Browse > Article
http://dx.doi.org/10.22807/KJMP.2022.35.3.367

Changes in the Linear Compressibility and Bulk Modulus of Natural Stilbite Under Pressure with Varying Pressure-Transmitting Media  

Hwang, Huijeong (School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology)
Lee, Hyunseung (Department of Geological Sciences, Pusan National University)
Lee, Soojin (Department of Geological Sciences, Pusan National University)
Jung, Jaewoo (Global Ocean Research Center, Korea Institute of Ocean Science & Technology)
Lee, Yongmoon (Department of Geological Sciences, Pusan National University)
Publication Information
Korean Journal of Mineralogy and Petrology / v.35, no.3, 2022 , pp. 367-376 More about this Journal
Abstract
This study is a preliminary step to understand the reaction between various liquids and zeolite in the subduction zone environment. Stilbite, NaCa4(Al9Si27)O72·28(H2O), was selected and high pressure study was conducted on compressional behavior by the pressure-transmitting medium (PTM). Water and NaHCO3 solution that can exist in the subduction zone was used as PTM, and samples were pressurized from ambient to a maximum of 2.5 GPa. Below 1.0 GPa, both experiments show a low linear compressibility in the range of 0.001 to 0.004 GPa-1 and a high bulk modulus of 220(1) GPa. This is presumably because the structure of the stilbite becomes very dense due to insertion of water molecules or cations into the channel. On the other hand, at 1.0 GPa or higher, the trends of the two experiments are different. In the water run, the linear compressibility of the c-axis is increased to 0.006(1) GPa-1. In the NaHCO3 run, the linear compressibility of the b- and c-axis is increased to 0.006(1) GPa-1. The bulk modulus after 1.0 GPa shows values of 40(1) and 52(7) GPa in water and NaHCO3 run, respectively, confirming that stilbite becomes more compressible than that before 1.0 GPa. It is caused by the migration of cations and water molecules inside the channel, as the water molecules in the PTM start to freeze and stop to insert toward the channel at 1.0 GPa or more. In the NaHCO3 run, it is assumed that the distribution of extra-framework species inside the structure is changed by substitution of the Na+ cation. It can be expected from tendency of the relative intensity ratio of the (001) and (020) peaks which show a different from that of the water run.
Keywords
Stilbite; Pressure-transmitting medium; X-ray diffraction; Linear compressibility; Bulk modulus;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Abers, G.A., van Keken, P.E., Kneller, E.A., Ferris, A. and Stachnik, J.C., 2006, The thermal structure of subduction zones constrained by seismic imaging: Implications for slab dehydration and wedge flow. Earth and Planetary Science Letters, 241(3), 387-397.   DOI
2 Akizuki, M. and Konno, H., 1985, Order-disorder structure and the internal texture of stilbite. American Mineralogist, 70(7-8), 814-821.
3 Angel, R.J., Alvaro, M., and Gonzalez-Platas, J., 2014, EosFit7c and a Fortran module (library) for equation of state calculations. Zeitschrift fur Kristallographie - Crystalline Materials, 229(5), 405-419.   DOI
4 Hwang, H., Seoung, D., Lee, Y., Liu, Z., Liermann, H.-P., Cynn, H., Vogt, T., Kao, C.-C. and Mao, H.-K., 2017, A role for subducted super-hydrated kaolinite in Earth's deep water cycle. Nature Geoscience, 10(12), 947-953.   DOI
5 Le Bail, A., Duroy, H. and Fourquet, J.L., 1988, Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction. Materials Research Bulletin, 23(3), 447-452.   DOI
6 Mao, H.K., Xu, J. and Bell, P.M., 1986, Calibration of the Ruby Pressure Gauge to 800-Kbar Under Quasi-hydrostatic Conditions. Journal of Geophysical Research-Solid Earth and Planets, 91(B5), 4673-4676.   DOI
7 Prescher, C., and Prakapenka, V.B., 2015, DIOPTAS: a program for reduction of two-dimensional X-ray diffraction data and data exploration. High Pressure Research, 35(3), 223-230.   DOI
8 Seryotkin, Y.V., Dementiev, S.N. and Likhacheva, A.Y., 2021, Crystal-fluid interaction: the evolution of stilbite structure at high pressure. Physics and Chemistry of Minerals, 48, 1-11.   DOI
9 Slaughter, M., 1970, Crystal structure of stilbite. American Mineralogist: Journal of Earth and Planetary Materials, 55(3-4_Part_1), 387-397.
