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Hydrogen storage of multiwall carbon nanotube decorated with bimetallic Pt-Pd nano catalysts using thermal vapor deposition  

Hwang, Sang-Woon (School of Chemical Engineering, Chonbuk National University)
So, Chang-Su (Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University)
Naik, Mehraj-Ud-Din (School of Chemical Engineering, Chonbuk National University)
Nahm, Kee-Suk (School of Chemical Engineering, Chonbuk National University)
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Abstract
In present work, we study the hydrogen storage of MWNT decorated with bimetallic Pt and Pd nanosize catalysts by Thermal Vapor Deposition [TVD]. The size of Pt and Pd particles is controlled as 5nm, 3nm, respectively by TVD. Before hydrogen storage measurement, the sample was heated for 1hr at $200^{\circ}C$ in H2 atmosphere. The Hydrogen sto rage of the sample was performed at room temperature and 33~34atm. The hydrogen storage of this composite showed 3.2wt% at 298K and 34atm, for three times. At 4th cycle, hydrogen storage is decreased to 1.5wt%, owing to the aggregation of bimetallic Pt and Pd nano particles.
Keywords
Hydrogen storage; Pt; Pd; catalyst;
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1 M. Sankarana, B. Viswanathan, S. S. Murthy, "Boron substituted carbon nanotubes—How appropriate are they for hydrogen storage?", Inter. J. Hydrogen Energy 33 (2008) 393   DOI   ScienceOn
2 John J. Vajo, Gregory L. Olson, "Hydrogen storage in destabilized chemical systems", Scripta Mater. 56 (2007) 829   DOI   ScienceOn
3 Chien-Hung Chen, Chen-Chia Huang, "Hydrogen storage by KOH-modified multi-walled carbon nanotubes", Inter. J. Hydrogen Energy. 32 (2007) 237   DOI   ScienceOn
4 Shi-chun Mu, Hao-lin Tang, Sheng-hao Qian, Mu Pan, Run-zhang Yuan. "Hydrogen storage in carbon nanotubes modified by microwave plasma etching and Pd decoration", Carbon. 44 (2006) 762   DOI   ScienceOn
5 W. Qikun, Z. Changchun, L. Weihua, W. Ting, "Hydrogen storage by carbon nanotube and their films under ambient pressure" Inter. J. Hydrogen Energy. 27 (2002) 497   DOI   ScienceOn
6 P. Benard, R. Chahine, "Storage of hydrogen by physisorption on carbon and nanostructured materials", Scripta Materialia. 56 (2007) 803   DOI   ScienceOn
7 Y. J. Choi, J. Lu, H. Y. Sohn, Z. Z. Fang, "Hydrogen storage properties of the Mg–Ti–H system prepared by high-energy–high-pressure reactive milling"J. Power Sources. 180 (2008) 491   DOI   ScienceOn
8 Sang-Woon Hwang, Sami-ullah Rather, Mehraj-ud-din Naik, Chang Su Soo, Kee-Suk Nahm. "Hydrogen uptake of multiwalled carbon nanotubes decorated with Pt –Pd alloy using thermal vapour deposition method", J. Alloy. Comp. 480 (2009) L20   DOI   ScienceOn
9 C. Weng, S. P. Ju, K. C. Fang, F. P. Chang, "Atomistic study of the influences of size, VDW distance and arrangement of carbon nanotubes on hydrogen storage", Comput. Mater. Sci. 40 (2007) 300   DOI   ScienceOn
10 W.C. Xu, K. Takahashi, Y. Matsuo, Y. Hattori, M. Kumagai, S. Ishiyama, K. Kaneko, S. Iijima, "Investigation of hydrogen storage capacity of various carbon materials", Inter. J. Hydrogen Energy. 32 (2007) 2504   DOI   ScienceOn
11 A. Paolone, O. Palumbo, R. Cantelli, S. Roth, U. Dettlaff, "An anelastic spectroscopy investigation of carbon nanotubes produced by the high-pressure CO method", Mater. Science and Eng. A 442 (2006) 314   DOI   ScienceOn
12 P. Benard, R. Chahine, P.A. Chandonia, D. Cossement, G. D. Douville, L. Lafi, P. Lachance, R. Paggiaro, E. Poirier, "Comparison of hydrogen adsorption on nanoporous materials", J. Alloy. Comp. 446 (2007) 380   DOI   ScienceOn
13 A. L. M. Reddy, S. Ramaprabhu, "Hydrogen adsorption properties of single-walled carbon nanotube—Nanocrystalline platinum composites", Inter. J. Hydrogen Energy. 33 (2008) 1028   DOI   ScienceOn
14 C. H. Chen, C. C. Huang, "Hydrogen adsorption in defective carbon nanotubes" Micro. Meso. Mater. 109 (2008) 549   DOI   ScienceOn