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http://dx.doi.org/10.5762/KAIS.2010.11.12.5221

A Study on the Complexation of Nickel(II) Ion with 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol(Monotris) in Aqueous Solution  

Hong, Kyung-Hee (Dept. of Cosmetology & Beauty, Sahmyook Health College)
Shim, Seung-Bo (Dept. of Chemical Engineering, Hanyang University)
Oh, Seong-Geun (Dept. of Chemical Engineering, Hanyang University)
Chun, Yong-Jin (Dept. of Cosmetic Science, Chungwoon University)
Publication Information
Journal of the Korea Academia-Industrial cooperation Society / v.11, no.12, 2010 , pp. 5221-5231 More about this Journal
Abstract
The complex formation from Ni(II) ion and 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol(Monotris) in aqueous solution at $25^{\circ}C$ and at ionic strength of 0.10M has been studied potentiometrically. In the Monotris(L) comlex $NiL^{2+}$, hydroxyl oxygen atom as well as the amine nitrogen of the ligand are coordinated to the Ni(II) ion.. The complex $NiL^{2+}$ undergoes further dissociation as the pH is increased forming triply deprotonated dinuclear complex $Ni_2L_2H_{-3}^+$.
Keywords
Potentiometric; Deprotonated dinuclear complex; $NiL^{2+}$; $Ni_2L_2H_{-3}^+$;
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