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http://dx.doi.org/10.12772/TSE.2015.52.126

Fabrication of Rewritable Pattern Images with Ultraviolet-responsive Polycaprolactone Electrospun Fibers  

Ali, Shamshad (Department of Organic and Nano Engineering, Hanyang University)
Ahmed, Farooq (Department of Textile Engineering, Mehran University of Engineering and Technology)
Khatri, Zeeshan (Department of Textile Engineering, Mehran University of Engineering and Technology)
Kim, Seong Hun (Department of Organic and Nano Engineering, Hanyang University)
Publication Information
Textile Science and Engineering / v.52, no.2, 2015 , pp. 126-131 More about this Journal
Abstract
For the first time, the photochromic spiropyran dye [1'-3'-dihydro-1',3',3'-trimethyl-6-nitrospiro [2H-1-benzopyran-2,2'-(2H)-indole] (indole) was successfully embedded as a guest molecule into the poly(${\varepsilon}$-caprolactone) (PCL) host polymer matrix via the electrospinning technique. The resulting PCL/Indole electrospun fibers exhibit photo-switchable properties without losing depth of color upon alternate irradiation with ultraviolet (UV) and visible light. We found that patterned color images could be recorded on the photochromic PCL/Indole electrospun fiber mats using photo-masked UV irradiation. Subsequent irradiation of the mat with visible light completely erased the recorded patterned color image. The transformation of indole from the colorless form to the colored form upon UV irradiation was confirmed by UV-visible spectrophotometry, fluorescence micrography, and water contact angle measurements. Field emissionscanning electron microscopy images revealed the smooth morphology of the PCL/Indole electrospun fibers. Additionally, the average diameter of the PCL/Indole electrospun fibers was significantly lower than that of the PCL electrospun fibers. Good to excellent ratings were achieved for the washing fastness of the PCL/Indole electrospun fiber mats.
Keywords
photochromic; spiropyran; poly(${\varepsilon}$-caprolactone); electrospinning; electrospun fibers;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 M. Aldib and R. M. Christie, "Textile Applications of Photochromic Dyes. Part 5: Application of Commercial Photochromic Dyes to Polyester Fabric by a Solvent-based Dyeing Method", Color Technol., 2013, 129, 131-143.   DOI
2 A. F. Little and R. M. Christie, "Textile Applications of Photochromic Dyes. Part 1: Establishment of a Methodology for Evaluation of Photochromic Textiles Using Traditional Colour Measurement Instrumentation", Color Technol., 2010, 126, 157-163.   DOI
3 Y.-S. Nam, I. Yoo, O. Yarimaga, I. S. Park, D.-H. Park, S. Song, J.-M. Kim, and C. W. Lee, "Photochromic Spiropyran-embedded PDMS for Highly Sensitive and Tunable Optochemical Gas Sensing", Chem. Commun., 2014, 50, 4251-4254.   DOI
4 A. F. Little and R. M. Christie, "Textile Applications of Photochromic Dyes. Part 3: Factors Affecting the Technical Performance of Textiles Screen-printed with Commercial Photochromic Dyes", Color Technol., 2011, 127, 275-281.   DOI
5 A. F. Little and R. M. Christie, "Textile Applications of Photochromic Dyes. Part 2: Factors Affecting the Photocoloration of Textiles Screen‐printed with Commercial Photochromic Dyes", Color Technol., 2010, 126, 164-170.   DOI
6 J. Lee, C.-W. Lee, and J.-M. Kim, "Fabrication of Patterned Images in Photochromic Organic Microfibers", Macromol. Rapid Comm., 2010, 31, 1010-1014.   DOI   ScienceOn
7 L. Shuiping, T. Lianjiang, H. Weili, L. Xiaoqiang, and C. Yanmo, "Cellulose Acetate Nanofibers with Photochromic Property: Fabrication And Characterization", Mater Lett., 2010, 64, 2427-2430.   DOI   ScienceOn
8 W. Hu, S. Liu, S. Chen, and H. Wang, "Preparation and Properties of Photochromic Bacterial Cellulose Nanofibrous Membranes", Cellulose, 2011, 18, 655-661.   DOI
9 F. B. De Sousa, J. D. Guerreiro, M. Ma, D. G. Anderson, C. L. Drum, R. D. Sinisterra, and R. Langer, "Photo-response Behavior of Electrospun Nanofibers Based on Spiropyrancyclodextrin Modified Polymer", J. Mater. Chem., 2010, 20, 9910-9917.   DOI
10 F. Di Benedetto, E. Mele, A. Camposeo, A. Athanassiou, R. Cingolani, and D. Pisignano, "Photoswitchable Organic Nanofibers", Adv. Mater., 2008, 20, 314-318.   DOI
11 M. Wang, S. A. Vail, A. E. Keirstead, M. Marquez, D. Gust, and A. A. Garcia, "Preparation of Photochromic Poly(vinylidene fluoride-co-hexafluoropropylene) Fibers by Electrospinning", Polymer, 2009, 50, 3974-3980.   DOI
12 L. Liu, Y. Zhang, G. Wang, M. Zhang, and H. Guan, "High Stability of Photoinduced Merocyanine in Naphthopyrandoped Polyvinylpyrrolidone Electrospun Nanofibers", Polym. Int., 2014, 63, 1991-1996.   DOI
13 Z. Khatri, S. Ali, I. Khatri, G. Mayakrishnan, S. H. Kim, and I.- S. Kim, "UV-responsive Polyvinyl Alcohol Nanofibers Prepared by Electrospinning", Appl. Surf. Sci., 2015, 342, 64-68.   DOI
14 F. C. Braganca and D. S. Rosa, "Thermal, Mechanical and Morphological Analysis of Poly($\varepsilon$-caprolactone), Cellulose Acetate and Their Blends", Polym. Adv. Technol., 2003, 14, 669-675.   DOI   ScienceOn
15 S. J. Choi, Y. K. Ha, and H. S. Kim, "Study on High-speed Camera Observation of Electrospinning Behaviors", Text. Sci. Eng., 2014, 51, 314-318.   DOI
16 J. Han, C. J. Branford-White, and L.-M. Zhu, "Preparation of Poly($\varepsilon$-caprolactone)/poly(trimethylene carbonate) Blend Nanofibers by Electrospinning", Carbohydr. Polym., 2010, 79, 214-218.   DOI
17 Y. Xu, C. Wang, N. M. Stark, Z. Cai, and F. Chu, "Miscibility and Thermal Behavior of Poly($\varepsilon$-caprolactone)/long-chain ester of Cellulose Blends", Carbohydr. Polym., 2012, 88, 422-427.   DOI   ScienceOn
18 M. Y. Kariduraganavar, F. J. Davis, G. R. Mitchell, and R. H. Olley, "Using an Additive to Control the Electrospinning of Fibres of Poly($\varepsilon$-caprolactone)", Polym. Int., 2010, 59, 827-835.
19 S. Ali, M. A. Mughal, U. Shoukat, M. A. Baloch, and S. H. Kim, "Cationic Starch (Q-TAC) Pre-Treatment of Cotton Fabric: Influence on Dyeing with Reactive Dye", Carbohydr. Polym., 2015, 117, 271-278.   DOI
20 S. M. R. Billah, R. M. Christie, and R. Shamey, "Direct Coloration of Textiles with Photochromic Dyes. Part 1: Application of Spiroindolinonaphthoxazines as Disperse Dyes to Polyester, Nylon and Acrylic Fabrics", Color Technol., 2008, 124, 223-228.   DOI