Trends in Research and Technical Development of Sorbents for Hot Gas Desulfurization for H2S Removal |
Seo, Jun-Hyung
(Department of Research and Development, Korea Institute of Limestone and Advanced Materials)
Baek, Chul-Seoung (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) Kwon, Woo Tech (Department of Energy Environment Materials, Korea Institute of Ceramic Engineering and Technology) Ahn, Ji-Whan (Affiliation Carbon Resource Recycling Appropriate Technology Center, Korea Institute of Geoscience and Mineral Resources) Cho, Kye-Hong (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) |
1 | Kobayashi, S., 1990 : Test Result of Yubari Hot Gas Desulfurization Pilot Plant, Coal Conversion Technology Department Ishikawajima-Harima Heavy Industries CO. Ltd, Engineering Research Association for IGCC Report, pp. 198. |
2 | Westmoreland P. R and Harrison D. P., 1976 : Evaluation of candidate solids for high-temperature desulfurizaton of low-Btu gases, J. of Environmental Science and Technology, 10(7), pp. 659-661. DOI |
3 | Mayernick, A. D et al., 2011 : Energetics and Mechanism for Adsorption by Ceria-Lanthanide Mixed Oxides : Implications for the Desulfurization of Biomass Gasifier Effluents, The Journal of Physical Chemistry, 115(49), pp. 24178-24188. |
4 | Wang. J et al., 2015 : Calcium-based regenerable sorbents for high temperature removal, Fuel, 154(15), pp. 17-23. DOI |
5 | Yu, J. L et al., 2013 : Sulfur removal property of activated-char-supported Fe-Mo sorbents for integrated cleaning of hot coal gases, Fuel. 108, pp. 91-98. DOI |
6 | Dooley, K. M. et al., 2011 : High-Temperature Desulfurization of Gasifier Effluents with Rare Earth and Rare Earth/Transition Metal Oxides, Energy Fuels, 25(3), pp. 1213-1220. DOI |
7 | Dhage, P et al., 2011 : Regenerable sorbents for room temperature removal of H2S from fuel reformates : performance, active sites, Operando studies, Physical Chemistry Chemical Physics, 13(6), pp. 2179-2187. DOI |
8 | Ryu, C, K. et al., 1998 : Status of research on Development of High Temperature Desulfurization Sorbents for IGCC (I), Chemical industry and Technology, 16(1), pp. 17-29. |
9 | Satterfield, C. N. and Feakes, F., 1959 : Kinetics of the thermal decomposition of calcium carbonate, American Institute of Chemical Engineers. 5(1), pp. 115-122. DOI |
10 | Gallagher, P. K. and Johnson, D. W., 1976 : Kinetics of the thermal decomposition of in and some observations on the kinetic compensation effect, Thermochimica Acta, 14(3), pp. 255-261. DOI |
11 | Caldwell, K. M. et al., 1977 : Effect of thermal transport mechanisms on the thermal decomposition of , Thermochimica Acta, 18(1), pp. 15-19. DOI |
12 | Fenouil, L. A. and Lynn, S., 1995 : Study of Calcium-Based Sorbents for High-Temperature Removal. 3. Comparison of Calcium-Based Sorbents for Coal Gas Desulfurization, Industrial and Engineering Chemistry Research, 34(7), pp. 2343-2348. DOI |
13 | Slimane, R. B. and Abbasian, J., 2001 : Utilization of metal oxide-containing waste materials for hot coal gas desulfurization, Fuel Processing Technology, 70(2), pp. 97-113. DOI |
14 | Fenoutl, L. A and Lynn. S., 1995 : Study of Calcium Based Sorbents for High-Temperature Removal. 1. Kinetics of Sorption by Uncalcined Limestone, Industrial Engineering Chemical Resources, 34(7), pp. 2324-2333. DOI |
15 | Fenoutl, L. A and Lynn. S., 1995 : Study of Calcium Based Sorbents for High-Temperature Removal. 2. Kinetics of Sorption by Calcined Limestone, Industrial Engineering Chemical Resources, 34(7), pp. 2334-2342. DOI |
