Browse > Article
http://dx.doi.org/10.15681/KSWE.2020.36.2.153

Application Status and Prospect of Magnetic Separation Technology for Wastewater Treatment  

Chu, Shaoxiong (Department of Environmental Engineering, Daejeon University)
Lim, Bongsu (Department of Environmental Engineering, Daejeon University)
Choi, Chansoo (Department of Applied Chemistry, Daejeon University)
Publication Information
Abstract
Magnetic separation technology is an efficient and environmentally friendly technology. Compared with the traditional wastewater treatment technology, the magnetic separation technology has its unique advantages and characteristics, and has been widely applied in the field of wastewater treatment. In particular, the emergence of superconducting magnetic separation technology makes possible for high application potential and value. In this paper, which through consulting with the literatures of Korea, Chinese, United States and other countries, the magnetic separation technology applied to wastewater treatment was mainly divided into direct application of magnetic field, flocculation, adsorption, catalysis and separation coupling technology. Advantages and limitations of the magnetic separation technology in sewage treatment and its future development were also studied. Currently, magnetic separation technology needs to be studied for additional improvement in processing mechanism, design optimization of magnetic carrier and magnetic separator, and overcoming engineering application lag. The selection, optimization and manufacturing of cheap magnetic beads, highly adsorbed and easily desorbed magnetic beads, specific magnetic beads, nanocomposite magnetic beads and the research of magnetic beads recovery technology will be hot application of the magnetic separation technology based on the magnetic carriers in wastewater treatment. In order to further reduce the investment and operation costs and to promote the application of engineering, it is necessary to strengthen the research and development of high field strength using inexpensive and energy-saving magnet materials, specifically through design and development of new high efficiency magnetic separators/filters, magnetic separators and superconducting magnetic separators.
Keywords
Magnetic adsorption; Magnetic catalysis; Magnetic flocculation; Magnetic separation; Wastewater treatment;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Philippova, O., Barabanova, A., Molchanov, V., and Khokhlow, A. (2011). Magnetic polymer beads: recent trends and developments in synthetic design and applications, European Polymer Journal, 47(4), 542-559.   DOI
2 Sarikaya, M., Abbasov, T., and Erdemoglu, M. (2006). Some aspects of magnetic filtration theory for removal of fine particles from aqueous suspensions, Journal of Dispersion Science and Technology, 27, 193-198.   DOI
3 Sharma, Y., Srivastava, V., Singh, V., Kaul, S., and Weng C. (2009). Nano-adsorbents for the removal of metallic pollutants from water and wastewater, Environmental Technology, 30(6), 583-69.   DOI
4 Shen, Z., Mei, R., and Wei, Y. (2014). Pilot research on treating wastewater by magnetic flocculation, Environment Engineering, 32, 367-369. [Chinese Literature]
5 Shi, W. (2005). The biologic effects of magnetization in sewage treatment, Journal of Lanzhou University(Natural Sciences), 41(2), 38-40. [Chinese Literature]   DOI
6 Su, T. L., Chiou, C. S., and Chen, H. W. (2012). Preparation photocatalytic activity, and recovery of magnetic photocatalyst for decomposition of benzoic acid, International Journal of Photoenergy, 26, 909678.
7 Sun, H., Shi, S., and Wang, P. (2006). Research on the application of several complex magnetic flocculants to restaurant wastewater, Industrial Water Treatment, 26(8), 55-58.   DOI
8 Sun, W., Li, Z., Wu, S. and Jia, S. (2006). Application of magnetic separating technology in polluted water treatment, Journal of Magnetic Materials & Devices, 37(4), 6-10.   DOI
9 Tang, S. C. and Lo, I. M. (2013). Magnetic nanoparticles: essential factors for sustainable environmental applications, Water Research, 47(8). 2613-2632.   DOI
10 Tuutijarvi, T., Lu, J., Sillanpaa, M., and Chen, G. (2009). As(V) adsorption on maghemite nanoparticles, Journal of Hazardous Materials, 166, 1420-1415.
11 Chen, Q., Feng, Y., and Dong, B. (2015). Research on inorganic scale pollution control of nano-filtration membrane using high gradient magnetizing pretreatment, Industrial Water Treatment, 35(3), 34-36.
12 Ambashta, R. D. and Sillanp, M. (2010). Water purification using magnetic assistance: a review, Journal of Hazardous Materials, 180(1), 38-49.   DOI
13 Baker, J. S., Judd, S. J., and Parsons, S. A. (1997). Antiscale magnetic pretreatment of reverse osmosis feedwater, Desalination, 110(1), 151-165.   DOI
14 Borlido, L., Azevedo, A. M., Roque, A. C. A., and Aires-Barros, M. R. (2013). Magnetic separations in biotechnology, Biotechnology Advances, 31(8), 1374-1385.   DOI
15 Wang, R. (2001). Test of anti-scale by powerfully magnetic waterprocessor, Technology of Water Treatment, 27(4), 239-241.   DOI
16 Wang, J., Yang, J., Jia, H., and Zhang, H. (2014). Enhanced magnetic cleaning in magnetic enhanced flocculation membrane filtration process, Chemical Industry and Engineering Society of China Journal, 65(12), 4997-5003.
