The corrosion of aluminium alloy and release of intermetallic particles in nuclear reactor emergency core coolant: Implications for clogging of sump strainers

Clogging of sump strainers that filter the recirculation water in containment after a loss-of-coolant accident (LOCA) seriously impedes the continued cooling of nuclear reactor cores. In experiments examining the corrosion of aluminium alloy 6061, a common material in containment equipment, in borated solutions simulating the water chemistry of sump water after a LOCA, we found that Fe-bearing intermetallic particles, which were initially buried in the Al matrix, were progressively exposed as corrosion continued. Their cathodic nature $vis-{\grave{a}}-vis$ the Al matrix provoked continuous trenching around them until they were finally released into the test solution. Such particles released from Al alloy components in a reactor containment after a LOCA will be transported to the sump entrance with the recirculation flow and trapped by the debris bed that typically forms on the strainer surface, potentially aggravating strainer clogging. These Fe-bearing intermetallic particles, many of which had a rod or thin strip-like geometry, were identified to be mainly the cubic phase ${\alpha}_c-Al(Fe,Mn)Si$ with an average size of about $2.15{\mu}m$; 11.5 g of particles with a volume of about $3.2cm^3$ would be released with the dissolution of every 1 kg 6061 aluminium alloy.