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Investigation of Nonylphenols Contamination in Solvents and Solid-phase Extraction Cartridge, and its Removal Protocols  

Park, Jong-Min (Division of Chemical Safety, National Academy of Agricultural Science, RDA)
Choi, Geun-Hyonng (Division of Chemical Safety, National Academy of Agricultural Science, RDA)
Kim, Jung-Im (Division of Chemical Safety, National Academy of Agricultural Science, RDA)
Hong, Su-Myeong (Division of Chemical Safety, National Academy of Agricultural Science, RDA)
Kwon, Oh-Kyung (Division of Chemical Safety, National Academy of Agricultural Science, RDA)
Im, Geon-Jae (Division of Chemical Safety, National Academy of Agricultural Science, RDA)
Kim, Jin-Hyo (Division of Chemical Safety, National Academy of Agricultural Science, RDA)
Publication Information
The Korean Journal of Pesticide Science / v.15, no.1, 2011 , pp. 22-27 More about this Journal
Abstract
Nonylphenols are toxic compounds classified as endocrine disruptors. We investigated the nonylphenols clean-up procedures for the contamination control in the quantitative analysis. In this research we analyzed the residual nonylphenols in the solvent and the SPE cartridges. First, at the analysis of HPLC grade solvents (n-hexane, diethyl ether, ethyl acetate and its mixture), diethyl ether was confirmed the residue as 0.963 ${\mu}g/mL$, and we eliminated the contaminant through the distillation with $CaH_2$, Second, at the analysis of SPE cartridges (silica gel and Florisil), all products were showed the residue at 0.046~13.0 ${\mu}g/mL$, but unfortunately the residue in the cartridge were not easily removed with referenced methods in all tested SPE cartridges except in silica gel SPE cartridge with glass ware.
Keywords
Nonylphenols; EDs; Contamination; Quantitative analysis;
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