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http://dx.doi.org/10.5322/JES.2008.17.2.203

Treatment of Diesel-Contaminated Soils by Fenton Oxidation  

Lim, Myung-Hee (Department of Civil, Environmental and Architectural Engineering, Korea University)
Son, Young-Gyu (Department of Civil, Environmental and Architectural Engineering, Korea University)
Yun, Jun-Ki (Research institute of technology, Samsung Corporation)
Khim, Jee-Hyeong (Department of Civil, Environmental and Architectural Engineering, Korea University)
Publication Information
Journal of Environmental Science International / v.17, no.2, 2008 , pp. 203-210 More about this Journal
Abstract
The batch tests were performed to determine the ratio of Fenton reagent on diesel contaminated soil. The objective of a column test was to determine and optimize the hydrogen peroxide requirements for the remediation of a soil contaminated with diesel fuel. The batch test were done on 5 g diesel contaminated soil containing hydrogen peroxide (35%) and Iron (II) sulfate. The $H_2O_2(g):Fe^{2+}(g)$ ratio varied 1:0, 30:1, 15:1, 5:1, 1:1, with contact reaction time 120min. Initial diesel concentration were 2,000 mg/kg, 5,000 mg/kg, and 10,000 mg/kg. Average diesel removal from the contaminated soil is 97% after 2hrs. Results of this study showed possible application of without addition of iron source. In column test, treatment of a diesel-contaminated soil (initial diesel concentration: 2,000 mg/kg, 5,000 mg/kg, and 10,000 mg/kg) with hydrogen peroxide (35%) only was containing natural-occurring minerals. The time required for the column test was approximately 90min, 180min, 270min; column length was 5 em, 10 em, and 15 em. The most effective stoichiometry (final diesel cone.: $200{\sim}300mg/kg$) of 0.2 g peroxide consumed/mg diesel degraded. Further investigation is required to identify the effect of soil organic matter and soil mineral.
Keywords
Fenton oxidation; Diesel; Soil; Hydrogen peroxide;
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1 Spencer C. J., Stanton P. C., Watts R. J., 1996, A central composite rotatable analysis for the catalyzed hydrogen peroxide remediation of diesel-contaminated soils, Air & Waste Manage. Assoc. 46, 1067-1074   DOI   ScienceOn
2 최진호, 김재호, 공성호, 1997, 석유로 오염된 토양의 과수를 이용한 처리에 관한 연구, 한국토양환경학회지, 2(3), 49-57
3 Kang S., Laio C., Chen M., 2002, Pre-oxidation and coagulation of textile wastewater by the Fenton process, Chemosphere, 923-928
4 Lopez A., Pagano M., Volpe A., Pinto A. C., 2004, Fenton's pre-treatment of mature landfill leachate, Chemosphere, 54, 1005-1010   DOI   ScienceOn
5 Matinez N. S., Fernandez J. F., Segura X. F., Ferrer A. S., 2003, Pre-oxidation of an extremely polluted industrial wastewater by the Fenton's reagent, J. Haz. Mat., 101, 315-322   DOI   ScienceOn
6 남영우, 한금석, 박태욱, 2004, 펜톤 산화를 이용한 하수 슬러지의 유기산 생성 및 탈질에 관한 연구, 한국폐기물학회 춘계학술연구발표, 192-195
7 Baclocchl R., Boni M. R., D'Aprile L., 2003, Hydrogen peroxide lifetime as an indicator of theefficiency of 3-chlorophenol Fenton's and Fenton-like oxidation in soils, J. Haz. Mat. 96, 305-329   DOI   ScienceOn
8 Kakarla P. K. C., Watts R. J., 1997, Depth of fenton-like oxidation in remediation of surface soil, J. Env. Eng., 123(1), 11-17   DOI   ScienceOn
9 Kong S. H., Watts R. J. Choi J. H., 1998, Treatment of petroleum-contaminated soil using iron mineral catalyzed hydrogen peroxide, Chemosphere. 37(8). 1473-1482   DOI   ScienceOn
10 최석종, 최현진, 박진희, 이태진, 2004, 펜톤 유사반응을 이용한 디젤 오염토양의 저리와 잔류 과산화수소가 생물학적 처리에 미치는 영향, 대한환경공학회지 26(3), 334-339
11 Ravikumar J. X., Gurol M. D., 1994, Chemical oxidation of chlorinated organics by hydrogen peroxide in the presence of sand, Environ. Sci. Technol., 28, 394-400   DOI   ScienceOn
12 토양환경보전정책방향, 2004, 환경부
13 최진호, 김상대, 문제기, 공성호, 1999, 디젤과 등유로 오염된 토양의 철광석으로 촉매화된 과수를 이용한 처리에 관한 연구, J. of Korean Ind. & Eng. Chemistry, 10(1), 24-29
14 Watts R. J., Dilly S. E., 1996, Evaluation of iron catalysts for the fenton-like remediation of diesel-contaminated soils, J. Hazardous Materials. 51, 209-224   DOI   ScienceOn
15 Watts R. J., Haller D. R., Jones A. P., Teel A. L., 2000, A foundation for the risk-based treatment of gasoline-contaminated soils using modified fenton's reactions, J. Hazardous Materials. 76, 73-89   DOI   ScienceOn
16 최창석, 박진희, 김영식, 이태진, 2003, 과산화수소에 의한 디젤 오염 토양의 처리, 대한환경공학회, 431-435
17 지원현, 2001, Chemical oxidation treatment of diesel-contaminated soil by $Fe^0/H_2O_2$ system, 석사학위논문, 환경시스템협동과정, 고려대학교
18 최희철, 지재성, 유도윤, 1997, 탄화수소화합물로 오염된 지반환경복원기술 개발연구, 한국건설기술연구원
19 Chen C. T., Tafuri A. N., Rahman M., Forest M. B., 1998, Chemical oxidation treatment of petroleum contaminates soil using fenton's reagent, J. Environ. Sci. Health. A33(6), 987-1008
20 Millioli V. S., Freire D. D. C., Cammarota M. C., 2003, Petroleum oxidation using Fenton's reagent over beach sand following a spill, J. Hazardous Materials. 103, 79-91   DOI   ScienceOn
21 In situ chemical treatment, 1999, GWRTAC
22 토양오염공정시험방법 환경부, 2002, 환경부