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Hydrogen Production and Organic Removal according to Mixture Ratio of Food Wastewater and Swine Wastewater using Anaerobic Batch Reactor  

Kim, Choong-Gon (광운대학교 환경공학과)
Kang, Seon-Hong (광운대학교 환경공학과)
Publication Information
Journal of Korean Society of Water and Wastewater / v.21, no.5, 2007 , pp. 641-647 More about this Journal
Abstract
This study aims to find out optimum condition for hydrogen production and organic removal when treating food and swine wastewater together. For this purpose, various batch tests were conducted by changing mixture ratio from 6:4 (food wastewater:swine wastewater) to 1:9 without pretreatment process. For hydrogen production through anaerobic fermentation, the mixture ratios of R-1 (6:4), R-2 (5:5) and R-6 (1:9) were out of pH range appropriate for hydrogen production and mixture ratios of R-3 (4:6), R-4 (3:7), and R-5(2:8) showed appropriate hydrogen production where their pH ranges were 5.1~5.5. Especially in case of R-3, it consistently maintained appropriate pH range for hydrogen production for 72hr and produced maximum hydrogen. The characteristics of hydrogen production and cumulative hydrogen production according to each mixture ratio showed that R-1, R-2 and R-6 did not produce any hydrogen, and maximum hydrogen productions of R-3, R-4 and R-5 were 593ml, 419ml and 90ml, respectively. Total cumulative hydrogen productions of R-3, R-4 and R-5 were 1690ml, 425ml and 96ml, respectively. Based on previous results, it was concluded that, the most appropriate mixture ratio of food wastewater and swine wastewate rwas 4:6 (R-3). The experiment for COD removal rate to evaluate organic removal efficiency revealed that R-3, R-4 and R-5 showed high removal efficiencies during the highest hydrogen production amount and the highest efficiency was 41% with R-3.
Keywords
Food wastewater; Swine wastewater; Mixture ratios; Hydrogen; Anaerobic Fermentation; Organic Removal;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 Hwang, M.H. (2004) Characteristic of anaerobic biological hyd1'ogen produaion in nio phase anaerobic process, Ph.D. Thesis, K-JIST
2 Inane, B., Matsui, S. and Idle, S., (1996) Propionic acid accumulation and controlling factors in anaerobic treatment of carbohydrate: Effect of $H_{2}$ and pH, Wat. Sci. Tech., 34(56), pp. 317-325   DOI   ScienceOn
3 Mizuno, O., Dinsdale, R., Hawkes, F.R., Hawkes, D.L. and Noike, T.(2000) Enhancement of hydrogen production from glucose by nitrogen gas sparging, Bioresouce Technol., 73, pp. 57-65
4 Richard, E. Speece (1983) Anaerobic biotechnology for industrial wastewater treatment, Emnron Sci. Tecbnol., 17(9), pp.416-427
5 김동건 (2006) 음식물쓰레기와 폐활성슬러지를 이용한 수소생산에서의 최적 발효조건, pp. 96-97, 서울시립대 박사학위 논문
6 Kim, S.H., Han, S.K., and Shin, H.S. (2004) Feasibility of biohydrogen production by anaerobic co-digestion of food waste and sewage sludge, Int. J. Hydrogen Energy, 29, pp. 1607-1616   DOI   ScienceOn
7 Chang, F.Y. and Lin, C.Y. (2004) Biohydrogen production using an up-flow anaerobic sludge blanket reactor, Int. J. Hydrogen Energy, 29(1), pp. 33-39   DOI   ScienceOn
8 Lee, Y.J., Miyahara, T. and Noiks, T. (1999) Effect of pH on the microbial hydrogen fermentation, In proceeding of the 6th IAWQ Asian-Pacifu conference, Taipei, pp. 215-220
9 Fan, Y., Li, c, Lay, J.J., Hou, H. and Zhang, G. (2004) Optimization of initial substrate and pH levels for germination of sporing hydrogen producing anaerobes in cow dung compost, Bioresouce Technol., 91, pp. 189-193   DOI   ScienceOn
10 환경부 (2006a) 유기성오니 처리 종합대책, pp.1
11 Das, D. and T.N. Veziroglu (2001) Hydrogen Production by Biological Processes: a Survey of Literature, International Journal of Hydrogen Energy, 26, pp.13-28   DOI   ScienceOn
12 김총곤, 강선홍 (2007) 혐기성 발효에서 수소 생산 시 온도의 영향에 관한 연구, 상하수도학회지, 21(4), pp. 467-475
13 Chen, C.C. and Lin, C.Y. (2003) Using sucrose as a substrate in an anaerobic hydrogen producing reactor, Adc. Environ. Res., 7, pp.695-699   DOI   ScienceOn
14 환경부 (2006b) 2006년 환경백서, pp. 547
15 강창민 (2002) 도시하수슬러지의 전처리에 따른 혐기성 소화공정의 생분해율 향상에 관한 연구, 유기성자원학회지, 10(1), pp. 87-95
16 APHA., AWWA, and WEF (1998) Stamford Metbodsior the Examination of Water and Wastewater, 20th edition, Washington DC, USA
17 박상철, 김진철, 이정갑, 이남훈, 김혜진 (2006) 하수슬러지 고화처리 및 음식물탈리액 처리에 관한 기술, 유기성자원학회 춘계학술발표논문 발표집, pp. 139-143
18 Fang, H.H.P., Liu, Hong. (2002) Effect of pH and hydrogen production from glucose by a mixed culture. Bioresource Technology, 82, pp. 87-93   DOI   ScienceOn
19 Lin, C.Y., and Chang, R.C. (1999) Hydrogen production during the anaerobic acidogenic conversion of glucose. J. Chem. Technol. Biochnol. 74, pp. 498-500   DOI   ScienceOn