17 Wang, L., He, Y., Fan, H., Hu, Y., and Wei, Y. (2007). Magnetic flocculation separation method for the treatment of oily wastewater. Environmental Engineering, 25(3), 12-14.   DOI
18 Wang, L., Li, J., Wang, Y., and Zhao, L. (2011). Preparation of nanocrystalline Fe3-xLaxO4 ferrite and their adsorption capability for congored, Journal of Hazardous Materials, 196, 342-349.   DOI
19 Wang, Y., Pugh, R., and Forssberg, E. (1994). The influence of interparticle surface forces on the coagulation of weakly magnetic mineral ultrafines in a magnetic field, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 90(2-3), 117-133.
20 Wu, D. and Lin, D. (2004). Study on sterile of stable-magnetic field, Jiangsu Preventive Medicine, 4, 3-5. [Chinese Literature]
21 Xing, Z., Tang, B., Chen, X., Fu, F., Zhang, Z., and Lu, Z. (2014). Adsorption mechanism of acid red 73 onto magnetic nanoparticles Fe3O4 from aqueous phase, Acta Scientiae Circumstantiae, 34(9), 2246-2255.
22 Yavuz, C. T., Prakash, A., Mayo, J., and Colvin V. (2009). Magnetic separations: from steel plants to biotechnology, Chemical Engineering Science, 64(10), 2510-2521.   DOI
23 Zhang, L., Wang ,W., Zhou, L., Shang, M., and Sun, S. (2009). $Fe_3O_4$ coupled BiOCl: A highly efficient magnetic photocatalyst, Applied Catalysis B: Environmental, 90, 458-462.   DOI
24 Zhang, X., He, X., Wei, M., Li, F., Hou, P., and Zhang, C. (2019). Magnetic flocculation treatment of coal mine water and a comparison of water quality prediction algorithms, Mine Water and the Environment, 38(1), 391-401.   DOI
25 Chin, C. J. M., Chen, P. W., and Wang, L. J. (2006). Removal of nanoparticles from CMP wastewater by magnetic seeding aggregation, Chemosphere, 63(10), 1809-1813.   DOI
26 Cui, L., Wang, K., and Wang, Y. (2010). Experimental study on large scale of piggery wastewater by magnetic flocculation, Industrial Safety and Environmental Protection, 36(5), 3-4.   DOI
27 De Vicente, I., Merino-Martos, A., Guerrero, F., Amores, V., and De Vicente, J. (2011). Chemical interferences when using high gradient magnetic separation for phosphate removal: consequences for lake restoration, Journal of Hazardous Materials, 192(3), 995-1001.   DOI
28 Zhang, W., Wang, M., Zhao, W., and Wang, B. (2013). Magnetic composite photocatalyst $ZnFe_2O_4/BiVO_4$:synthesis, characterization, and visible-light photocatalytic activity, Dalton Transactions, 42(43), 15464-15474.   DOI
29 Zhang, X., Chen, J., Han, J., and Zhang, G. (2013). Preparation and evaluation of shell-core structured $Fe_3O_4/MnO_2$ magnetic adsorbent for Pb(II) removal from aqueous solutions, Acta Scientiae Circumstantiae, 33(10), 2730-2736.
30 Zhao, H. and Wang, J. (2002). Experiment in treatment of municipal wastewater by magnetic flocculation, Journal of Lanzhou Railway University(Natural Sciences), 21(3), 79-82. [Chinese Literature]   DOI
31 Zhao, Y., Xi, B., Li, Y., Wang, M., Zhu, Z., Xia, X., Zhang, L., Wang, L., and Luan, Z. (2012). Removal of phosphate from wastewater by using open gradient superconducting magnetic separation as pretreatment for high gradient superconducting magnetic separation, Separation and Purification Technology, 86, 255-261.   DOI
32 Zhou, M. and Ni, M. (2009). Application technology and development trend of magnetic separation technology in water treatment engineering, Water-Industry Market, 8, 48-53. [Chinese Literature]
33 Zaidi, N. S., Sohaili, J., Muda, K., and Sillanpaa, M. (2014). Magnetic field application and its potential in water and wastewater treatment systems, Separation & Purification Reviews, 43(3), 206-240.   DOI
34 Gao, J., Ma, S., Xie, Z., Mo, H., Lu, J., Chu, L., and Du, L. (2009). Study on magnetic seeds and flocculationg-high gradient magnetic separation and ultrafiltration lustration in cane mixed juice, The Food Industry, 6, 17-18. [Chinese Literature]
35 Ditsch, A., Lindenmann, S., Laibinis, P. E., Wang, D. I. C., and Hatton, T. A. (2005). High-gradient magnetic separation of magnetic nanoclusters, Industrial & Engineering Chemistry Research, 44(17), 6824-6836.   DOI
36 Dong, T., Yang, L., Zhu, M., Liu, Z., Sun, X., Yu, J., and Liu, H. (2015). Removal of cadmium(II) from wastewater with gas-assisted magnetic separation, Chemical Engineering Journal, 280(15), 426-432.   DOI
