Browse > Article
http://dx.doi.org/10.5322/JES.2006.15.5.397

Compositional Characteristics and Origin of Polycyclic Aromatic Hydrocarbons[PAHs] of Crude Oils and Petroleum Products  

Chung, Hung-Ho (Gwangyangbay Zone Environmental Institute)
Park, Eun-Hee (Gwangyangbay Zone Environmental Institute)
Choi, Sang-Won (Department Chemical Engineering, College of Engineering, Chonnam National University)
Publication Information
Journal of Environmental Science International / v.15, no.5, 2006 , pp. 397-403 More about this Journal
Abstract
Compositional characteristics and origin of polycyclic aromatic hydrocarbons(PAHs), which should be strongly regulated for environmental protection in the crude oils and petroleum products, have been investigated by gas chromatography-mass spectrometry(GC/MS). In the crude oils analyzed, two-rings compound(naphthalene) of PAHs was detected around $72.3\sim93.5%$, but five- or six-rings compound of PAHs was not detected. In the crude oils analyzed, the molecular ratio indices of Phe/Ant(phenanthrene/anthracene)>15, Fla/Pyr(fluoranthene/pyrene)<1, BaA/Chr(benzo (a)anthracene/chrysene)$\leq0.4$ could be effectively applied, and we found that the origin of PAHs was petrogenic sources. Total PAHs concentrations in the crude oils were increased with increasing API gravity and with decreasing sulfur contents of the analyzed crude oils. Five- or six-rings compound of PAHs were not included in ail petroleum products except bunker-C. Furthermore, the molecular ratio indices of Phe/Ant(phenanthrene/anthracene) vs. Fla/Pyr(fluoranthene/pyrene) could be effectively applied as the standard for the PAHs contamination criterion at the other Korean areas.
Keywords
Polycyclic Aromatic Hydrocarbons(PAHs); Origin; Crude oils; Petroleum products; GC-MS;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Readman, J. W., G. Fillmann, I. Tolosa, J. Bartocci, J. P. Villeneuve, C. Catinni and L. D. Mee, 2002, Petroleum and PAR contamination of the Black Sea, Marine Pollution Bulletin, 44, 48-62   DOI   ScienceOn
2 Budzinski, H., I. Jones, J. Bellocq, C. Pierard and P. Garriguses, 1997, Evaluation of sediment contamination by polycyclic aromatic hydrocarbons in the Gironde estuary, Mar. Chem., 58, 85-97   DOI   ScienceOn
3 Ying, Wu, J. Zhang and Z. Zhijian, 2003, Polycyclic aromatic hydrocarbons in the sediments of the Yalujiang Estuary, North China, Marine Pollution Bulletin, 46(5), 619-625   DOI   ScienceOn
4 Maciaszamora, J. V., E. Mendozavega and J. A. Villaescusacelaya, 2002, PAHs composition of surface marine sediments: a comparison to potential local sources in Todos Santos Bay, B.C., Mexico, Chemosphere, 46(3), 459-468   DOI   ScienceOn
5 김태승, 신선경, 2001, 환경중의 다환방향족탄화 수소류의 배출 및 분석 현황, Analytical Science & Technology, 14(4), 47A-74A
6 이종섭, 이문옥, 박일흠, 이삼노, 1997, 광양만권 개발에 따른 해양환경의 변화, 대한토목학회, 학술발표회 논문집, 473-476
7 조규탁, 이동수, 신용승, 2000, 다환방향족탄화 수소(PAHs)의 국내 배출량추정-잔류성 유기오 염물질의 국제규제에 대응하여-, 대한환경공학회지 -기술자료, 22(10), 1921-1932
8 권개경, 정성영, 이정현, 현정호, 김상진, 2004, 다환방향족 탄화수소가 광양만 퇴적토의 미생물 군집구조에 미치는 영향, Korean J. Environ. Bio., 22(special issue), 38-49
9 Intenational Agency for Research on Cancer, 1991, IARC, monographs on the Evaluation of Carcinogenic Risks to Humans, 43-53
10 정홍호, 정호승, 김은영, 조환익, 황주찬, 최상원, 2004, 광양만 유역 퇴적토 중의 다환방향족탄화 수소류, 한국환경과학회지 , 13(6), 543-549
11 Gschwend, P. M. and R. A. Hites, 1981, Fluxes of the polycyclic aromatic compounds to marine and lacustrine sediments in the northeastern United States, Geochim. Cosmochim. Acta., 45, 2359-2367   DOI   ScienceOn
12 Colombo, J. C., E. Pelletier, C. Brochu, M. Khalil and J. A Catoggio, 1989, Determination of hydrocarbon sources using n-alkenes and poly aromatic hydrocarbon composition indexes. Case study: Rio de la Plate, Argentina, Environ. Sci. Technol., 23, 888-894   DOI
13 김성우, 김윤선, 전준민, 2001, 여천공단내 실내.외 미세분진증의 화학원소 농도 및 발생원 추정에 관한 연구, 대한환경공학회지, 23(2), 305-317
14 오경택, 박귀환, 이정일, 이중기, 김성준, Kubo Motoki, 정선용, 2002, 미생물을 이용한 원유 및 석유제품의 분해 특성, 한국생물공학회지, 17(3), 247-254
15 Benner, B. A., G. E. Gordon and S. A. Wise, 1989, Mobile sources of atmospheric polycyclic aromatic hydrocarbons- A roadway tunnel study, Environ. Sci. Technol., 23, 1269-1278   DOI
16 Wise, S. A., B. A. Benner, N. P. Bryner, S. N. Chesler, R. E. Rebbert and M. M. Schantz, 1988, Determination of polycyclic aromatic hydrocarbons in a coal tar standard reference material, Anal. Chem., 60, 887-894   DOI   ScienceOn
17 Sicre, M. A., J. C. Marty, A. Saliot, X. Aparicio, J. Grimalt and J. Albaiges, 1987, Aliphatic and aromatic hydrocarbons in different sized aerosols over the Mediterranean Sea: Occurrence and origin, Atmos. Environ., 21, 2247-2259   DOI
18 Benner, B. A., N. P. Bryner, S. A. Wise, G. H. Mulholland, R. C. Lao and M. F. Fingas, 1990, Polycyclic aromatic hydrocarbons emissions from combustion of crude oil on water, Environ. Sci. Technol., 24, 1418-1427   DOI