Browse > Article
http://dx.doi.org/10.7584/ktappi.2015.47.4.030

Development of Hybrid Calcium Carbonate for High Loading Paper (I) - Manufacture and Application of Hybrid Calcium Carbonate -  

Jung, Jae Kwon (Dept. of Bio-based Materials, Chungnam National University)
Seo, Yung Bum (Dept. of Bio-based Materials, Chungnam National University)
Publication Information
Journal of Korea Technical Association of The Pulp and Paper Industry / v.47, no.4, 2015 , pp. 30-37 More about this Journal
Abstract
Needs for high ash loading in printing paper increase as green house gas (GHG) emission regulation becomes more stricter and pressure of lowering paper production cost increases. To meet the needs, a new type of filler was developed. The mixture of ground calcium carbonate (GCC) and calcium oxide was pre-floccuated with polyelectrolyte and further treated with carbon dioxide to form new calcium carbonate between GCCs. The final products were called as hybrid calcium carbonate (HCC), and its properties were compared to the GCC and the pre-flocculated GCC. Results showed increase in tensile, smoothness, opacity, and bulk for HCC.
Keywords
Calcium carbonate; high loaded paper; hydrid calcium carbonate; pre-flocculation; mechanical properties;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Baker, C. F. and Nazir, B. A., Practical ways forward to achieving higher filler content papers, Paper 5, Pira International Conference of Use of Minerals in Papermaking, Manchester, U.K., February (1997).
2 Dong, C., Song, D., and Patterson, T., Energy saving in papermaking through filler addition, Ind. Eng. Chem. Res. 47:8430-8435 (2008).   DOI
3 Zhao, Y., Kim, D., and White, D., Developing a new paradigm for linerboard fillers, Tappi J. 7(3):3-7 (2008).
4 Liimatainen H., Haapala A., and Niinimaki J., Retention of PCC and GCC fillers on chemical pulp fines surfaces, Tappi J. 39(9):38-42 (2009).
5 Zhao, Y. L., Hu, Z. S., Deng, Y., and Ragauskas, A., Improvement of paper properties using starch-modified precipitated calcium carbonate filler, Tappi J. 4(2):3-7 (2005).
6 Fan, H., Wang, D., Bai, W., and Liu, J., Starch-sodium stearate complex modified PCC filler and its application in papermaking, BioResources 7(3):3317-3326 (2012).
7 Yoon, S. Y. and Deng, Y. L., Clay-starch composite and their application in papermaking, Applied Polymer Science 100:1032-1038 (2006).   DOI
8 Yoon, S. Y. and Deng, Y. L., Starch-fatty complex modified filler for papermaking, Tappi J. 5(9):3-9 (2006).
9 Sang, Y. Z., McQuaid, M., and Englezos, P., Pre-flocculation of precipitated calcium carbonate filler by cationic starch for highly filled mechanical grade paper, BioResources 7(1):354-373 (2012).
10 Chauhan, V. S. and Bhardwaj, N. K., Effect of particle size and preflocculation of talc filler on sizing characteristics of paper, APPITA J. 66(1):66-72 (2013).
11 Seo, D., Im, W. H., Youn, H. J., and Lee, H. L., The effect of process variables for GCC pre-flocculation on floc and handsheet properties, Nordic Pulp Pap. Res. J. 27 (2):382-387 (2012).   DOI
12 Sang, Y. and Xiao, H. J., Clay flocculation improved by cationic poly (vinyl alcohol)/anionic polymer dual-component system, Colloids Interface Sci. 326:420-425 (2008).   DOI
13 Saghavaz, K. M., Resalati, H., and Mehrabi, E., Characterization of cellulose-PCC composite filler synthesized from CMC and BSKP fibrils by hydrolysis of ammonium carbonate, Powder Technol. 246:93-97 (2013).   DOI
14 Subramanian, R., Fordsmand, H., Paltakari, J., and Paulapuro, H., A new composite fine paper with high filler loading and functional cellulosic microfines, J. Pulp Pap. Sci. 34(3):146-152 (2008).
15 Silenius, P., Improving the combinations of critical properties and process parameters of printing and writing papers and paperboards by new paper-filling methods, Ph.D. Thesis, Helsinki University of Technology, Laboratory of Paper Technology, Reports, Series A 14 (2002).
16 Kim, J. J., Ahn, J. W., Lee, M. W., Lee, J. K., and Seo, Y. B., Improving recycled fibres in printing paper by application of an in-situ $CaCO_3$ formation method, I. Process effects, APPITA J. 65(4):347-351 (2012).
17 Seo, Y. B., Lee, Y. H., and Chung, J. K., The improvement of recycled newsprint properties by in-situ $CaCO_3$ loading, BioResources 9(4):6254-6266 (2014).
18 Kim, J. J., Ahn, J. W., Lee, M. W., Lee, J. K., and Seo, Y.B., Improving recycled fibres in printing paper by application of an in-situ $CaCO_3$ formation method, 2. Paper properties, APPITA J. 66(1):54-58 (2013).
19 Seo, Y. B., Chung, J. K., and Lee, Y. H., Korea patent registered No. 10-1510313 (2015).