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http://dx.doi.org/10.5762/KAIS.2017.18.2.711

Study on Synthesis of Honeycomb-patterned Resin Dispersed Silver Nanoparticles  

Lee, Dong Chang (Division of Chemical Engneering, Kongju National University)
Lee, Jong Jib (Division of Chemical Engneering, Kongju National University)
Publication Information
Journal of the Korea Academia-Industrial cooperation Society / v.18, no.2, 2017 , pp. 711-718 More about this Journal
Abstract
Silver nanoparticles were attached by chemical reduction after synthesizing a porous PVK-CTA complex. The PVK-CTA complex was synthesized by polymerizing N-vinylcarbazole in a CTA-chloroform solution using iron(III) chloride as an oxidizing agent and a honeycomb-pattern with uniformly formed macropores was formed by applying steam to the complex surface soaked with a volatile solvent under humid conditions. Using TTF as a reducing agent and PVP as a dispersant, silver nanoparticles were attached on the Honeycomb-pattern complex surface through chemical reduction. The formation of the complex was confirmed by FT-IR and UV-Vis spectrometry, and the degree of thermal decomposition of the complexes was analyzed after N-vinylcarbazole was polymerized by varying its concentration. The uniformity of the pores on the composite surface and the dispersibility of the attached silver nanoparticles were investigated by SEM. The dispersibility of the silver nanoparticles was also analyzed by varying the concentrations of reducing agent and dispersant and precursor.
Keywords
Ag composite resin; Ag nanoparticle; Chemical reduction; Honeycomb-patterned resin; PVK-CTA complex;
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