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http://dx.doi.org/10.11629/jpaar.2013.9.4.201

Carbonic Anhydrase Mimicry for Carbon Dioxide Fixation and Calcium Carbonate Mineralization  

Sahoo, Prakash C. (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources)
Jang, Young Nam (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources)
Chae, Soo Chun (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources)
Lee, Seung Woo (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources)
Publication Information
Particle and aerosol research / v.9, no.4, 2013 , pp. 201-208 More about this Journal
Abstract
Copper (II) and Nickel (II) mimic complexes of enzyme carbonic anhydrase were evaluated under ambient condition for carbon dioxide capture and conversion process. The synthesized complexes were characterized by ATR-FTIR and UV-DR spectroscopy. It was found that all the complexes have biomimetic activity towards $CO_2$ using para-nitrophenyl acetate (p-NPA) hydrolysis as the model reaction. Interestingly, the proper geometry obtained by the restricted orientation of tripodal N atoms in Cu (II) complex of 2,6-bis(2-benzimidazolyl) pyridine showed the highest activity (1.14 au) compared to others. The $CO_2$ bio-mineralization to $CaCO_3$ was carried out via in-vitro crystallization approach. Results indicate that the biomimetic complexes have a role in determining $CaCO_3$ morphology. The present observations establish a qualitative insight for the design of improved small-molecule catalysts for carbon capture.
Keywords
Carbon dioxide; Carbonic anhydrase; Metal complex; Calcium Carbonate;
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