16 | Lee. H. D, 2014 : Coal energy utilization technology and market trends, J. of the Electric World, pp. 45-51. |
17 | Greenpeace, 2015 : http://www.greenpeace.org/korea. |
18 | World Coal Association, 2015 : COP21 Position Statement, http://www.worldcoal.org. |
19 | Kim, S. C, 2011 : Integrated Gasification Combined cycle Technology and Carbon Capture Storage, NICE, 29(5), pp. 600-604. |
20 | Lee. C. U. et al., 2011 : Reactivity of Zinc-based Desulfurization Sorbents with Various Supports, J. of the Korean Society for Energy Engineering, Korea, Nov. 2011, pp. 239-242. |
21 | Ji, P. S., et al., 1993 : Integrated Gasification Combined cycle Technology, J. of the Korean Institute of Chemical Engineers, 11(2), pp. 76-86. |
22 | Harrison, D. P., 1990 : A Calcium Oxide Sorbent Process for Bulk Separation of Carbon Dioxide, DOE Annual report, DOE/MC/26366-2979. |
23 | Bhatia, S. K. and Perlmutter, D. D., 1983 : Effect of the product layer on the kinetics of the -lime reaction, American Institute of Chemical Engineers. 29(1), pp. 79-86. DOI |
24 | Akiti Jr. T. T. et al., 2002 : An improved core-in-shell sorbent for desulfurization hot coal gas, Advances in Environmental Research, 6(4), pp. 419-428. DOI |
25 | Delucia, D. E., 1985 : The cyclic use of limestone for capture, Massachusetts Institute of Technology, M. S. Thesis, pp. 1-150. |
26 | Kim. Y. S. et al., 1999 : Kinetic of High-Temperature Removal of by Ca-based Sorbents, J. of Environmental Science International, 8(1), pp. 125-133. |
27 | Kim, J. K. et al., 2002 : Reaction Characteristics of Separation from a Syngas Using CaO, J. of the Korean Institute of Chemical Engineers, 40(5), pp. 582-587. |
28 | Park, Y. C. et al., 2003 : Reaction Characteristics of Calcium-Based Adsorbents for Bulk Separation of in High-Temperature, J. of Korean Society of Environmental Engineers, 25(5), pp. 595-601. |
29 | Office of Fossil Energy., 2001 : Market-Based Advanced Coal Power Systems, Washington Technology, DOE report, DOE/FE-0400. |
30 | Schrodt, J. T. et al., 1975 : High-temperature desulfurization of low-CV fuel gas, Fuel, 54(4), pp. 269-272. DOI |
31 | Rutkowski, M. D. et al., 1996 : Assessment of Hot Gas Containment Control, Proceeding of the Advanced Coal-Fired Power Systems, 1996 Review Meeting. |
32 | Copeland, R, J. et al., 1996 : A Long Life Sorbent, Proceeding of the Advanced Coal-Fired Power Systems, 1996 Review Meeting. |
33 | Lew, S. et al., 1989 : High-Temperature Removal from Fuel Gases by Regenerable Zinc Oxide-Titanium Dioxide Sorbents, Industrial and Engineering Chemistry Research, 28(5), pp. 535-541. DOI |
34 | Park. N. K et al., 2003 : A Study on the Reactivity of Zinc-based Sorbents Using Yellow Earth as Support at Middle Temperatures, J. of Energy Engineering, 12(4), pp. 302-308. |
35 | Kwon, W. T et al., 1996 : Preparation of High Attrition Resistance Sorbents on High Temperature Desulfurization, Theories and Applications of Chemical Engineering, 2(1), pp. 709-712. |
36 | Park. N. K., 2000 : Reactivity of Calcium Carbonate for Hot Gas Desulfurization System, J. of the Institute of Industrial Technology, 28(2), pp. 85-93. |
37 | Copeland, R, J. et al., 1996 : Long Life and Novel Sorbent, Proceeding of the Advanced Coal-Fired Power Systems, 1996 Review Meeting. |
38 | Gibson, J. B. and Harrison, D. P., 1980 : The reaction between hydrogen sulfide and spherical pellets of zinc oxide, Industrial and Engineering Chemistry Process Design and Development, 19(2), pp. 231-237. DOI |