37 Fang, M., Mishima, F., and Akiyama, Y., and Nishijima, S. (2010). Fundamental study on magnetic separation of organic dyes in wastewater, Physica C: Superconductivity and its Applications, 470(20), 1827-1830.   DOI
38 Gokon, N., Shimada, A., Hasegawa, N., Kaneko, H., Tamaura, Y., Lto, K., and Ohara, T. (2002). The magnetic coagulation reaction between paramagnetic particles and iron ions coprecipitates, Journal of Magnetism and Magnetic Materials, 246(1), 275-282.   DOI
39 Han, G. (2017). Experiment and comparison of waste liquid treatment technology in daqing grape flower oilfield, Oil-Gasfield Surface Engineering, 36(2), 21-24. [Chinese Literature]
40 Ha, D., Kwon, J., Baik, S., Lee, Y., Han, K., Ko, R., Sohn, M., and Seong, K. (2011). Purification of condenser water in thermal power station by superconducting magnetic separation, Physica C: Superconductivity and its Applications, 471(21), 1530-1532.   DOI
41 Karapinar, N. (2003). Magnetic separation of ferrihydrite from wastewater by Magnetic seeding and high-gradient magnetic separation. International Journal of Mineral Processing, 71(1), 45-54.   DOI
42 Higashitani, K., Okuhara, K., and Hatade, S. (1992). Effects of magnetic fields on stability of nonmagnetic ultrafine colloidal particles, Journal of Colloid and Interface Science, 152(1), 125-131.   DOI
43 Ihara, I., Kanamura, K., Shimada, E., and Watanabe, T. (2004). High gradient magnetic separation combined with electrocoagulation and electrochemical oxidation for the treatment of landfill leachate, IEEE Transactions on Applied Superconductivity, 14(2), 1558-1560.   DOI
44 Kang, X. and Yang, Y. (2011). An experimental study in removal of copper ions from industrial wastewater by magnetic flocculation, Industrial Water & Wastewater, 42(3), 24-27.   DOI
45 Kim, Y., Lee, B., and Yi, J. (2003). Preparation of functionalized mesostructured silica containing magnetite(MSM) for the removal of copper ions in aqueous solutions and its magnetic separation. Separation Science and Technology, 38(11), 2533-2548.   DOI
46 Guan, D., Yuan, L., Xu, J., and He, D. (2014). Treatment of coal-to-oil production wastewater enhanced by magnetic flocculation technology, Environmental Science & Technology, 37(9), 141-144.
47 Kim, Y., Park, K., and Oh, C. (2014). Survey on electrocoagulation to purify contaminated water, Journal of Energy Engineering, 23(3), 17-20.   DOI
48 Li, S., Wang, M., Zhu, Z., Wang, Q., Zhang, X., Song, H., and Cang, D. (2012). Application of superconducting HGMS technology on turbid wastewater treatment from converter, Separation and Purification Technology, 84, 56-62.   DOI
49 Lee, S., Kim, H., Kim, D., Kim, O., Lee, M., and Lee, J. (2006). Development of technology for recycling the waste cutting oil and by-products by magnetic separation, Ministry of Environment. [Korean Literature]
50 Li, J., Liu, J., Yang, T., and Xiao, C. (2007). Quantitative study of the effect of electromagnetic field on scale deposition on nanofiltration membranes via UTDR, Water Research, 41(20), 4595-4610.   DOI
51 Li, Y., Tan, S., Zhang, W., Sun, Z., and Zhou, B. (2018). Recovery of phosphorus in sewage wastewater using magnetized FeOOH and superconducting magnetic separation, Desalination and water treatment, 133, 167-176.   DOI
52 Lim, D., Kim, Y., Kim, D., Lee, T., and Lim H. (2012). Synthesis and phosphorus adsorption characteristics of zirconium magnetic adsorbent having magnetic separation capability, Journal of Korean Society of Water and Wastewater, 26(3), 431-442. [Korean Literature]   DOI
53 Liu, Y. and Sun, X. (2000). Restraint of scale formation by magnetized water and its mechanism, Journal of Harbin Institute of Technology, 32(1), 86-90. [Chinese Literature]   DOI
54 Luo, M. and Lu, Z. (2000). A study of influence of magnetic field on anti-scale effect in water treatment, Technology of Water Treatment, 26(4), 218-221.   DOI
55 Ma, Y., Sun, Y., Zhu, X., and Ruan, Y. (2018). The synthesis of $CoFe_2O_4$, $CoFe_2$, $CoFe_2/CoFe_2O_4$ and their applications in photocatalysis, Journal of Anhui University(Natural Science Edition), 42(1), 54-60. [Chinese Literature]
56 Narsetti, R., Curry, R. D., Mcdonald, K. F., Clevenger, T. E., and Nichols, L. M. (2006). Microbial inactivation in water using pulsed electric fields and magnetic pulse compressor technology, IEEE Transactions on Plasma Science, 34(4), 1386-1393.   DOI