Browse > Article
http://dx.doi.org/10.5516/NET.2008.40.6.489

EVALUATION OF FERROCYANIDE ANION EXCHANGE RESINS REGARDING THE UPTAKE OF Cs+ IONS AND THEIR REGENERATION  

Won, Hui-Jun (Korea Atomic Energy Research Institute)
Moon, Jei-Kwon (Korea Atomic Energy Research Institute)
Jung, Chong-Hun (Korea Atomic Energy Research Institute)
Chung, Won-Yang (Department of Chemistry, Kangwon University)
Publication Information
Nuclear Engineering and Technology / v.40, no.6, 2008 , pp. 489-496 More about this Journal
Abstract
Ferrocyanide-anion exchange resin was prepared and the prepared ion exchange resins were tested on the ability to uptake $Cs^+$ ion. The prepared ion exchange resins were resin-KCoFC, resin-KNiFC, and resin-KCuFC. The three tested ion exchange resins showed ion exchange selectivity on the $Cs^+$ ion of the surrogate soil decontamination solution, and resin-KCoFC showed the best $Cs^+$ ion uptake capability among the tested ion exchange resins. The ion exchange behaviors were explained well by the modified Dubinin-Polanyi equation. A regeneration feasibility study of the spent ion exchange resins was also performed by the successive application of hydrogen peroxide and hydrazine. The desorption of the $Cs^+$ ion from the ion exchange resin satisfied the electroneutrality condition in the oxidation step; the desorption of the $Fe^{2+}$ ion in the reduction step could also be reduced by adding the $K^+$ ion.
Keywords
Cesium; Ion Exchange Resin; Regeneration; Soil; Decontamination;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 1
연도 인용수 순위
1 T. J. Tranter, R. S. Herbst, T. A. Todd, A. L. Olson and H. B. Eldredge, 'Application of a Second Order Kinetic Model for the Preliminary Design of an Adsorption bed System Using Ammonium Molybdophosphate Polyacrylonitrile for the Removal of $^{137}Cs$ from Acidic Nuclear Waste Solutions', Advances in Environmental Research, 7, 913 (2003)   DOI   ScienceOn
2 R. W. Peters, 'Chelant Extraction of Heavy Metals from Contaminated Soils', Journal of Hazardous Materials, 66, 1(1999)   DOI   ScienceOn
3 P. K. A. Hong, C. Li, S. K. Banerji and Y. Wang, 'Feasibility of Metal Recovery from Soil Using DTPA and Its Biostability', Journal of Hazardous Materials, B 94, 253 (2002)
4 H. J. Won, B. G. Ahn, C. H. Jung, G. N. Kim and W. Z. Oh 'Fixation of - Radionuclides by the PVA-PMAA System', J. Korean Nuclear Society, 32, 3 (2000)
5 M. Pourbaix, 'Atlas of Electrochemical Equilbria in Aqueous Solutions', National Association of Corrosion Engineers, Houston, Texas, USA (1974)
6 M. Ebadi, 'Electrocatalytic Oxidation and Flow Amperometric Detection of Hydrazine in a Dinuclear Ruthenium Phthalocyaninemodified Electrode', Can. J. Chem., 81, 2 (2003)
7 J. S. Kim, Y. S. Jeon, S. D. Park, B. C. Song, S. H. Han and J. G. Kim, 'Dissolution of Irradiated U-Zr Alloy Nuclear Fuel by Chemical Methods', Nuclear Engineering and Technology, 38, 3 (2006)   과학기술학회마을
8 D. M. Ruthven, 'Principles of Adsorption and Adsorption Process', John Wiey & SONS, New York (1994)
9 J. K. Moon, C. H. Jung, E. H. Lee, H. T. Kim and Y. G. Shul, 'Preparation of PAN-Zeolite 4A Composite Ion Exchanger and Its Uptake Behavior for Sr and Cs Ions in Acid Solution', Korean J. Chem. Eng., 19, 5 (2002)
10 Y. Inoue, H. Yamazaki and F. Kasuga, 'Studies on the Hydrous Titanium Oxide Ion Exchanger and Rate of the Isotopic Exchange of Sodium Ions between the Exchanger in the $Na^+$ Ion Form and Aqueous Solution', Bull. Chem. Soc., 68, 191 (1995)   DOI   ScienceOn
11 D. R. Mann and S. A. Casso, 'In Situ Chemisorption of Radiocesium from Sea Water', Marine Chem., 14, 307 (1984)   DOI   ScienceOn
12 K. Tanihara, 'Method for the Preparation of an Ion Exchanger for Cesium Ions and Method for Regeneration Thereof', Patent No. US 5601722 (1997)
13 T. R. Folsom, N. Hansen, T. J. Tatum and V. F. Hodge, 'Recent Developments in Method for Concentrating and Analyzing Radiocesium in Sea Water', J. Radiation. Res., 16, 19 (1975)   DOI
14 H. J. Won, M. K. Kim, G. N. Kim, C. H, Jung, J. H. Park and W. Z. Oh, 'Treatment of Simulated Soil Decontamination Waste Solution by Ferrocyanide-Anion Exchange Resin Beads', J. Kor. Rad. Waste Soc., 3, 1 (2005)
15 H. H. Someda, A. A. ElZahhar, M. K. Shehata and H. A. El-Nagger, 'Supporting of Some Ferrocyanides on Polyacrlonitrile (PAN) Binding Polymer and Their Application for Cesium Treatment', Separation and Purification Technology, 29, 1 (2002)   DOI   ScienceOn
16 S. M. Robinson, W. D. Arnold and C. W. Byers, 'Multicomponent Liquid Ion Exchange with Chabazaite Zeolites', ORNL/TM-12403, Oak Ridge National Laboratory (1993)
17 J. K. Moon, E. H. Lee, Y. J. Han, B. C. Lee and H. T. Kim, 'Multi-component Ion Exchange Kinetics with PANKCoFC Composite Ion Exchanger', Korean J. Chem. Eng., 22, 1 (2005)   DOI
18 Y. Onodera, H. Mimura, T. Iwasaki, H. Hayashi and T. Ebina, 'Biopolymer Composite Ion Exchanger with High Cesium Selectivity and Its Manufacturing Method', US Patent 6616860 B1 (2003)
19 M. S. Yang, J. H. Park, W. I. Ko, K. C. Song, K. M. Choi and J. K. Kim, 'Evaluation of Proliferation Resistance Using the INPRO Methodology', Nuclear Engineering and Technology, 39, 2 (2007)   과학기술학회마을   DOI
20 S. D. Collyer, F. Davies, A. Lucke, C. J. M. Stirling and S. P. J. Higson, 'The Electrochemistry of the Ferri/ferrocyanide couple at a calix[4]resorcinarene- tetrathiol-modified Gold Electrode as a Study of Novel Electrode Modifying Coatings for Use within Electroanalytical Sensors', J. Electroanalytical Chemistry, 549, 119 (2003)   DOI   ScienceOn
21 K. Watari, K. Imai, Y. Ohmomo, Y. Muramatsu, Y. Nishimura, M. Izawa and L. R. Baciles, 'Simultaneous Adsorption of Cs-137 and I-131 from Water and Milk on Metal Ferrocyanide-Anion Exchange Resin', J. Nucl. Sci. Techn. 25, 5 (1988)