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http://dx.doi.org/10.5322/JESI.2022.31.12.1103

Adsorption Characteristics of Pesticides in Zeolites  

Chang-Han Lee (Department of Environmental Adminstration, Catholic University of Pusan)
Kil-Seong Kim (Research Institute of Health and Environment, Jeju Special-Governing Province)
Sang-Kyu Kam (Department of Environmental Engineering, Jeju National University)
Publication Information
Journal of Environmental Science International / v.31, no.12, 2022 , pp. 1103-1115 More about this Journal
Abstract
The adsorption characteristics of four pesticides (phosphamidon, fenitrothion, triadimefon, and diniconazole) on natural clinoptilolite (CLIN) and three synthetic zeolites were investigated. The synthetic zeolites included faujasite (FAUF) synthesized from coal fly ash; the mixture of FAU and Na-P1 (FAU + Na-P1)SF synthesized using Jeju scoria and coal fly ash at the ratio of 1.5 by weight; and waste fluid catalytic cracking catalyst (FCCW). The distribution coefficient, KD and the Freundlich constant, KF decreased in the following sequence: FCCW > FAUF > (FAU + Na-P1)SF > CLIN among the zeolites and diniconazole>fenitrothion> triadimefon> phosphamidon among the pesticides. The pesticide adsorptivity increased with increasing temperature for FAUF, (FAU+Na-P1)SF and FCCW, however, it decreased for CLIN, regardless of the type of pesticide. The adsorptivity of pesticides was independent of pH for phosphamidon, fenitrothion and triadimefon, whereas it decreased with increasing pH for diniconazole, regardless of zeolite type.
Keywords
Adsorption; Natural zeolite; Synthetic zeolites; Pesticides;
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