39 | Siriwardane, R. V. et a., 1994 : Spectroscopic Characterization of Molybdenum-Containing Zinc Titanate Desulfurization Sorbents, Industrial and Engineering Chemistry Research, 33(11), pp. 2810-2818. DOI |
40 | Tamhankar, S. S. et al., 1986 : Mixed-oxide sorbents for high-temperature removal of hydrogen sulfide, Industrial and Engineering Chemistry Process Design and Development, 25(2), pp. 429-437. DOI |
41 | Lew, S. et al., 1992 : Sulfidation of Zinc Titanate and Zinc Oxide Solids, Industrial and Engineering Chemistry Research, 31(8), pp. 1890-1899. DOI |
42 | Woods, M. C. et al., 1990 : Reaction Between Hydrogen Sulfide and Zinc Oxide-Titanium Oxide Sorbents, I. Single Pellet Kinetic Studies, Industrial and Engineering Chemistry Research, 29(7), pp. 1160-1167. DOI |
43 | Gupta, R. et al., 1992 : Development of Zinc Ferrite Sorbents for Desulfurization of Hot Coal Gas in a Fluid-Bed Reactor, Energy Fuels, 6(1), pp. 21-27. DOI |
44 | Ibarra, J. W. et al., 1998 : Vibrational Spectroscopy Study of Zinc-Containing Mixed as Regenerable Sulfur Sorbents at High-Temperature, Vibrational Spectroscopy, 16(1), pp. 1-10. DOI |
45 | Khare, G, P., 1994 : Absorption of Hydrogen Sulfide and Absorbent Composition Therefor, U.S patent, 5,306,685. |
46 | Lee, T, J. et al., 1996 : Removal of by Zinc-Based Sorbents from High Temperature Coal-Derived Gases, J. of the Korean Institute of Chemical Engineers, 34(4), pp. 435-442. |
47 | Park. N. K., 2014 : Status of development for Coal Gas Clean up in Integrated System of Hot Gas Desulfurization process, Trend Data of New and Renewable Energy, New and Renewable Energy Center in Korea Energy Agency, pp. 54-60. |
48 | Ikenaga, N. et al., 2004 : Preparation of zinc ferrite in the presence of carbon material and its application to hot gas cleaning, Fuel, 83(6), pp. 661-669. DOI |
49 | Susan. L. et al., 1992 : Modeling of the sulfidation of zinctitanium oxide sorbents with hydrogen sulfide, American Institute of Chemical Engineers Journal, 38(8), pp. 1161-1169. DOI |
50 | Kim. K. S. et al., 1997 : A Study on Preparation and Reactivity of Zinc Titanate Sorbents for Removal, J. of the Korean Industrial and Engineering Chemistry, 8(1), pp. 122-131. |
51 | Lee. T. J. et al., 1997 : A study on Regeneration of Zinc Titanate Sorbents for Removal, Korean Journal of Chemical Engineering, 14(6), pp. 513-518. DOI |
52 | Park, N. K et al., 2005 : The preparation of a high surface area metal oxide prepared by a matrix-assisted method for hot gas desulphurization, Fuel, 84(17), pp. 2165-2171. DOI |
53 | Park. N. K. et al., 2003 : A Study on the Reactivity of Zinc-based Sorbents for Hot Gas Desulfurization using Natural Zeolite as the Support, J. of the Korean Institute of Chemical Engineers, 41(5), pp. 667-674. |
54 | Turkdogan, E. T. and Olsson, R, G, 1979 : Desulfurization of hot reducing gases with manganese oxide pellets, Proceedings of the Third International Iron and Steel Congress ASM. ASM International, Materials Park, OH, pp. 277-288. |
55 | Hepworth, M. T. et al., 1993 : Thermodynamic Comparison of Several Sorbent System for Hot Coal Derived Fuel-Gas Desulfurization, Energy and Fuels, 7(6), pp. 602-609. DOI |
56 | Focht, G. D. et al., 1988 : High temperature desulfurization using zinc ferrite : reduction and sulfidation kinetics, Chemical Engineering Science, 43(11), pp. 3005-3013. DOI |
57 | Westmoreland. et al., 1997 : Comparative kinetics of high temperature reaction between and selected metal oxides, Environmental Science and Technology, 11(5), pp. 488-491. DOI |