10 Yun, S., Hwang, H., Hwang, G., Kim, Y., Blom, D., Vogt, T., Post, J.E., Jeon, T.-Y., Shin, T.J., Zhang, D.-Z., Kagi, H. and Lee, Y., 2022, Super-hydration and reduction of manganese oxide minerals at shallow terrestrial depths. Nature Communications, 13(1), 1942.   DOI
11 Hermann, J. and Spandler, C.J., 2007, Sediment Melts at Sub-arc Depths: an Experimental Study. Journal of Petrology, 49(4), 717-740.   DOI
12 Mei, S. and Kohlstedt, D.L., 2000b, Influence of water on plastic deformation of olivine aggregates: 2. Dislocation creep regime. Journal of Geophysical Research: Solid Earth, 105(B9), 21471-21481.   DOI
13 Akizuki, M., Kudoh, Y. and Satoh, Y., 1993, Crystal structure of the orthorhombic [001] growth sector of stilbite. European Journal of Mineralogy, 5(5), 839-843.   DOI
14 Sharp, J.D. and Byrne, R.H., 2019, Carbonate ion concentrations in seawater: Spectrophotometric determination at ambient temperatures and evaluation of propagated calculation uncertainties. Marine Chemistry, 209, 70-80.   DOI
15 Ryan, J.G., and Chauvel, C., 2014, 3.13 - The SubductionZone Filter and the Impact of Recycled Materials on the Evolution of the Mantle. In H.D. Holland, and K.K. Turekian, Eds. Treatise on Geochemistry (Second Edition), p. 479-508. Elsevier, Oxford.
16 Toby, B.H., 2001, EXPGUI, a graphical user interface for GSAS. Journal of Applied Crystallography, 34(2), 210-213.   DOI
17 Zheng, Y.-F. and Hermann, J., 2014, Geochemistry of continental subduction-zone fluids. Earth, Planets and Space, 66(1), 93.   DOI
18 Birch, F., 1947, Finite Elastic Strain of Cubic Crystals. Physical Review, 71(11), 809-824.   DOI
19 Bridgman, P.W., 1912, Water, in the Liquid and Five Solid Forms, under Pressure. Proceedings of the American Academy of Arts and Sciences, 47(13), 441-558.
20 Cruciani, G., Artioli, G., Gualtieri, A., Stahl, K. and Hanson, J.C., 1997, Dehydration dynamics of stilbite using synchrotron X-ray powder diffraction. American Mineralogist, 82(7-8), 729-739.   DOI
21 Karato, S.-I. and Jung, H., 2003, Effects of pressure on hightemperature dislocation creep in olivine. Philosophical Magazine, 83(3), 401-414.   DOI
22 Lebow, S.T., Foster, D.O. and Lebow, P.K., 1999, Release of copper, chromium, and arsenic from treated southern pine exposed in seawater and freshwater. Forest Products Journal, 49, 80-89.
23 Mei, S. and Kohlstedt, D.L., 2000a, Influence of water on plastic deformation of olivine aggregates: 1. Diffusion creep regime. Journal of Geophysical Research: Solid Earth, 105(B9), 21457-21469.   DOI
24 Murnaghan, F.D., 1944, The Compressibility of Media under Extreme Pressures. Proceedings of the National Academy of Sciences, 30(9), 244-247.   DOI