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http://dx.doi.org/10.12654/JCS.2016.32.3.09

A Study on Extraction and Analysis of Red Dyed Fabric  

Imn, Se Yeon (Department of Heritage Conservation & Restoration, Graduate School of Convergence Cultural Heritage, Korea National University of Cultural Heritage)
Chung, Yong Jae (Department of Heritage Conservation & Restoration, Graduate School of Convergence Cultural Heritage, Korea National University of Cultural Heritage)
Publication Information
Journal of Conservation Science / v.32, no.3, 2016 , pp. 385-394 More about this Journal
Abstract
A fabric excavated from tombs or passed down is not easy to find its original color as it degrades and discolors by UV and visible rays, oxygen and microorganisms. LC-MS analysis is commonly used for separating and analyzing colors, but color extraction process is complicated and important in dye-qualitative analysis. To extract red colors from a fabric which is dyed with safflower and lac, solvents; hydrogen chloride, pyridine and oxalic acid are used and oxalic acid was the most effective solvent. Meanwhile, dyed samples were put in degradation condition; UV-A for 168 hours and analyzed with LC-MS to find out its colors'chemical changes. As a result, carthamin is detected in $T_R$ 13 min and laccaic acid A is detected in $T_R$ 10 min. However carthamin is not detected in a degraded fabric dying with safflower, it could be identified as a safflower fabric by the molecular weight of m/z 931. Through this study the most optimal method for red color extraction is found so it is expected to be used as a base line data for red color LC-MS analysis.
Keywords
Safflower; Lac; Yeonji; Color extraction; LC-MS;
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  • Reference
1 Ahn, C.S. and Obendorf, A.K., 2004, Dyes on archaeological textiles: Analyzing alizarin and its degradation products. Textiles Research Journal, 74(11), 949-954.   DOI
2 Ahn, C.S., Zeng, X., Li, L. and Obendorf, S.K., 2014, Thermal degradation of natural dyes and their analysis using HPLC-DAD-MS. Fashion and Textiles, 1, 1-13.   DOI
3 Clementia, C., Nowikb, W., Romania, A., Cibinc, F. and Favaro, G., 2007, A spectrometric and chromatographic approach to the study of ageing of madder(Rubia tinctorum L.) dyestuff on wool. Analytica Chimica Acta, 596, 46-54.   DOI
4 Cardon, D., 2007, Natural dyes : Sources, traditional, technology and Science. Archetype, London.
5 Imn, S.Y., 2016, A study on extraction and analysis of traditional red dye 'Yeonji'. Master's thesis, Korea National University of Cultural Heritage, Buyeo. (in Korean with English abstract)
6 Jo, K.R., 2010, A study of natural dyeing. Hyungseul Publishing, Seoul. (in Korean)
7 Laursen, R. and Mouri, C., 2013, Decomposition and analysis of carthamin in safflower-dyed textiles. e-preservation Science, 10, 35-37.
8 Mouri, C. and Laursen, R., 2012, Identification of anthraquinone markers for distinguishing Rubia species in madder-dyed textiles by HPLC. Microchimica Acta, 179, 105-113.   DOI
9 Oka, H., Ito, Y., Yamada, S., Kagami, T., Hayakawa, J., Harada, K., Atsumi, E., Suzuki, M., Suzuki, M., Odani, H., Akahori, S., Maeda, K., Tanaka, T. and Mizuno, M., 1998, Identification of lac dye components by electrospray high performance liquid chromatography tandem mass spectrometry. Journal of Mass Spectrometry Society of Japan, 46(1), 63-68.   DOI
10 Sato, K., Sugimotoa, N., Ohtaa, M., Yamazakia, T., Maitania T. and Tanamotoa, K., 2003, Structure determination of minor red pigment in carthamus red colorant isolated by preparative LC/MS. Food Additives and Contaminants, 20(11), 1015-1022.   DOI
11 Surowieca, I., Quyeb, A. and Trojanowicz, M., 2006, Liquid chromatography determination of natural dyes in extracts from historical Scottish textiles excavated from peat bogs. Journal of Chromatography A, 1112, 209-217.   DOI
12 Valianou, L., Karapanagiotis, I. and Chryssoulakis, Y., 2009, Comparison of extraction methods for the analysis of natural dyes in historical textiles by high-performance liquid chromatography. Analytical and Bioanalytical Chemistry, 395(7), 2175-2189.   DOI
13 Zhang, X. and Laursen, R.A., 2005, Development of mild extraction methods for the analysis of natural dyes in textiles of historical interest using LC-diode array detector-MS. Journal of Analytical Chemistry, 77, 2022-2025.   DOI
14 Wouters, J., Grzywacz, M. and Claro, A., 2010, Markers for identification of faded safflower(Carthamus tinctorius L.) colorants by HPLC-PDA-MS. Studies in Conservation, 55, 186-203.   DOI