Browse > Article
http://dx.doi.org/10.4191/KCERS.2002.39.4.394

Fabrication and Characterization of Sn1-xSixO2 Anode for Lithium Secondary Battery by R.F. Magnetron Sputtering Method  

Lee, Sang-Heon (School of materials Science & Engineering, Pusan national University)
Park, Keun-Tae (School of materials Science & Engineering, Pusan national University)
Son, Young-Guk (School of materials Science & Engineering, Pusan national University)
Publication Information
Abstract
Tin oxide thin films doped with silicon as anodes for lithium secondary battery were fabricated by R. F. magnetron sputtering technique. The electrochemical results for lithium secondary battery anodes showed that addition of silicon decreases the oxidic state of tin, and, hence, reduced the irreversible capacity during the first discharge/charge cycle. The (110),(101),(211) planes were grown with increasing substrate temperatures. The reversible capacity of thin films fabricated in conditions of $300^{\circ}C$ substrate temperature and 7:3 $Ar:O_2$ ratio was 700 mAh/g.
Keywords
Sn$_{1-x}Si_xO_2$; R.F. magnetron sputtering; Lithium secondary battery;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 H. Huang, E. M. Kelder, L. Chen and J. Schoonman, 'Ele-crochemical Characterization of $Sn_{1-x}Si_xO_2$ as Anode for Lithium-ion Batteries,' J. Power Sources, 81-82 362-67 (1999)
2 Y. G. Son, 'Electrical Properties of $Ba_{0.5}Sr_{0.5}TiO_3$ Thin Film with Various Heat Treatment Conditions(in Kor.),' J. Kor. Ceram. Soc., 38 [5] 492-98 (2001)
3 S. H. Jeong, 'A Study on Electrochemical Characteristics of Li Secondary Microbattery of Sn Alloy,' Yonsei University (2001)
4 H. C. Son, 'Anode Characterisdcs of Tin Oxide Tin Film for Lithium Secondary Microbattery,' Hanyang University (1998)
5 Y. Nishi, 'Lithium lon Secondary Batteries; Past 10 Years and the Future,' J. Power Soures, 100 101-06 (2001)   DOI   ScienceOn
6 T. U. Woo and Y. G. Son, 'Fabrication and Characterization of Li$Mn_2O_4$ Cathode for Litium Rechargeable Battery by R.P. Magnetron Sputtering(in Kor.),' J. Kor. Ceram. Soc., 37 [6] 552-58 (2001)
7 I. A. Courtney and J. R. Dahn, 'Key Factors Controlling the Reversibility of the Reaction of Lithium with $SnO_2BPO_6$ and $SnO_2$ Glass,' J. EIectrochem. Soc., 144 2045 (1997)   DOI   ScienceOn
8 J. S. Kim, W. Y Yoon and K. S. Yoo, 'Enhancement of Cell Performance for an Carbon Anode in Li-ion Battery(in Kor),' J. Kor. Ceram. Soc., 38 [8] 755-60 (2001)
9 Y. Idota, T. Kubota, A. Matusufuji, Y. Maekawa and T. Miyasaka, 'TIn-based Amorphous Oxide: A High-capacity Lithium lon-storage Materials,' Science, 276 [30] 1395-97 (1997)   DOI   ScienceOn
10 R. A. Huggins, 'Lithium Alloy Negadve Electrodes Formedfrom Convertible Oxides,' Solid State Ionics, 113-15, 57-67, (1998)