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Preparation and Application of Microcapsule - Preparation and Properties of Suspension-Polymerized Poly(vinyl alcohol) Microsphere with Core-Shell Structure -  

김혜인 (부산대학교 섬유공학과)
김효정 (부산대학교 섬유공학과)
박수민 (부산대학교 섬유공학과)
Publication Information
Textile Coloration and Finishing / v.15, no.4, 2003 , pp. 65-72 More about this Journal
Abstract
Poly(ethylene-co-vinylacetate) (EVA) microspheres were prepared by a thermally induced phase separation. Poly(vinyl Alcohol) (EVAL) microsphere with Core-Shell Structure were synthesized by a saponification on sheath of EVA microspheres. The size of EVA core/EVAL shell microsphere was decreased from $4.09\mu{m}\;to\;2.55\mu{m}$ by partial saponification of $NaOH/Na_2SO_4$/methanol(2 : 1 : 1 by weight) at $60^\circ{C}$ for 4h to produce a saponified surface layer of about 60% of original radius. In this process, the surface layer of EVAL microsphere was dissolved partially and morphology of surface was not showed. Add-on of cotton and silk printed with EVA core/EVAL shell microsphere was increased and that of printed PET was decreased. In case of EVA core/EVAL shell microsphere, Hand of cotton and silk printed was flexible and fullness.
Keywords
Microcapsule; Microsphere; Core-Shell Structure; EVA; EVAL;
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