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http://dx.doi.org/10.5322/JES.2007.16.10.1111

Bismuth Coated Carbon Fiber Microelectrode with Gallic Acid n-Propyl Ester for Trace Copper Analysis  

Ly, Suw-Young (Biosensor Research Institute, Seoul National University of Technology)
Lee, Chang-Hyun (Division of General Education, Pyeongtaek University)
Jung, Young-Sam (Department of Chemistry Korea University)
Publication Information
Journal of Environmental Science International / v.16, no.10, 2007 , pp. 1111-1118 More about this Journal
Abstract
A bismuth-coated carbon fiber microelectrode was prepared using cyclic voltammetry (CV). An analytical application was performed for the copper analysis with Square Wave Stripping Voltammetry (SWSV). Gallic acid n-propyl ester (PG) was used for the complex formation with a copper ion, and electrochemical measurements were performed with a pre-amplifier of a low-current module for nano am per detection. The effects of various parameters on the response were optimized. Analytical working ranges of $0.03-25.9\;{\mu}gl^{-1}$ and $0-25\ Cu(II) were obtained. The relative standard deviation at $13\;mgl^{-1}$ Cu was 0.9% (n = 12) in optimum conditions. The detection limit was found to have been $0.019\;{\mu}gl^{-1}$, with a 30-sec accumulation time. The developed methods were applied to a copper assay in water samples.
Keywords
Stripping voltammetry; Bismuth coating; Carbon fiber microelectrode; Gallic acid n-propyl ester;
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Times Cited By KSCI : 1  (Citation Analysis)
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