Browse > Article
http://dx.doi.org/10.15681/KSWE.2015.31.4.387

Nitrogen and Phosphorus Recoveries from Anaerobic Digester Supernatant Using Seawater as Magnesium Source for Struvite Formation  

Kim, Yong-Beom (Department of Environmental Engineering, College of Engineering, Kangwon National University)
Ahn, Johng-Hwa (Department of Environmental Engineering, College of Engineering, Kangwon National University)
Publication Information
Abstract
This study was performed to evaluate the effect of pH (8-12) and molar ratio of magnesium and phosphate ($[Mg^{2+}]/[PO_4{^{3-}}]$) (0.6-1.4) on struvite crystallization of anaerobic digester supernatant using seawater as magnesium source. pH range of 9-10 is favorable for ammonium and phosphate recoveries. The recovery efficiency of ammonium was highest at $[Mg^{2+}]/[PO_4{^{3-}}]$ of 1.0 and pH 10. On the other hand, high phosphate recovery efficiency (> 99%) was achieved at ($[Mg^{2+}]/[PO_4{^{3-}}]$) of 1.4 and pH 10. The results demonstrated that seawater can be considered as low-cost magnesium source to recover phosphorus from anaerobic digester supernatant.
Keywords
Anaerobic digester supernatant; Nitrogen recovery; Phosphorus recovery; Seawater; Struvite crystallization;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 American Public Health Association (APHA). (2012). Standard Method for the Examination of Water & Wastewater, 22nd Edition, American Public Health Association, Washington D.C., USA.
2 Choi, S. H. (2003). Official Test Methods of Water Quality, Shinkwang Publisher. [Korean Literature]
3 Choi, W. J., Park, K., M., Yoon, B. G., Kim, M. C., and Oh, K. J. (2009). Recovery of Presource from Sewage Sludge by a Struvite-Forming Method, Journal of Korean Society of Environmental Engineers, 31(7), pp. 557-564. [Korean Literature]
4 Ichihashi, O. and Hirooka, K. (2012). Removal and Recovery of Phosphorus as Struvite from Swine Wastewater Using Microbial Fuel Cell, Bioresource Technology, 114, pp. 303-307.   DOI
5 Jaffer, Y., Clark, T. A., and Pearce, S. A. (2002). Potential Phosphorus Recovery by Struvite Formation, Water Research, 36(7), pp. 1834-1842.   DOI
6 Kim, J. O., Jung, J. T., and Kim, H. K. (2006). Removal of Nitrogen and Phosphorus in Anaerobic Fermentation Supernatant by Struvite Crystallization, Journal of the Korean Geo-Environmental Society, 7(6), pp. 5-12. [Korean Literature]
7 Kim, J. Y., Moon, Y. T., Seo, I. S., and Kim, B. G. (2007). Estimation of the Optimum Factor of the Struvite Crystallization for Nitrogen and Phosphorus Removal in WWTP, Journal of the Korean Society of Water and Wastewater, 21(6), pp. 745-753. [Korean Literature]
8 Lahav, O., Telzhensky, M., Zewuhn, A., Gendel, Y., Gerth, J., Calmano, W., and Birnhack, L. (2013). Struvite Recovery from Municipal-Wastewater Sludge Centrifuge Supernatant Using Seawater NF Concentrate as a Cheap Mg(II) Source, Separation and Purification Technology, 108, pp. 103-110.   DOI
9 Lee, H. and Yun, Z. (2013). Possibility of Anoxic Phosphorus Removal by Denitrifier in Denitrifying EBPR System, Journal of Korean Society on Water Environment, 29(6), pp. 782-789. [Korean Literature]
10 Liu, B., Giannis, A., Zhang, J., Chang, V. W. C., and Wang, J. Y. (2013). Characterization of Induced Struvite Formation from Source-Separated Urine Using Seawater and Brine as Magnesium Sources, Chemosphere, 93, pp. 2738-2747.   DOI
11 Luz, E. B. and Yoav, B. (2004). Recent Advances in Removing Phosphorus from Wastewater and its Future Use as Fertilizer, Water Research, 38(19), pp. 4222-4246.   DOI
12 Muryanto, S. and Bayuseno, A. P. (2012). Wastewater Treatment for a Sustainable Future: Overview of Phosphorus Recovery, Applied Mechanics and Materials, 110-116, pp. 2043-2048.
13 Ryu, H. D., Kim, T. S., Park, H. S., and Lee, S. I. (2007). Struvite Crystallization of Wastewater Using Bittern, Journal of Korean Society on Water Environment, 23(1), pp. 138-143. [Korean Literature]
14 Yim, S. B. (2010). Feasibility of Industrial By-products as a seed Crystal of Struvite Crystallization for the Removal of Highly Concentrated Nitrogen and Phosphorus, Journal of Korean Society on Water Environment, 26(4), pp. 664-672. [Korean Literature]
15 Tchobanoglous G. and Burton, F. L. (1991). Wastewater Engineering: Treatment Disposal Reuse, 3rd Edition, McGraw Hill, New York, N. Y. p. 308.