Browse > Article
http://dx.doi.org/10.5764/TCF.2013.25.1.1

Characteristics of HOMO and LUMO Energy Potentials toward Rhodamine 6G-Naphthaldehyde Chemosensor  

Kim, Hyungjoo (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
Lee, Do-Hyun (Korea Dyeing Technology Center)
Son, Young-A (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
Publication Information
Textile Coloration and Finishing / v.25, no.1, 2013 , pp. 1-6 More about this Journal
Abstract
Nowdays, the computational simulation of molecular energy potentials and the empirical evidence using electrochemical reduction/oxidation values are very significant factors to predict of molecule's energy potentials. The prepared chemosensor herein consists of spirolactam ring system in the structure, providing intra-structural change with metal cation binding. In this study, rhodamine 6G-Naphthaldehyde chemosensor was determined and compared with HOMO/LUMO energy levels by computational calculation and cyclic voltammogram method.
Keywords
chemosensor; HOMO; LUMO; Rhodamine 6G; naphthaldehyde; cyclicvoltammogram; absorption; electron distribution;
Citations & Related Records
Times Cited By KSCI : 4  (Citation Analysis)
연도 인용수 순위
1 Y. S. Kim, J. I. Shin, S. Y. Park, K. Jun, and Y. A. Son, Electrochemical Studies on Heptamethine Cyanine Dyes, Textile Coloration and Finishing(J. Korean Soc. Dye. and Finish.), 21(5), 35(2009).   과학기술학회마을   DOI   ScienceOn
2 Y. S. Kim, S. H. Kim, T. K. Kim, and Y. A. Son, Characteristics of HOMO and LUMO Potentials by Altering Substituents: Computational and Electrochemical Determination, Textile Coloration and Finishing(J. Korean Soc. Dye. and Finish.), 20(5), 41(2008).   과학기술학회마을   DOI   ScienceOn
3 G. B. Ferreira, E. Hollauer, N. M. Comerlato, and J. Wardell, An Experimental and Theoretical Study of the Electronic Spectra of Tetraethylammonium [bis(1,-dthiole-2-thione-45-2-thione-45-ditho ato)M(III)] and Tetraethylammonium [bis(1,3-dithiole- 2-e-4,5-dithilato)M(III)] (M = Sb or Bi), Spectrochim. Acta Part A, 71(1), 215(008).   DOI   ScienceOn
4 C. N. Ramachadran, D. Roy, and N. Sathyamurthy, Host-Guest Interaction in Endohedral Fullerenes, Chem. Physic. Lett., 461, 87(2008).   DOI   ScienceOn
5 I. Losito, F. Palmisano, and P. G. Zambonin, O-Phenylenediamine Electropolymerization by Cyclic Voltammetry Combined Ectrospray Ioization-Ion Tap Mass Spectrometry, Anal. Chem., 75(19), 4988 (2003).   DOI   ScienceOn
6 C. J. Tonzola, M. M. Alam, W. Kainsky, and S. A. Jenekhe, New n-Type Organic Semiconductors: Synthesis, Single Crystal Structures, Cyclic Voltammetry, Photophysics, Electron Transport, and Electroluminescence of Series of Diphenylanthrazolines, J. Am. Chem. Soc., 125(44), 13548(2003).   DOI   ScienceOn
7 H. Kim and Y. A. Son, Synthesis and Optical Properties of Novel Chemosensor Based on Rhodamine 6G, Textile Coloration and Finishing(J. Korean Soc. Dye. and Finish.), 24(4), 233(2012).   과학기술학회마을   DOI   ScienceOn
8 S. P. Wu, T. H. Wang, and S. R. Liu, A Highly Selective Turn-On Fluorescent Chemosensor for Copper(II) Ion, Tetrahedron, 66(51), 9655(2010).   DOI   ScienceOn
9 M. Beija, C. A. Afonso, and J. M. Martinho, Synthesis and Applications of Rhodamine Derivatives as Fluorescent Probes, Chem. Soc. Rev., 38(8), 2410(2009).   DOI   ScienceOn
10 W. Y. Kang and J. S. Park, Preparation of Polymeric Metal Complex Containing Azo Dye Rotaxane, Textile Coloration and Finishing(J. Korean Soc. Dye. and Finish.), 23(3), 163(2011).   과학기술학회마을   DOI   ScienceOn
11 L. Huang, X. Wang, G. Xie, P. Xi, Z. Li, M. Xu, Y. Wu, D. Bai, and Z. Zeng, A New Rhodamine- Based Chemosensor $Cu^{2+}$ and The Study of Its Behaviour in Living Cells, Dalton Trans., 39(34), 7894(2010).   DOI   ScienceOn
12 D. Wu, W. Huang, C. Duan, Z. Lin, and Q. Meng, Highly Sensitive Fluorescent Probe or Selective Detection of $Hg^{2+}$ in DMF Aqueous Media, Inorg. Chem., 46(5), 1538(2007).   DOI   ScienceOn
13 X. Chen, T. Pradhan, F. Wang, J. S. Kim, and J. Yoon, Fluorescent Chemosensors Based on Spiroring-Opening of Xanthenes and Related Derivatives, Chem. Rev., 112(3), 1910(2012).   DOI   ScienceOn
14 M. Dong, T. H. Ma, A. Zhang, Y. M. Dong, Y. W. Wang, and Y. Peng, A Series of Highly Sensitive and Selective Fluorescent and Colorimetric "Off- On" Chemosensors for Cu(II) Based on Rhodamine Derivatives, Dyes and Pigments, 87(2), 164 (2010).   DOI   ScienceOn
15 G. H. Wu, D. X. Wang, D. Y. Wu, Y. Gao, and Z. Q. Wang, Highly Sensitive Optical Chemosensor for the Detection of $Cu^{2+}$ Using a Rhodamine B Spirolatam, J. Chem. Sci., 121(4), 543 (2008).
16 H. S. Lee and J. H. Kim, Measurement of Physical Properties of Conducting Polymers, Polymer Sci. Technol, 18, 488(2007).