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http://dx.doi.org/10.5855/ENERGY.2019.28.1.001

Evaluation and application of grinding index of domestic desulfurization limestone  

Seo, Jun Hyung (Korea Institute of Limestone and Advanced Materials)
Baek, Chul Seoung (Korea Institute of Limestone and Advanced Materials)
Cho, Jin Sang (Korea Institute of Limestone and Advanced Materials)
Ahn, Young Jun (Daesung MDI)
Ahn, Ji Whan (Korea Institute of Geoscience and mineral resources)
Cho, Kye Hong (Korea Institute of Limestone and Advanced Materials)
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Abstract
In the flue gas desulfurization process of the coal-fired power plant, the grinding efficiencies of the limestone as the sorbent for desulfurization were compared after BWI and HGI measurements. As a result, the grinding index of the domestic desulfurization limestone were linear inversely proportional relationship with decreasing BWI was observed with increasing HGI. There was a difference in grinding efficiency depending on the chemical composition and crystal structure. Therefore, it is considered that when grinding ability of limestone is measured, the grinding property of the sample can be confirmed even by using HGI which can be measured more easily than BWI which is difficult to measure and takes a long time. The desulfurization efficiency can be improved by selective utilization of limestone depending on the crushing characteristics.
Keywords
Bond's Work Index; Hardgrove Grindability Index; Ball Mill; Limestone; Desulfurization;
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1 Srivastava, R. K., Jozewicz, W., 2001, Flue Gas Desulfurization : The State of the Art, Journal of the Air and Waste Management Assiciation, Vol 51, No. 12, pp. 1676-1688   DOI
2 Angel, I., Javier, R., Immaculada, O., 1990, Thermal Dehydration of Calcium Hydroxide. 1. Kinetic Model and Parameters, Journal of Industrial and Engineering Chemistry, Vol. 29, No. 8, pp. 1599-1606   DOI
3 Lee, H., Cho, H. C., 2002, Determination of the Breakage Parameters on the Nonmetallic Minerals, Journal of Korean Society of Mineral and Energy Resources, Vol. 39, No. 4, pp. 248-256
4 Cho, H. C., Jeong, S., 2005, A Characteristic Study of Ball Mill and Centrifugal Mill using Discrete Element Method, Journal of Korean Society of Mineral and Energy Resources, Vol. 42, No. 4, pp. 393-402.
5 Bond, F. C., 1961, Crushing and Grinding Calculations ; Part 1. British Chemical Engineering, Vol. 6, No. 6, pp. 378-385
6 Bond, F. C., 1952, The Third theroy of comminution, Transactions of the American Institute of Mining and Metallurgical Engineers, Vol. 193, No. 4, pp. 484-494
7 The British Standards Institution., 1995, Methods for Analysis and testing of coal and coke, Determination of Hardgrove grindability index of hard coal (BS 1016-112), England
8 Kong, B. S., Kim, Y. H., 2015, Grinding and equipment for limestone, Mineral science and industry, Vol. 18, No. 2, pp. 52-62
9 Han, S. S. et al., 2018, Simulation of Grinding/Classification Circuit in Domestic Gold ore Processing Plant Using Energy-based Grinding Model and Mathematical Classification Model, Journal of Korean Society of Mineral and Energy Engineers, Vol. 55, No. 1, pp. 8-19.   DOI
10 Noh, J. H., Lee, N. K., 2007, Applied-mineralogical Study on the Grinding Effects and Powder Properties of High- Ca Limestone, Journal of the Korean Society of Mineral and Energy Resources Engineers, Vol. 44, No. 3, pp. 191-207
11 Cho, J. S. et al., 2010, The Effect on Calcination and Hydration Properties of Different Grade Limestone in Danyang Area, Journal of the Korean Society of Mineral and Energy Resources Engineers, Vol. 47, No. 4, pp 487-495
12 Geological Investigation Corps of Teabaeksan Regian in Korea (GICTR), 1962, Geological Investigation Report of Taebaeksan Regian, Journal of the Geological Society of Korea, p. 107
13 Korea Institute of Geoscience and mineral resources(KIGAM), 2016, MEGO Geologic Information System, mego.kigam.re.kr
14 Korea Industrial Standards Commission (KISC), 2002, Method for X-ray fluorescence spectrometric analysis of limestone and dolomite (KS E 3075), Korea
15 American society for testing and materials (ASTM), 1987, Standard Test Method for Performing the Sieve Analysis of Coal and Designating Coal Size (ASTM D 4749), USA
16 Korea Agency for Technology and Standards (KATS), 2011, Testing method of grinding work index (KS E 3600), Korea
17 Cuhadaroglu, A. D. et al., 2013, Characterization of the Grinding Behavior of Binary Mixtures of Clinker and Colemanite, Particulate Science and Technology, Vol. 31, No. 6, pp. 596-602   DOI
18 American society for testing and materials (ASTM), 2008, Standard Test Method for Grindability of Coal by the Hardgrove-Machine Method (ASTM D 409), USA
19 Korea Limestone Industry Cooperation (KLIC), 2015, Limestone for flue gas desulfurization (SPS-KLIC-004-775), Korea
20 Ohliger, A., Forster, M., Kneer, R., 2013, Torrefaction of beechwood: a parametric study including heat of reaction and grindability, Fuel, Vol. 104, pp. 607-613   DOI
21 Raimie, H. H. et al., 2013, Physicochemical characterization of torrefied biomass, Journal of Analytical and Applied Pyrolysis, Vol. 103, pp. 21-30   DOI
22 Bond, F. C., 1955, How Does Rock Break?, The Scientific Monthly, Vol. 81, No. 4, pp. 196-198.
23 Jung, M. Y., 2003, Development Trend of Mineral Powder Manufacturing Technology, Mineral science and industry, Vol. 16, No. 2, pp, 24-35
24 Agus, F., Waters, P. L., 1971, Determination of the grindability of coals, shales and other minerals by a modified Hardgrove-machine method, Fuel, Vol. 50, No. 4, pp. 405-431   DOI
25 Park, S. S., Kim, K. H. and Park, S. Y., 1997, Grindability and Reactivity of Limestones for Flue Gas Desulfurization, Applied Chemistry, Vol. 1, No. 2, pp. 465-4680
26 McIntyre, A., Plitt, L. R., 1980, Interrelationship between Bond and Hardgrove grindabilities. Canadian Institute of Mining and Metallurgy, Vol. 73, No. 818, pp. 149-155
27 Hower, J. C., Barton, L. S., Moshier, S. O., 1992, Application of the Hardgrove grindability index in carbonate characterization, Minerals and Metallurgical Processing, Vol. 9, No. 3, pp. 146-150
28 Frantisek, T., 2008, Contribution to determination of coal grindability using Hardgrove method, GeoScience Engineering, Vol. LIV, No. 1, pp. 27-32