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http://dx.doi.org/10.5764/TCF.2021.33.3.141

Correlation between Volume and Pressure of Dichloromethane using Equation of State  

Kwon, Woong (Department of Textile System Engineering, Kyungpook National University)
Kim, Jiyun (Department of Textile System Engineering, Kyungpook National University)
Lee, Kwonyun (Department of Textile System Engineering, Kyungpook National University)
Jeong, Euigyung (Department of Textile System Engineering, Kyungpook National University)
Publication Information
Textile Coloration and Finishing / v.33, no.3, 2021 , pp. 141-146 More about this Journal
Abstract
Supercritical fluid has excellent dissolving power for various materials based on low viscosity and high diffusion coefficient and is used as solvents in various chemical processes. However, its industrial application can be very tricky because the design, especially the size of the supercritical apparatus, should be carefully chosen to optimize the cost and the production of supercritical fluidic state. And the first step of the supercritical fluid apparatus design is to choose the appropriate size of the reactor vessel to produce supercritical fluid above its critical pressure and temperature. Therefore, this study aims to analyze thermodynamic behaviors of dichloromethane based on ideal gas, van der Waals, Redlich-Kwong, Soave-Redlich-Kwong, and Peng-Robinson equations of state. The correlation between the volume and pressure of dichloromethane at 200℃ was revealed and it can be used to design the optimized size of the supercritical apparatus for industrial production.
Keywords
supercritical fluid; dichloromethane; equation of state; Peng-Robinson equation; maxwell construction;
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