid Film, 308/309 363-68 (1997)   DOI   ScienceOn
8 K. Goedicke, J.-S. Liebig, O. Zywitzki, and H. Sahm, 'Influence of Process Parameters on the Structure and the Properties of $ZrO_2$ Coatings Deposited by Reactive Pulsed Magnetron Sputtering(PMS),' Thin Solid Film, 377/378 37-42 (2000)   DOI   ScienceOn
9 J. S. Kim, H. A. Marzouk, and P. J. Reucroft, 'Deposition and Structural Characterization of $ZrO_2$ and Yttria-Stabilized $ZrO_2$ Films by Chemical Vapor Deposition,' Thin Solid Film, 254 33-8 (1995)   DOI   ScienceOn
10 Y. G. Son, 'Electrical Properties of $Ba_{0.5}Sr_{0.5}TiO_3$ Thin Film with Various Heat Treatment Conditions(in Korean),' J. Kor. Ceram. Soc., 38 [5] 492-98 (2001)