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http://dx.doi.org/10.7584/ktappi.2013.45.2.021

Conversion of Fructose to 5-HMF(5-hydroxymethylfurfural) in DMSO(dimethylsulfoxide) solvent  

Sung, Yong Joo (Dept. of Biobased Materials, College of Agriculture and Life Science, Chungnam Nat'l Univ.)
Park, Chong-Jin (Samyang Genex Corp. Samyang Group Food R&D Center)
Kim, Byung-Ro (Department of Wood and Paper Science, Chungbuk National University)
Shin, Soo-Jeong (Department of Wood and Paper Science, Chungbuk National University)
Publication Information
Journal of Korea Technical Association of The Pulp and Paper Industry / v.45, no.2, 2013 , pp. 21-26 More about this Journal
Abstract
Conversion of fructose to 5-hydroxymethylfurfural (5-HMF) was investigated in dimethylsulfoxide (DMSO) solvent with increasing reaction temperatures and impact of residual water from dehydration reaction byproduct. To convert fructose to 5-HMF, increasing reaction temperature led more conversion to 5-HMF than lower temperature at the range of $120-150^{\circ}C$ in DMSO solvent. DMSO engaged in the acid-catalyzed dehydration and rearrangement reaction as acid and solvent. Increasing temperature led to more furanose structure than pyranose at the range of $30-80^{\circ}C$. Formed 5-HMF could be degraded to levulinic and formic acid at the presence of acid and water. Removal of water in reaction medium could prevent 5-HMF degradation.
Keywords
fructose; dimethylsulfoxide; 5-hydroxymethylfurfural; levulinic acid; formic acid;
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Times Cited By KSCI : 3  (Citation Analysis)
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