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http://dx.doi.org/10.5762/KAIS.2020.21.4.575

Surface Resistance of Antistatic Agent Using Lithium-Fluoro Compound and Quaternary Ammonium Salt and Characteristics Evaluation of Antistatic Film  

Soh, Soon-Young (Department of Chemical Engineering, Chungwoon University)
Chun, Yong-Jin (Department of Chemical Engineering, Chungwoon University)
Lee, Jae-Kyeong (GnB Corporation)
Publication Information
Journal of the Korea Academia-Industrial cooperation Society / v.21, no.4, 2020 , pp. 575-581 More about this Journal
Abstract
A colorless antistatic agent was prepared for use in antistatic films for liquid crystal displays (LCDs) requiring low surface resistance and high transmittance. Among various lithium-fluoro compounds and quaternary ammonium salts, antistatic materials were selected based on their electrical conductivity, and antistatic agents were prepared to measure the surface resistance. As a result, the material with high conductivity showed a relatively low surface resistance, i.e., relatively good antistatic performance. Based on the antistatic materials selected, the formulation ratio for producing the best antistatic agent was established through the experimental design method and the effects of each factor were analyzed. The higher the use of lithium- fluoro compounds as antistatic materials, the higher the ratio of oligomer use with multi-functional groups, and the smaller the surface resistance. The quaternary ammonium salts increased the antistatic performance of the lithium-fluoro compounds, but the effects of the amount used were not relatively large. After manufacturing the antistatic PET film, the properties of the antistatic film showed low surface resistance values (<109 Ω/sq.), high permeability (>92%), low haze (<0.5%), and high whiteness (L>95). In addition, the antistatic film reliability was found to be excellent by showing a stable surface-resistance change rate of less than 10%, even under high temperature and high humidity conditions.
Keywords
Antistatic Agent; Surface Resistance; Conductivity; Experimental Design; Antistatic Film Evaluation;
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1 H. K. Gurakin, A. C. Turan, and H. Deligoza, "Synthesis of a novel polyester-ether copolymer and its derivatives as antistatic additives for thermoplastic films", Polymer Testing, Vol. 81, Jan. 2020. DOI:https://doi.org/10.1016/j.polymertesting.2019.106214
2 A. Tsurumaki, T. Iwata, M. Tokuda, H. Minami, M. A. Navarra, and H. Ohno, "Polymerized ionic liquids as durable antistatic agents for polyether-based polyurethanes", Electrochimica Acta, Vol. 308, pp 115-120, Jun. 2019. DOI: https://doi.org/10.1016/j.electacta.2019.04.031   DOI
3 T. Iwata, A. Tsurumaki, S. Tajima, and H. Ono, "Fixation of ionic liquids into polyether-based polyurethane films to maintain long-term antistatic properties", Polymer, Vol. 55, No. 10, pp. 2501-2504, May 2014. DOI: https://doi.org/10.1016/j.polymer.2014.03.028   DOI
4 T. Kobayashi, B. A. Wood, A. Takemura, and H. Ono, "Antistatic performance and morphological observation of ternary blends of poly(ethylene terephthalate), poly(ether esteramide), and Na-neutralized poly(ethylene -co-methacrylic acid) opolymers", Journal of Electrostatics, Vol. 64, No. 6, pp. 377-385, Jun. 2006. DOI: https://doi.org/10.1016/j.elstat.2005.09.004   DOI
5 J. T. Whang, "Development trend of polymer antistatic agent", Proceedings of Autumn Conference on the Korean Polymer Society, Vol. 43, No.1, pp.52-52, Oct. 2018. http://www.dbpia.co.kr/Article/NODE07545322
6 S. W. Park, S. Y. See, M. Y. Seo, J. H. Seo, Y. S. Shin, and G. Koo, "A study on the synthesis of durable antistatic agent using water soluble polymers and amines", Journal of the Korean Society of Dyers and Finishers, Vol.13, No. 6, pp.55-69, 2001. http://www.dbpia.co.kr/Article/NODE01798405
7 Z. M. Xue, C. Q. Ji, W. Zhou, C. H. Chen, "A new lithium salt with 3-fluoro-1,2-benzenediolato and oxalato complexes of boron for lithium battery electrolytes", Journal of Power Sources, Vol. 195, No. 11, pp. 3689-3692, Jun. 2010. DOI: https://doi.org/10.1016/j.jpowsour.2009.12.049   DOI
8 Z. M. Xue, B. H. Zhao, C. H. Chen, "A new lithium salt with 3-fluoro-1,2-benzenediolato and lithium tetrafluoroborate for lithium battery for lithium battery electrolytes", Journal of Power Sources, Vol. 196, No. 15, pp. 6478-6482, Aug. 2011. DOI: https://doi.org/10.1016/j.jpowsour.2011.04.011   DOI
9 J. H. Kim, and J. W. Ha, "A study on the preparation and application of uv-curing antistatic agent", Proceedings of 2004 Spring Conference on the Korea Academia-Industrial cooperation Society, pp.264-266, Jun. 2004. http://www.dbpia.co.kr/Article/NODE07215790
10 Y Kugimoto, A. Wakabayashi, T. Dobashi, O.samu Ohnishi, T. K. Doi, and S. Kurokawa, "Preparation and characterization of composite coatings containing a quaternary ammonium salt as an anti-static agent", Progress in Organic Coatings, Vol.92, pp. 80-84, Mar. 2016. DOI: https://doi.org/10.1016/j.porgcoat.2015.11.013   DOI
11 L. Wu, Y. Ge, L. Zhang, D. Yu, M. Wu, and H. Ni, "Enhanced electrical conductivity and competent mechanical properties of polyaniline/polyacrylate(PANI/PA) composites for antistatic finishing prepared at the aid of polymeric stabilizer", Progress in Organic Coatings, Vol. 125, pp. 99-108, Dec. 2018. DOI: https://doi.org/10.1016/j.porgcoat.2018.09.002   DOI
12 L&J TECH Homepage, Available From: http://lnjcompany.com/antistatic-coating (accessed Mar, 19, 2020)
13 H. Nikoofard, and M. Hosseini, "Study of electrical conductivity and thermochemical stability of oligo (3,4-ethylenedioxythiophene) at temperature range of 50-400 K", Synthetic Metals, Vol. 256, Article 116118, Oct. 2019. DOI: https://doi.org/10.1016/j.synthmet.2019.116118