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Adsorption Features of Nickel Ion on Deep Sea Manganese Nodule  

Baek, Mi-Hwa (Department of Environmental Science and Engineering, Ewha Womans University)
Shin, Myung-Sook (Department of Environmental Science and Engineering, Ewha Womans University)
Kim, Dong-Su (Department of Environmental Science and Engineering, Ewha Womans University)
Jung, Sun-Hee (Department of Environmental Science and Engineering, Ewha Womans University)
Park, Kyoung-Ho (Minerals and Materials Processing Division, Korea Institute of Geoscience and Mineral Resources)
Publication Information
Journal of Korean Society on Water Environment / v.22, no.1, 2006 , pp. 116-121 More about this Journal
Abstract
Fundamental investigations have been carried out to find the applicability of manganese nodule as an adsorbent of nickel ion with an intention that nickel can be secured in manganese nodule along with the treatment of wastewater. The average content of manganese in nodules which used in the experiments was about 27%. The content of nickel in manganese nodules was observed to increase up to 4 times higher with comparison to its original value after adsorption. When the initial concentration of nickel ion in artificial wastewater was lower than 500 mg/L, its adsorbed amount on manganese nodule was shown to increase continuously. However, no more than about 82 mg/L of nickel was attained at higher initial nickel ion concentration than 500 mg/L. The adsorption of nickel ion was increased with temperature under experimental conditions and as the size of manganese nodule particles became smaller more nickel ion was adsorbed on adsorbent. Regarding the effect of pH, the adsorption of nickel ion was more hindered as the solution became acidic. Adsorption behavior of nickel ion on manganese nodule was found to follow the Freundlich model well and kinetic analysis showed that the adsorption reaction of nickel ion was second order. Thermodynamic parameters for the nickel ion adsorption were estimated on the basis of thermodynamic equations and they were in good agreement with experimental results.
Keywords
Adsorption; Manganese nodule; Nickel;
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1 Huang, Y. S., Zeng, X.P., Hu, X. F. and Liu, F. M., Corrosion Resistance Properties of Electroless Nickel Composite Coatings, Electrochimica Acta, 49, pp.4313-4319 (2004).   DOI   ScienceOn
2 Fuerstenau, D. W. and Han, K. N., Metallurgy and Processing of Marine Manganese Nodules, Mineral Processing and Technology Review, 1, pp. 1-83 (1983)
3 Muller, C., Sarret, M. and Benballa, M., Some Peculiarities in the Codeposition of Zinc-Nickel Alloys, Electrochimica Acta, 46(18), pp. 2811-2817 (2001)   DOI   ScienceOn
4 Han, K. N. and Fuerstenau, D. W., Kinetics of the Extraction of Metals from Deep-Sea Manganese Nodules: Part I. The Pore Diffusion Controlling Case, Metall. Trans. B, 7, pp. 679-985 (1976)   DOI   ScienceOn
5 Nishiyama, T., Kita, H., Sanada, K. Y. and Takahashi, K., The Absorption Behavior of Metal Ions on Manganese Nodules, J. of Min, Met. Inst of Japan, 100, pp. 587-591 (1984)
6 Brooke, J. N. and Prosser, A. P., Manganese Nodules as a Sources of Copper and Nickel, Trans. Inst. Min. Metall., 78, pp. 64-73 (1970)
7 Murray, J. W., Balistrieri, L. S. and Paul, B., The Oxidation State of Manganese in Marine Sediments and Ferromanganese Nodules, Geochim. Cosmochim. Acts, 48, pp. 1237-1247 (1984)   DOI   ScienceOn
8 Iammartino, N. R., Metals from Mn Nodules, Chemical Engineering, 81(25), pp. 52-53 (1974)
9 남철우, 김병수, 박경호, 환원배소-용융에 의한 망간단괴로 부터 코발트, 니켈, 구리 회수, 한국지구시스템공학회지, 40(3) , pp. 191-197 (2003)
10 박경호, 심해저 망간단괴의 처리기술, 한국광물학회지, 7(1) , (1994)
11 곽용완, 박재구, 암모니아성 망간단괴 침출액으로부터 코발 트의 회수, 한국자원공학회지, 36(6), pp. 448-455 (1999)
12 Murray, D. J., Heary, T. W. and Fuerstenau, D. W., The Adsorption of Aqueous Metal on Colloidal Hydrous Manganese Oxide, Adsorption of Aqueous Metal, pp. 74-81 (1967)