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http://dx.doi.org/10.22807/KJMP.2021.34.2.95

Mineral Phase Transitions of Jarosite Substituted by Oxyanions during the Reductive Dissolution Using Oxalate Solution  

Lee, Myoungsin (School of Earth System Sciences, Kyungpook National University)
Lee, Dongho (School of Earth System Sciences, Kyungpook National University)
Chun, Herin (School of Earth System Sciences, Kyungpook National University)
Kim, Yeongkyoo (School of Earth System Sciences, Kyungpook National University)
Baek, YoungDoo (Department of Biomedical Laboratory Science, Daegu Health College)
Publication Information
Korean Journal of Mineralogy and Petrology / v.34, no.2, 2021 , pp. 95-106 More about this Journal
Abstract
The SO4 in the jarosite structure can be substituted by other oxyanions, and therefore, the transition of jarosite to goethite plays a very important role in controlling the behavior of oxyanions. In this study, the phase change according to the species of the oxyanion in jarosite and the related behavior of the oxyanion was studied by mineralogical and geochemical methods when jarosite, which is coprecipitated with various oxynions, undergoes a phase change by a reductive dissolution. Jarosite substituted by five oxyanions by 5 mol% was used in this study. The mineral phase change induced by reductive dissolution using ammonium oxalate was investigated, and the order of phase transition rate of jarosite to goethite was MoO4-jarosite ≥ SeO4-jarosite ≥ CrO4-jarosite > pure jarosite > SeO3-jarosite > AsO4-jarosite, showing that the transition rates vary depending on the substituted oxyanion. The resultant concentration of the leached Fe was slightly different depending on the type of oxyanion and time but did not show a noticeable difference. The concentration of each oxyanion leached according to the change of the mineral phase showed that the order of concentration of oxyanions was Mo > Se(SeO3) > As > Se(SeO4) > Cr in general, and showed a slight increase with time. This trend was related to the species of oxyanions rather than mineral phase change. The results of this study showed that the phase transition of jarosite to goethite was affected by the species of oxyanions, but this tendency did not affect the concentrations leached oxyanions.
Keywords
Jarosite; Oxyanion; Acid mine drainage; Goethite; Phase transition;
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