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http://dx.doi.org/10.5322/JES.2003.12.1.087

Simultaneous Determination of Polycyclic Aromatic Hydrocarbons by Synchronous Spectrofluorimetry  

이상학 (경북대학교 자연과학대학 화학과)
손범목 (경북대학교 자연과학대학 화학과)
Publication Information
Journal of Environmental Science International / v.12, no.1, 2003 , pp. 87-92 More about this Journal
Abstract
Synchronous spectrofluorimetry was carried out for the simultaneous determination of various polycyclic aromatic hydrocarbons(PAHs) in aqueous solution by fluorescence spectrometry have been studied. The optimal wavelength interval(${\triangle}{\lambda}$) for synchronous spectra of acenaphthene, anthracene, benzo[a]anthracene, fluorene and pyrene were investigated in the presence of surfactants. The great enhancement of the fluorescence of these PAHs in Triton X-100 was obtained and optimal wavelength was 50 nm. The calibration curves in synthetic mixture solution of 5 PAHs were linear over the range from $1.0{\times}10^{-8}M$ to $1.0{\tiems}10^{-4}M$. Under the optimal experimental conditions, the detection limits were $4.9{\tiems}10^{-9}M$,\;7.0{\times}10^{-9}M,\;4.7{\tiems}10^{-9}M,\;1.6{\tiems}10^{-9}M$ and $3.2{\tiems}10^{-9}M$ for acenaphthene, anthracene, benzo[a]anthracene, fluorene and pyrene, respectively.
Keywords
Polycyclic aromatic hydrocarbons; Synchronous spectrofluorimetry; Surfactant;
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1 Latz, H. W, A H. Ullmar, and J. D. Winefordener, 1978, Limitation of synchronous luminescence spectrometry in multicomponent analysis, Anal. Chem., 50 656-657.   DOI
2 Inman, E. L. Jr. and J. D. Winefordner, 1982, Constant energy synchronous fluorescence for analysis of polynuclear aromatic hydrocarbon mixture, Anal. Chem., 54, 2018-2022.   DOI   ScienceOn
3 Dickhut, R. M. and K. E. Gustafson, 1995, Atmospheric washout of polycyclic aromatic hydrocarbons in the southern chesapeake bay region, Environ. Sci. Technol, 29, 1518-1525.   DOI   ScienceOn
4 Later, D. W. and M. L. Lee, 1982, Selective detection of amino acid polycyclic aromatic compounds in solvent refined coal, Anal. Chem., 54, 117-123.   DOI   ScienceOn
5 Pinto, C. G., J. L. P. Pavon, and B. M. Cordero, 1994, Cloud point preconcentration and high-performance liquid chromatographic determination of polycyclic aromatic hydrocarbons with fluorescence detection, Anal. Chem, 66, 874-881.   DOI   ScienceOn
6 Schwarz, F. P. and S. P. Wasik, 1976, Fluorescence measurements of benzene, naphthalene, anthracene, pyrene, fluoranthene and benzene [eJpyrene in water, Anal. Chem., 48, 534-528.   DOI
7 Mcgroddy, S. E. and J. W. Farrington, 1995, Sediment porewater partitioning, of polycyclic aromatic hydrocarbons in three cores from boston harbor, massachusetts, Environ. Sci. TechnoL, 29, 1542-1550.   DOI   ScienceOn
8 Chou, J. X. Qu, T. Lu, S. Dong, and Y. Wu, 1995, The effect of solution pH on synchronous fluorescence spectra of cytochrome c solution, Microchemical Journal, 52, 159-165.   DOI   ScienceOn
9 Rubio, S., A. G. Hens, and M. Valcarcel, 1985, Analysis of binary and ternary mixtures of titanium, zirconium and hafnium by derivative synchronous fluorescence spectrometry, Anal. Chem., 57, 1101-1106.   DOI   ScienceOn
10 Rodriques, M. A, R C. Tena, and F. J G Montelongo, 1999, determination of polycyclic aromatic hydrocarbons in limpet samples, Chromatographia, 50, 235-238.   DOI
11 Cirovic, D. A., R. G. Brereton, P. T. Walsh, J. A Ellwood, and E. Scobbie, 1996, Application of partial least squares calibration to measurements of polycyclic aromatic hydrocarbons in coal tar pitch volatiles, Analyst, 121, 575-580.   DOI   ScienceOn
12 Khakhel', O. A and V. E. Krykunova, 1999, Determination of dimer concentration of chromophores by the method of fluorescence synchronous scanning, Journal of Luminescence, 81, 79-84.   DOI   ScienceOn
13 Murayama, M. and P. K. Dasgupta, 1996, Liquid chromatographic determination of nitro-substituted polynuclear aromatic hydrocarbons by sequential electrochemical and fluorescence detection, Anal. Chem, 68, 1226-1232.   DOI   ScienceOn
14 Rodriguez, J. J. S., J. H. Garcia, M. M. B. Surarez, and A B. M. Lazaro, 1993, Analysis of mixtures of polycyclic aromatic hydrocarbons in seawater by synchronous fluorescence spectrometery In organized media, Analyst, l18, 917-921.   DOI   ScienceOn
15 Dadachs, J., J. M. Bayona, C. Raoux, and J. Albaiges, 1997, Spatial, vertical distribution and budget of polycyclic aromatic hydrocarbons in western mediterranean seawater, Environ. Sci. Technol., 31, 682-688.   DOI   ScienceOn
16 Ayala, J. H., A. M. Afonso, and V. G. Diaz, 1998, Selective analysis of fluorene by quenched fluorescence in cetylpyridinium bromide micelles, Microchemical Journal, 60, 101-109.   DOI   ScienceOn
17 Patil, S. R. and S. B. Patwari, 1999, Red shift in fluorescence of naphthalene doped by anthracene and perylene, Journal of Luminescence, 82, 115-119.   DOI   ScienceOn
18 Green, G. L. and T. C. O'Haver, 1974, Derivative luminescence spectrometry, Anal. Chem., 46, 2191-2196.   DOI
19 Wise, S. A., M. M. Schantz, B. A. Benner, Jr., M. J. Hay, and S. B. Schiller, 1995, Certification of polycyclic aromatic hydrocarbons in a marine sediment standard reference material, Anal. Chem., 67, 1171-1178.   DOI
20 May, W. E. and S. P. Wasik, 1978, Determination of the aqueous solubility of polynuclear aromatic hydrocarbons by a coupled column liquid chromatographic technique, Anal. Chem, 50, 175-179.   DOI   ScienceOn
21 Kiss, G., Z. V. Puchony, A. Gelencser, Z. Krivacsy, A. Molnar, and J Hlavay, 1998, Survey of concentration of polycyclic aromatic hydrocarbons in lake Balaton by HPLC with fluorescence detection, Chromatographia, 48, 149-153.   DOI   ScienceOn