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http://dx.doi.org/10.5764/TCF.2019.31.3.165

Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide  

Park, Ji-Hyeon (Department of Organic Material Science and Engineering, Pusan National University)
Park, Jong-Seung (Department of Organic Material Science and Engineering, Pusan National University)
Choi, Pil-Jun (Korea Institute of Footwear and Leather Technology)
Ko, Jae-Wang (Korea Institute of Footwear and Leather Technology)
Lee, Jae-Yeon (Korea Institute of Footwear and Leather Technology)
Sur, Suk-Hun (Korea Institute of Footwear and Leather Technology)
Publication Information
Textile Coloration and Finishing / v.31, no.3, 2019 , pp. 165-176 More about this Journal
Abstract
Polyurethane-ureas(PUUs) were prepared from 4,4'-methylenebis(cyclohexyl isocyanate) and various diols including isosorbide. Isosorbide is starch-derived monomer that exhibit a wide range of glass transition temperature and are therefore able to be used in many applications. PUU was synthesized by a pre-polymer polymerization using a catalyst. Successful synthesis of the PUU was characterized by fourier transform-infrared spectroscopy. Thermal properties were determined by differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. It was found that by tuning isosorbide content in the resin, their glass transition temperature(Tg) slightly decreased. Physical properties were also determined by tensile strength and X-ray diffraction. There is no significant differences between petroleum-derived diol and isosorbide in XRD analysis. Moreover, their physical and optical properties were determined. The result showed that the poly(tetramethylene ether glycol)/isosorbide-based PUU exhibited enhanced tensile strength, transmittance, transparency and biodegradability compared to the existing diols. After 11 weeks composting, the biodegradability of blends increased in ISB-PUU. The morphology of the fractured surface of blend films were investigated by scanning electron microscopy.
Keywords
isosorbide; polyurethane; biopolymer; biodegradability; coating;
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