58 | Jha, M. C. and Hepworth, M. T., 1986 : Enhanced Sorbent Durability for Hot Gas Desulfurization, DOE Final Report, DOE Contract DE-AC21-84MC21168, |
59 | Huang, Z. B. et al., 2016 : Performance of rare earth oxide doped Mn-based sorbent on various silica supports for hot coal gas desulfurization, Fuel, 177(1), pp. 217-225. DOI |
60 | Shon, B. H. et al., 2001 : Regeneration Properties of Manganese-Based Sorbent for Hot Coal Gas Desulfurization, J. of Korean Society of Environmental Engineers, 23(11), pp. 1775-1784. |
61 | Hong, S. C., 2005 : A Study on Simulation of Desulfurization in a Continuous Fluidized Bed Using Natural Manganese Ore, J. of Korean Chemical Engineering Research, 43(2), pp. 278-285. |
62 | Oh, K. J. et al., 2000 : Physical Properties and Sulfidation Kinetics of Mn-Based Sorbent for Hydrogen Sulfide Removal, J. of Korean Society of Environmental Engineers, 22(11), pp. 2067-2076. |
63 | Kang. S. H. et al., 1996 : A Study on Reaction Characteristics of High-Temperature Desulfurization Sorbents, J. of the Korean Society for Energy, 5(2), pp. 123-130. |
64 | Patrick, V. and Gavalas, G. R., 1993 : Reduction, Sulfidation, and Regeneration of Mixed Iron-Aluminum Oxide Sorbents, Industrial Engineering Chemistry Research, 32(3), pp. 519-532. DOI |
65 | Pan, Y. G. et al., 2005 : Kinetic behaviour of iron oxide sorbent in hot gas desulfurization, Fuel, 84(9), pp. 1105-1109. DOI |
66 | Sasaoka, E. et al., 1993 : Reactivity and Durability of Iron Oxide High Temperature Desulfurization Sorbents, Energy and Fuels, 7(5), pp. 632-638. DOI |
67 | Wild, P. J., Kiel, J. H. A. and Schenk, E., 1996 : Iron Oxide/Molybdenum Oxide Sorbents for High temperature Fuel Gas Desulfurization, In Proceedings of the 13th Annual International Pittsburgh Coal Conference, Pittsburgh, PA (United States). |
68 | Tseng, S. C. et al., 1981 : Kinetic studies on the reactions involved in the hot gas desulfurization using a regenerable iron oxide sorbent. II. Reactions of iron sulfide with oxygen and sulfur dioxide. Chemical Engineering Science, 36(8), pp. 1287-1294. DOI |
69 | Lee. H. P. et al., 2004 : A study on Reactivity of Iron-based Sorbents for Removal, J. of the Korean Industrial and Engineering Chemistry, 15(2), pp. 260-264. |
70 | Kim. H. T. 2001 : Development of -based desulfurization sorbents in Domestic, Department of Chemical Engineering, Hanyang University, pp. 1-9. |
71 | Ayala, R, E and March, D. W., 1991 : Characterization and Long-Range Reactivity of Zinc Ferrite in High-Temperature Desulfurization Processes, Industrial Engineering and Chemical Research, 30(1), pp. 55-60. DOI |
72 | Ayala, R. E. et al., 1995 : Advanced Low-Temperature Sorbent, Proceedings of the Advanced Coal Fired Power Systems' 1995 Review Meeting, Washington DC, pp. 407. |
73 | Kyotani, T. et al., 1989 : Removal of from hot gas in the presence of Cu-containing sorbents, Fuel, 68(1), pp. 74-79. DOI |
74 | Kyotani, T. et al., 1989 : High-Temperature Desulfurizing Reaction with Cu-Containing Sorbents, Environmental Science and Technology, 23(2), pp. 218-223. DOI |
75 | Song, Y. K. et al., 2001 : Desulfurization characteristics of sorbents. J. of the Korean Institute of Chemical Engineers, 18(5), pp. 635-639. DOI |
76 | Patrick. V. et al., 1997 : High-Temperature Sulfidation-Regeneration of Sorbents, Industrial Engineering and Chemical Research. 28(7), pp. 931-940. |
77 | Li. Z and Stephanopoulos, M. F., 1997 : Cu-Cr-O and Cu-Ce-O Regenerable Oxide Sorbents for Hot Gas Desulfurization, Industrial Engineering Chemical Resources, 36(1), pp. 187-196. DOI |
