Browse > Article
http://dx.doi.org/10.9721/KJFST.2011.43.1.006

A Study on Residual Amounts of Vinyl Chloride/Vinylidene Chloride in Poly(vinyl chloride)/Poly(vinylidene chloride) Food Packaging using Headspace GC/MS  

Sung, Jun-Hyun (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Kwak, In-Shin (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Park, Sung-Kwan (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Kim, Hyung-Il (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Lim, Ho-Soo (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Lee, Ju-Young (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Byun, Mi-Yun (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Kim, So-Hee (Food Additives and Packages Division, National Institute of Food and Drug Safety Evaluation)
Publication Information
Korean Journal of Food Science and Technology / v.43, no.1, 2011 , pp. 6-11 More about this Journal
Abstract
Vinyl chloride (VC) and vinylidene chloride (VDC), which may be present in poly(vinyl chloride) (PVC) and poly(vinylidene chloride) (PVDC) food packaging, were analyzed by using a headspace-gas chromatograph (GC)/mass spectrometer (MS) equipped with a PLOT Q column. 1-Chloropropane (1-CP) was used as an internal standard. The determinations of VC and VDC were carried out by monitoring the characteristic ions for each compound: m/z=61, 62, 64 and m/z=61, 96, 98, respectively. The method validated in this study can be suitable for the compliance test of EU regulation. Among 103 food packaging samples, VC and VDC were not detected, except in one PVDC food package. However, the detected level of VDC in the sample was below the EU regulatory specific limitation.
Keywords
vinyl chloride; vinylidene chloride; food packaging;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Fujiwara H, Izutsu K. Mechanochemical block copolymerization in heterogeneous systems of poly(vinyl chloride) with vinyl acetate by ultrasonic irradiation. Memoirs of the Osaka Institute of Technology. Series A. 49(1): 1-9 (2004)
2 U.S. EPA. Toxicological review of 1,1-dichloroethylene. In support of summary information on the integrated risk information system (IRIS) EPA/635/R02/002: 37-38 (2002), available online at http://www.epa.gov/iris/toxreviews/0039tr.pdf. Accessed Aug. 19, 2010.
3 European Union (EU). Council Directive 78/142/EEC on the approximation of the laws of the member states relating to materials and articles which contain vinyl chloride monomer and are intended to come into contact with foodstuffs. Off. J. Eur. Commun. L44: p.15 (1978)
4 World Health Organization (WHO). 1,1-Dichloroethene (vinylidene chloride). Concise International Chemical Assessment Document 51: 6-7 (2003)
5 EU. Commission Directive 80/766/EEC, the Community method of analysis for the official control of the vinyl chloride monomer level in materials and articles which are intended to come into contact with foodstuffs. (1980) avaliable online at http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=CELEX:31980L0766:EN:NOT. Accessed Aug. 19, 2010.
6 EU. Commission Directive 81/432/EEC, the Community method of analysis for the official control of vinyl chloride released by materials and articles into foodstuffs. (1981) available online at http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=CELEX:31981L0432:en:NOT. Accessed Aug. 19, 2010.
7 U.S. EPA. IRIS. Vinyl chloride. (2000), available online at http://www.epa.gov/iris/subst/1001.htm. Accessed Aug. 19, 2010.
8 International Agency for Research on Cancer (IARC). IARC Monographs on the evaluation of carcinogenic risks to humans:overall evaluations of carcinogenicity: An updating of IARC Monographs Volumes 1 to 42, Supplement 7: 372-375 (1987), available online at http://monographs.iarc.fr/ENG/Monographs/suppl7/Suppl7.pdf. Accessed Aug. 19, 2010.
9 Ministry of Health and Welfare, Japan. Specification, standards and testing methods for foodstuffs, implements, containers and packaging, toys, detergents. Ministry of Health and Welfare Notice No. 499, Japan (2005)
10 Korea Food & Drug Administration (KFDA). Standards and specifications for utensil, containers.packaging. KFDA Notice No. 2010-96 (2010)
11 U.S. Department of health and human services. toxicological profile for vinyl chloride. Agency for toxic substances and disease registry (ATSDR): 2-4 (2006), available online at http://www.atsdr.cdc.gov/toxprofiles/tp20.pdf. Accessed Aug. 19, 2010.
12 U.S. Environmetnal Protection Agency (EPA). Toxicological review of vinyl chloride. In support of summary information on the integrated risk information system (IRIS). EPA/635R-00/004: 2-3 (2002), available online at http://www.epa.gov/ncea/iris/toxreviews/1001tr.pdf. Accessed Aug. 19, 2010.
13 Shimanouchi T. 'Tables of molecular vibrational frequencies', Natl. Stand. Ref. Data Ser., National Bureau of Standards, Garthersburg. Vol. I (1972), available online at http://www.ecosci.jp/mva/vib_p01.html. Accessed Aug. 19, 2010.
14 Dow Plastics. Vinylidene chloride monomer and polymers, Technical report on VDC and PVDC, reprinted from K. Othmer: Encyclopedia of Chemical Technology. 4th Ed. Vol. 24, New York, John Wiley & Sons, Inc., pp. 882-923, (1997), available online at http://www.dow.com/PublishedLiterature/dh_005d/0901b8038005d707.pdf?filepath=plastics_la/pdfs/noreg/190-00347.pdf&fromPage=GetDoc. Accessed Aug. 19, 2010.
15 IARC. IARC Monographs on the evaluation of carcinogenic risks to humans: Overall evaluations of carcinogenicity: An updating of IARC Monographs Volumes 1 to 42, Supplement 7: 376-377 (1987), available online at http://monographs.iarc.fr/ENG/Monographs/suppl7/Suppl7.pdf. Accessed Aug. 19, 2010.