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http://dx.doi.org/10.5229/JKES.2019.22.1.13

Prussian Blue Analogues for Rechargeable Batteries  

Kim, Yang Moon (School of Chemical and Biological Engineering, Seoul National University)
Choi, Seungyeon (School of Chemical and Biological Engineering, Seoul National University)
Choi, Jang Wook (School of Chemical and Biological Engineering, Seoul National University)
Publication Information
Journal of the Korean Electrochemical Society / v.22, no.1, 2019 , pp. 13-21 More about this Journal
Abstract
Prussian blue analogues(PBAs) are comprised of cyano-bridged transition metal ions. The wide and unique open-framework structures of the PBAs enable reversible intercalation and deintercalation of various ions such as $Na^+$, $K^+$, $Mg^{2+}$, $Zn^{2+}$, etc. In addition, since PBAs are synthesized through coprecipitation reaction in aqueous solution at room temperature, they are produced economically and environmentally friendly. However, the formation of crystals proceeds rapidly, and defects such as vacancy and crystal water tend to be present in the crystals, thereby affecting key battery performance. Therefore, significant efforts to inhibit defects in PBAs have been made. In the case of vacancy, the reaction rate was controlled at the synthesis stage to reduce the formation of vacancy, and the crystal water was removed by heat treatment under vacuum. In addition, by adding transition metals that do not react within the structure of PBA, the structural instability during the electrochemical reaction was largely alleviated.
Keywords
Prussian Blue Analogue; Vacancy; Interstitial Water; Coordinated Water; Structural Stability;
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