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http://dx.doi.org/10.5229/JKES.2019.22.1.43

A Review on Electrochemical Model for Predicting the Performance of Lithium Secondary Battery  

Yang, Seungwon (College of Transdisciplinary Studies, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Kim, Nayeon (College of Transdisciplinary Studies, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Kim, Eunsae (College of Transdisciplinary Studies, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Lim, Minhong (College of Transdisciplinary Studies, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Park, Joonam (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Song, Jihun (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Park, Sunho (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Appiah, Williams Agyei (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Ryou, Myung-Hyun (Department of Chemical and Biological Engineering, Hanbat National University)
Lee, Yong Min (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
Publication Information
Journal of the Korean Electrochemical Society / v.22, no.1, 2019 , pp. 43-52 More about this Journal
Abstract
As the application area of lithium secondary batteries becomes wider, performance characterization becomes difficult as well as diverse. To address this issue, battery manufacturers have to evaluate many batteries for a longer period, recruit many researchers and continuously introduce expensive equipment. Simulation techniques based on battery modeling are being introduced to solve such difficulties. Various lithium secondary battery modeling techniques have been reported so far and optimal techniques have been selected and utilized according to their purpose. In this review, the electrochemical modeling based on the Newman model is described in detail. Particularly, we will explain the physical meaning of each equation included in the model; the Butler-Volmer equation, which represents the rate of electrode reaction, the material and charge balance equations for each phase (solid and liquid), and the energy balance. Moreover, simple modeling processes and results based on COMSOL Multiphysics 5.3a will be provided and discussed.
Keywords
Electrochemical Modeling and Simulation; Butler-Volmer Equation; Material and Charge Balance; COMSOL; Lithium Secondary Battery;
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