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http://dx.doi.org/10.22807/KJMP.2020.33.3.185

Transformation Characteristics of Calcined Oyster Shell to Liquid Lime  

Ha, Su Hyeon (School of Earth System Sciences, Kyungpook National University)
Kim, Yeongkyoo (School of Earth System Sciences, Kyungpook National University)
Publication Information
Korean Journal of Mineralogy and Petrology / v.33, no.3, 2020 , pp. 185-193 More about this Journal
Abstract
There have been many studies on the calcination of oyster shells in the perspective of recycling of resources. The quicklime made by the calcination of oyster shells is used either as it is or after reacting with water to transform to liquid lime before being used. However, the liquid lime made from calcined oyster shells show slightly different properties from that of limestone. In this study, to compare these properties of oyster shell with those of limestone, the samples were calcined and reacted with water at various temperatures to transform to a liquid lime and filtered using 150 ㎛ sieves to calculate the transform rate to liquid lime. The calcined limestone was transformed to liquid lime at all temperatures, but calcined oyster shell did not show any transformation at 30℃ and 50℃ under the experimental conditions of this study, and rather increased the weight for the remaining after filtration due to the presence of Ca(OH)2 produced by the reaction with water, Even at 90℃, the transformation rate of calcined oyster shell to liquid lime was lower than that of limestone. This difference in oyster shell can be explained partly by the preventing calcined one from reacting with water by conchiolin which is protein found in the prismatic and pearl layers of oyster shell. Conchiolin is also known to be stable and does not decompose even at high temperature. However, even the calcined chalk layer without conchiolin shows lower transformation rate than that of calcined limestone, probably due to the small amount of Na in oyster shell, which may cause additional reaction including eutectic melt during calcination process.
Keywords
Oyster shell; calcination; liquid lime; limestone;
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Times Cited By KSCI : 4  (Citation Analysis)
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1 Castilho, S., Kiennemann, A., Pereira, M.F.C. and Dias, A.P.S., 2013. Sorbent for $CO_2$ capture from biogenesis calcium wastes. Chemical Engineering Journal, 226, 146-153.   DOI
2 Carter, J.G., 1980, Environmental and biological controls of bivalve shell mineralogy and microstructure. In Skeletal Growth of Aquatic Organisms (eds. Rhoads, D.C. and Lutz, R.A.) Plenum Press, New York, 69-113.
3 Carter, J.G. and Clark II, G.R., 1985, Classification andphylogenetic significance of molluscan shell microstructure. In Studies in Geology, Notes for a Short Course (Mollusks) (eds. Bottjer, D.J., Hickman, C.S., Ward, P.D. and Broadhead, T.W.) University of Tenessee, 50-71.
4 Chen, L., Wang, C., Wang, Z. and Anthony, E.J., 2017, The kinetics and pore structure of sorbents during the simultaneous calcination/sulfation of limestone in CFB. Fuel, 208, 203-213.   DOI
5 Dauphin, Y., Cuif, J.-P. and Massard, P., 2006, Persistent organic components in heated coral aragonitic skeletons- Implications for palaeoenvironmental reconstructions. Chemical Geology, 231, 26-37.   DOI
6 De D ieg o, L .F., d e las Obras-Loscertales, M ., G arcía-Labiano, F., Rufas, A., Abad, A. Gayan, P. and Adanez, J., 2011. Chracterization of a limestone in a batch fluidized bed reactor for sulfur retention under oxy-fuel operating conditions. Internatioanl Journal of Greenhouse Gas Control, 5 1190-1198.   DOI
7 Garcia-Carmona, J., Morales, J.G. and Clemente, R.R., 2003, Morphological control of precipitated calcite obtained by adjusting the electrical conductivity in the $Ca(OH)_2-H_2O-CO_2$ system. Journal of Crystal Growth, 249, 561-571.   DOI
8 Gregoire, C., 1968, Experimental alteration of the Nautilus shell by factors involved in diagenesis and metamorphism: Pt I. Thermal changes in conchiolin matrix of mother-of-pearl. Bulletin De L'Institut Royal Des Sciences Naturelles De Belgique, 44, 1-69.
