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http://dx.doi.org/10.4191/KCERS.2002.39.9.884

Preparation of Nanocrystalline ZrO2 Film by Using a Zirconium Naphthenate and Evaluation of Calcium Phosphate Forming Ability  

Oh, Jeong-Sun (Department of Chemistry, College of Natural Science, Chosun University)
Ahn, Jun-Hyung (School of Automotive and Mechanical Engineering and Institute of Manufacturing and Automation System, Nambu University)
Yun, Yeon-Hum (School of Automotive and Mechanical Engineering and Institute of Manufacturing and Automation System, Nambu University)
Kang, Bo-An (School of Automotive and Mechanical Engineering and Institute of Manufacturing and Automation System, Nambu University)
Kim, Sang-Bok (School of Automotive and Mechanical Engineering and Institute of Manufacturing and Automation System, Nambu University)
Hwang, Kyu-Seog (School of Automotive and Mechanical Engineering and Institute of Manufacturing and Automation System, Nambu University)
Shim, Yeon-A (Department of Ceramic Engineering, Chonnam National University)
Publication Information
Journal of the Korean Ceramic Society / v.39, no.9, 2002 , pp. 884-889 More about this Journal
Abstract
In order to investigate the calcium phosphate forming ability of nanocrystalline $ZrO_2$ film, we prepared $ZrO_2/Si$ structure by using a chemical solution deposition with a zirconium naphthenate as a starting material. Precursor sol was spin-coated onto the (100)Si substrate and prefired at 500$^{\circ}C$ for 10 min in air, followed by final annealing at 800$^{\circ}C$ for 30 min in air. Crystallinity of the annealed film was examined by X-ray diffraction analysis. Surface morphology and surface roughness of the film were characterized by field emission-scanning electron microscope and atomic force microscope. After annealing, nanocrystalline $ZrO_2$ grains were obtained on the surface of the film with a homogeneous interface between the film and substrate. After immersion for 1 or 5 days in a simulated body fluid, formation of calcium phosphate was observed on $ZrO_2$ film annealed at 800$^{\circ}C$ by energy dispersive X-ray spectrometer. The fourier transform infrared spectroscopy revealed that carbonate was substituted into the calcium phosphate.
Keywords
Nanocrystalline $ZrO_2 film$; Zirconium naphthenate; Calcium phosphate;
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Times Cited By KSCI : 4  (Citation Analysis)
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