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http://dx.doi.org/10.5322/JES.2003.12.9.1005

Surface Modification and Anchoring Titanium Dioxide on Mesoporous Activated Carbons  

주창식 (부경대학교 응용화학공학부)
박흥재 (인제대학교 환경시스템학부)
정갑섭 (동명대학 화공정보과)
Publication Information
Journal of Environmental Science International / v.12, no.9, 2003 , pp. 1005-1010 More about this Journal
Abstract
For the purpose of surveying any possibility of anchoring titanium dioxide on activated carbons to promote their activities as catalysts and/or adsorbents, two activated carbons were oxidized with ammonium peroxydisulfate and followed by anchoring titanium dioxide. The anchoring of titanium dioxide on the oxidized activated carbons were performed via the adsorption of tetrabutyltitanate, hydrolysis with deionized water, and calcination. The effect of oxidizing and anchoring treatment on the surface element composition, surface area, and pore texture were analyzed by XPS, BET and TPD. The oxidation of activated carbons with ammonium peroxydisulfate introduced carboxyl groups on the surface of activated carbons and these carboxyl groups promoted the anchoring of titanium oxide on the activated carbons. However, the treatments affected the surface area and the porosity of activated carbons.
Keywords
Activated carbon; Surface modification; Anchoring titanium dioxide; Mesoporous;
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