9 Gregoire, C. and Laurent, R., 1972, Alterations in conchiolin matrices of mother-of-pearl during conversion of aragonite into calcite under experimental conditions of pyrolysis and pressure. Biomineralization, 6, 70-83.
10 Gregoire, C., 1972, Experimental alteration of the Nautilus shell by factors involved in diagenesis and in metamorphism: Pt 3. Thermal and hydrothermal changes in the organic and mineral components of the mural mother-ofpearl. Bulletin De L'Institut Royal Des Sciences Naturelles De Belgique, 48, 1-85.
11 Gregoire, C. and Voss-Foucart, M.F., 1970, Proteins in shells of fossil Cephalopods (Nautiloids and Ammonoids) and experimental simulation of their alterations. Archives Internationales de Physiologie, de Biochimie et de Biophysique (Liege), 78, 191-203.
12 Ha, S.H., Cha, M.K., Kim, K., Kim, S.-H. and Kim, Y., 2017, Mineralogical and chemical characteristics of the oyster shells from Korea. Journal of the Mineralogical Society of Korea, 30, 149-159.   DOI
13 Ha, S.H., Kim, K., Kim, S.-H. and Kim, Y., 2019a, The effects of marine sediments and NaCl as impurities on the calcination of oyster shells. Economic and Environmental Geology, 52, 223-230.   DOI
14 Ha, S.H., Lee, J.W., Choi, S.-H., Kim, S.-H., Kim, K. and Kim, Y., 2019b, Calcination chracteristics of oyster shells and their comparison with limestone from the perspective of waste recycling. Journal of Material Cycles and Waste Management, 21, 1075-1084.   DOI
15 Lee, C.H., Lee, D.K., Ali, M.A. and Kim, P.J., 2008. Effects of oyster shell on soil chemical and biological properties and cabbage productivity as a liming materials. Waste Management, 28, 2702-2708.   DOI
16 Higuera, R.R. and Elorza, J., 2009, Biometric, microstructural, and high-resolution trace element studies in Crassostrea gigas of Cantabria (Bay of Biscay, Spain): Anthropogenic and seasonal influences. Estuarine, Coastal and Shelf Science. 82, 201-212.   DOI
17 Hsu, T.C., 2009, Experimental assessment of adsorption of $Cu^{2+}\;and\;Ni^{2+}$ from aqueous solution by oyster shell powder. Journal of Hazardous Materials, 171, 995-1000.   DOI
18 Kim, S.-H., Hong, B.-U., Lee, J.-W., Cha, W.-S., Kim, K. and Moon, B.-K., 2019, Evaluation of $SO_2$ absorption efficiency for calcined oyster shell slurry using a simulated spray type-flue gas desulfurization (FGD) system: A comparative study with limestone slurry. Economic and Envionmental Geology, 52, 119-128.
19 Kouzu, M., Kajita, A. and Fujimori, A., 2016, Catalytic activity of calcined scallop shell for rapeseed oil transesterification to produce biodiesel. Fuel, 182, 220-226.   DOI
20 Laursen, K., Grace, J.R., and Lim, C.J., 2001, Enhancement of the sulfur capture capacity of limestones by the addition of $Na_2CO_3$ and NaCl. Environmental Science & Technology, 35, 4384-4389.   DOI
21 Lee, J.W., Choi, S.-H., Kim, S.-H., Cha, W.S., Kim, K. and Moon, B.-K., 2019. Mineralogical changes of oyster shells by calcination: A comparative study with limestone. Economic and Environmental Geology, 51, 485-492.   DOI
22 Matalkah, F., Bharadwaj, H., Balachandra, A.M. and Soroushian, P., 2017, Development and Characterization of Gypsum-Based Binder. European Journal of Advances in Engineering and Technology, 4, 153-157.
