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http://dx.doi.org/10.12989/scs.2017.24.1.015

Investigation of natural solution effect in electrical conductivity of PANI-CeO2 nanocomposites  

Shafiee, Mohammad Reza Mohammad (Department of Chemistry, Faculty of Sciences, Najafabad Branch, Islamic Azad University)
Sattari, Ahmad (Department of Chemistry, Faculty of Sciences, Najafabad Branch, Islamic Azad University)
Kargar, Mahboubeh (Department of Chemistry, Faculty of Sciences, Najafabad Branch, Islamic Azad University)
Ghashang, Majid (Department of Chemistry, Faculty of Sciences, Najafabad Branch, Islamic Azad University)
Publication Information
Steel and Composite Structures / v.24, no.1, 2017 , pp. 15-22 More about this Journal
Abstract
A green biosynthesis method is described for the preparation of Polyaniline (PANI)-cerium dioxide ($CeO_2$) nanocomposites in different media via in-situ oxidative polymerization procedure. The effect of various media including use of HCl, Lemon Juice, Beverage, White Vinegar, Verjuice and Apple vinegar extracts on the particles size, morphology as well as the conductivity of $PANI-CeO_2$ nanocomposites was investigated. The electron-withdrawing feature of $CeO_2$ increases doping level of PANI and enhances electron delocalization. These cause a significantly blue shift of C = C stretching band of quinoid from $1570cm^{-1}$ to $1585cm^{-1}$. The optical properties of the pure material and polymeric nanocomposites as well as their interfacial interaction in nanocomposite structures analyzed by UV-visible spectroscopy. The DC electrical conductivity (${\sigma}$) of as-prepared HCl doped PANI and a $PANI-CeO_2$ nanocomposite measured by a four-probe method at room temperature was studied.
Keywords
natural solution; $PANI-CeO_2$; nanocomposite; in situ oxidative;
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