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http://dx.doi.org/10.5764/TCF.2015.27.4.340

Study on the Interaction between Curcumin and Ethylamines by Absorption and Fluorescence Spectroscopic Techniques  

Kim, Sung Hoon (Department of Textile System Engineering, Kyungpook National University)
Gwon, Seon Yeong (Department of Textile System Engineering, Kyungpook National University)
Lee, Eun-Mi (FITI Testing and Research Institute)
Bae, Jin-Seok (Department of Textile System Engineering, Kyungpook National University)
Publication Information
Textile Coloration and Finishing / v.27, no.4, 2015 , pp. 340-344 More about this Journal
Abstract
The interaction between curcumin(1,7-bis[4-hydroxy-3-methoxyphenyl]-1,6-heptadiene-3,5-dione) and ethylamines was studied in DMSO:$H_2O$(5:1, v/v) using absorption and fluorescence measurements. The association constant, $K_{ass}$, and the Stern-Volmer constants were calculated by the Benesi-Hildebrand and Stern-Volmer equation, respectively. Curcumin displayed marked UV-Vis absorption changes and highly responsive fluorescence quenching in the presence of ethylamine and the quenching ability was enhanced almost linearly with the concentration of ethylamines. The apparent Stern-Volmer constant measured for the ethylamine-curcumin system was about 1000-fold greater than that of the triethylamine-curcumin system, indicating considerably greater quenching efficiency of ethylamines.
Keywords
curcumin; ethylamines; Benesi-Hildebrand; Stern-Volmer; fluorescence; absorption;
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