23 Ma, K.W. and Teng, H., 2009. CaO powders from oyster shells for efficient $CO_2$ capture in multiple carbonation cycles. Journal of American Ceramic Society, 93, 221-227.   DOI
24 Ok, Y.S., Oh, S.E., Ahmad, M., Hyun, S., Kim, K.R., Moon, D.H., Lee, S.S., Lim, K.J., Jeon, W.T. and Yang, J.E., 2010, Effects of natural and calcined oyster shells on Cd and Pb immobilization in contaminated soils. Environmental Earth Sciences, 61, 1301-1308.   DOI
25 Moropoulou, A., Bakolas, A. and Aggelakopoulou, E., 2001, The effects of limestone characteristics and calcination temperature to the reactivity of the quicklime. Cement and Concrete Research, 31, 633-639.   DOI
26 Mymrin, V.A., Alekseev, K.P., Catai, R.E., Izzo, R.L.S., Rose, J.L., Nagalli, A. and Romano, C.A., 2015, Construction material from construction and demolition debris and lime production wastes. Construction and Building Materials, 79, 207-213.   DOI
27 Odoemelam, S.A. and Eddy, N.O., 2009, Studies on the Use of Oyster, Snail and Periwinkle Shells as Adsorbents for the Removal of $Pb^{2+}$ from Aqueous Solution, E-Journal of Chemistry. 6, 213-222.   DOI
28 Rochelle, C.A., Czernichowski-Lauriol, I. and Milodowski, A.E., 2004, The impact of chemical reactions on $CO_2$ storage in geological formations: A brief review. Geological Society London Special Publications, 233, 87-1060   DOI
29 Salvador, C., Lu, D., Anthony, E.J. and Abanades, J.C., 2003, Enhancement of CaO for $CO_2$ capture in an FBC environment. Chemical Engineering Journal, 96, 197-195.   DOI
30 Moon, D.H., Kim, K.W., Yoon, I.H., Grubb, D.G., Shin, D.Y., Cheong, K.H., Choi, H.I., Ok, Y.S. and Park, J.H., 2011. Stabilization of arsenic-contaminated mine tailings using natural and calcined oyster shells. Environmental Earth Sciences, 64, 597-605.   DOI
31 Voss-Foucart, M.F. and Gregoire, C., 1973, Experimental alteration of the Nautilus shell by factors of diagenesis and metamorphism: Part II. Amino acid patterns in the conchiolin matrix of the pyrolysed modern mother-ofpearl. Bulletin De L'Institut Royal Des Sciences Naturelles De Belgique, 49, 1-13.
32 Scala, F., Chirone, R., Meloni, P., Carcangju, G., Manca, M., Mulas, G. and Mulas, A., 2013. Fluidized bed desulfurization using lime obtained after slow calcination of limestone particles. Fuel, 114, 99-105.   DOI
33 Shearer, J.A., Johnson, I. and Turner, C.B., 1979, Effects of sodium chloride on limestone calcunation and sulfation in fluidized-bed combustion. Environmental Science & Technology, 13, 1113-1118.   DOI
34 Stanmore, B.R. and Gilot, P., 2005. Review-calcination and carbonation of limestone during thermal cycling for $CO_2$ sequestration. Fuel Processing Technology, 86, 1707-1743.   DOI
35 Wu, Y., Wang, C., Tan, Y., Jia, L. and Anthony, E.J., 2011, Characterization of ashes from a 100kWth pilot-scale circulating fluidized bed with oxy-fuel combustion. Applied Energy, 88, 2940-2948.   DOI
36 Zhang, Z.S., Lian, F., Ma, L.J. and Jiang, Y.S., 2015, Effects of quicklime and iron tailings as modifier on composition and properties of steel slag. Journal of Iron and Steel Research International, 22, 15-20.   DOI
37 Cao, X., Dermatas, D., Xuanfeng, X. and Shen, G., 2008, Immobilization of lead in shooting range soils by means of cement, quicklime, and phosphate amendments. Environmental Science and Pollution Research, 15, 120-127.   DOI
38 Alidoust, D., Kawahigashi, M., Yoshizawa, S., Sumida, H. and Watanabe, M., 2015, Mechanism of cadmium biosorption from aqueous solutions using calcined oyster shells. Journal of Environmental Management, 150, 103-110.   DOI
39 Ar, I. and Dogu, G., 2001, Calcination kinetics of high purity limestones. Chemical Engineering Journal, 83, 131-137.   DOI