78 | Lee. K. B. et al., 1999 : Low-Temperature Desulfurizing Reaction with Cu-Containing Sorbents, J. of the Korean Institute of Chemical Engineers, 37(5), pp. 795-799. |
79 | Kang, M. P. et al., 2002 : Investigation of Reduction and Sulfurization Reactions for CuO-based Sorbents, J. of the Korean Institute of Chemical Engineers, 40(4), pp. 492-497. |
80 | Baek. C. S. et al., 2015 : A Review of Desulfurization Technology using Limestone in Circulating Fluidized Bed Boiler Type Power Plant, J. of the Korean Institute of Resources Recycling, 24(5), pp. 3-14. DOI |
81 | Kidd, D. R., 1992 : Nickel-promoted Absorbing Compositions for Selective Removal of Hydrogen Sulfide, U.S. Patent No. 5,094,996. |
82 | Kidd. D. R. et al., 1994 : Selective Removal of Hydrogen Sulfide over a Zinc Oxide and Silica Absorbing Composition, U.S. Patent No. 5,358,921. |
83 | Khare, G. P and Gass. B. W., 1995 : Fluidizable Sulfur Sorbent and Fluidized Sorption Process, U.S. Patent No. 5,439,867. |
84 | Kidd, D. R., 1991 : Selective Removal of Hydrogen Sulfide over a Nickel promoted Absorbing Composition, U.S. Patent No. 4,990,318. |
85 | Cal. M. P. et al., 2000 : High temperature hydrogen sulfide adsorption on activated carbon: 1. Effect of gas composition and metal addition, Carbon, 38(3), pp. 1757-1765. DOI |
86 | Lim, C, J. et al., 2000 : A Study of Advanced Zinc Titanate Sorbent for Mid-Temperature Desulfurization, J. of the Korean Institute of Chemical Engineers, 38(1), pp. 111-116. |
87 | Kang, S. C. et al., 2002 : The Characterization of Zn-based Desulfurization Sorbents on Various Supports, J. of the Korean Institute of Chemical Engineers, 40(3), pp. 289-297. |
88 | Nguyen-Thanh. D and Bandosz, J., 2005 : Activated carbons with metal containing bentonite binders as adsorbents of hydrogen sulfide, Carbon, 43(2), pp. 359-367. DOI |
89 | Sakanishi, K et al., 2005 : Simultaneous removal of and COS using activated carbons and their supported catalysts. Catalysis Today, 104(1), pp. 94-100. DOI |
90 | Zhang. X. et al., 2004 : Effect of pore structure and loaded metal catalyst on removal property of porous carbon, Part (1) : Influence of Ca catalyst on meso-port formation of activated carbon, Coal Conversion, 17(4), pp. 87-90. |
91 | Itaya, Y. et al., 2009 : Dry gas cleaning process by adsorption of into activated cokes in gasification of carbon resources, Fuel, 88(9), pp. 1665-1672. DOI |
92 | Sasaoka, E. et al., 1999 : Modification of High-Temperature Desulfurization Sorbent by Addition, Industrial Engineering Chemistry Research, 38(3), pp. 958-963. DOI |
93 | Jun. H. K et al., 2001 : A Study of Zn-Ti-Based Removal Sorbents Promoted with Cobalt Oxides, Industrial Engineering Chemistry Research, 40(16), pp. 3547-3556. DOI |
94 | Zhijiang, Li and Maria, F. S., 1997 : Cu-Cr-O and Cu-Ce-O Regenerable Oxide Sorbents for Hot Gas Desulfurization, Industrial Engineering Chemistry Research, 36(1), pp. 187-196. DOI |
95 | Jothimurugesan, K and Gangwal. S. K., 1998 : Regeneration of Zinc Titanate Sorbents, Industrial Engineering Chemistry Research, 37(5), pp. 1929-1933. DOI |
96 | Jung, Y, K et al., 2003 : Effect of additives on Zinc-based Desulfurization Sorbents for hot coal gas clean-up, Applied Chemistry, 7(1), pp. 169-172. |
97 | Lee, J. B., et al., 2001 : Binder Matrix Screening and Properties for Attrition Resistant Sorbents, J. of the Korean Society for Energy Engineering, Korea, Nov. 2011, pp.225-230. |
98 | Kim. H. T. et al., 2004 : Effect of Additives for the Removal of by Iron-based Sorbents, J. of the Korean Industrial and Engineering Chemistry, 15(4), pp. 407-416. |