Browse > Article
http://dx.doi.org/10.7585/kjps.2016.20.2.128

Analysis of Residual Organic Solvent in Environmentally-friendly Farming Materials with Headspace Method  

Choi, Geun Hyoung (Chemical Safety Division, National Institute of Agricultural Sciences, RDA)
Kong, Seung-Heon (Division of Applied Life Science (BK21 plus), Institute of Agriculture and Life Science (IALS), Gyeongsang National University)
Park, Byung-Jun (Chemical Safety Division, National Institute of Agricultural Sciences, RDA)
Moon, Byeong-Cheol (Chemical Safety Division, National Institute of Agricultural Sciences, RDA)
Kim, Jin-Hyo (Division of Applied Life Science (BK21 plus), Institute of Agriculture and Life Science (IALS), Gyeongsang National University)
Publication Information
The Korean Journal of Pesticide Science / v.20, no.2, 2016 , pp. 128-132 More about this Journal
Abstract
Volatile organic solvents are used to extract the bioactive materials from raw materials for environmentally-friendly farming materials (EFFM), but the solvent should not remain in EFFM for the safety reasons. Thus qualitative and quantitative analysis method for the solvents using Headspace-GC were evaluated. Water content depleted the detection ratio of hydrophilic solvents and disturbing the hydrophilic interaction with solvents by DMSO might be helped to increase the detection ratio (up to 715%). Surfactant concentration affected to the detection ratio (68.5-179.1%) while surfactant type was not deeply involved the solvent detection. On the other hand, matrix-matched calibration method was accepted the minimum requirements for the quantitative analysis of the solvents in EFFM.
Keywords
Detergent; Environmentally-friendly farming material; Headspace; Matrix-matched calibration; Organic solvent;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Belsky, J. L., A. J. Ashley, P. A. Bhatt, K. V. Gilbert, H. R. Joyce, C. Pan, H. Pappa and S. Z. Wahab (2010) Optimization of the water-insoluble procedures for USP General Chapter Residual Solvents <467>. AAPS Pharm. Sci. Tech. 11:994-1004.   DOI
2 Ettre, L. S., C. Welter and B. Kolb (1993) Determination of gasliquid partition coefficients by automatic equilibrium Headspace-gas chromatography utilizing the phase ratio variation method. Chromatographia 35:73-84.   DOI
3 Huie, C. W. (2002) A review of modern sample-preparation techniques for the extraction and analysis of medicinal plants. Anal. Bioanal. Chem. 373:23-30.   DOI
4 Jumepaeng, T., D. L. Luthria and S. Chanthai (2012) The effect of surfactant on headspace single drop microextraction for the determination of some volatile aroma compounds in citronella grass and lemongrass leaves by gas chromatography. Anal. Methods 4:421-428.   DOI
5 Kim, J. H., G. H. Choi, S. J. Lim and B. J. Park (2015) Stability of matrine and oxymatrine from the biopesticide from Sophora flavescens under aquatic and soil environment. Kor. J. Environ. Agric. 34:1-5.   DOI
6 Kolb, B., C. Welter and C. Bichler (1992) Determination of partition coefficients by automatic equilibrium headspace gas chromatography by vapor phase calibration. Chromatographia 34:235-240.   DOI
7 Laus, G., M. Andre, G. Bentivoglio and H. Schottenberger (2009) Ionic liquids as superior solvents for headspace gas chromatography of residual solvents with very low vapor pressure, relevant for pharmaceutical final dosage forms. J. Chroma. A. 1216:6020-6023.   DOI
8 Luzar, A. and D. Chandler (1993) Structure and hydrogen bond dynamics of water-dimethyl sulfoxide mixture by computer simulations. J. Chem. Phys. 98:8160-8173.   DOI
9 Paik, M. K., J. M. Park, J. I. Kim, G. H. Choi, S. Y. Kim, S. M. Hong, G. J. Im, M. K. Hong and J. H. Kim (2011) Analyses of residual alkylbenzenes and its probabilistic risk assessment in Sundried salts. J. Kor. Soc. Appl. Biol. Chem. 54:124-127.
10 Somuramasami, J., Y. C. Wei, E. F. Soliman and A. M. Rustum (2011) Static headspace gas chromatographic method for the determination of low and high boiling residual solvents in Betamethasone valerate. J. Pharma. Biomed. Anal. 54:242-247.   DOI
11 Teja, A. S., A. K. Gupta, K. Bullock, X. S. Chai and J. Zhu (2001) Henry's constants of methanol in aqueous systems containing salts. Fluid Phase Equilibria 185:265-274.   DOI
12 Urakami, K., A. Higashi, K. Umemoto and M. Godo (2004) Matrix media selection for the determination of residual solvents in pharmaceuticals by static headspace gas chromatography. J. Chroma. A. 1057:203-210.   DOI
13 Ye, C. L., Q. X. Zhou and X. M. Wang (2006) Headspace liquid-phase microextraction using ionic liquid as extractant for the preconcentration of dichlorodiphenyltrichloroethane and its metabolites at trace levels in water samples. Analytica Chimica Acta. 572:165-171.   DOI