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http://dx.doi.org/10.5229/JKES.2015.18.1.1

Synthesis and Ionic Conductivity of Polystyrene Derivative Containing Cyclic Carbonate  

Kim, Doo-Hwan (Department of Engineering Chemistry, Chungbuk National University)
Ryu, Sang-Woog (Department of Engineering Chemistry, Chungbuk National University)
Publication Information
Journal of the Korean Electrochemical Society / v.18, no.1, 2015 , pp. 1-6 More about this Journal
Abstract
In this study polystyrene derivative, VBCE, having a cyclic carbonate was synthesized by Williamson reaction and polymerized to poly(VBCE) successfully in an usual polymerization conditions. The obtained polymer was blended with PEGMA and the effect of composition on the ionic conductivity was investigated. Interestingly, the ionic conductivity was decreased from $4.2{\times}10^{-5}S\;cm^{-1}$ to $3.93{\times}10^{-6}S\;cm^{-1}$ with the poly(VBCE) contents of 5.8mol%. From the DSC study, it was found that the $T_g$ of the blend was increased from $-50^{\circ}C$ to $-21^{\circ}C$ by the addition of poly(VBCE). Therefore, it is believed that the presence of a polar cyclic carbonate makes polymer matrix harder and it is necessary to design new structures less hindered the mobility of the matrix.
Keywords
Polymer electrolyte; Cyclic carbonate; Blend; Ionic conductivity; Thermal transition;
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1 G.-A. Nazri and G. Pistoia, 'Lithium Batteries Science and Technology' 574, Kluwer Academic Publishers, New York (2004).
2 M. Yosho, R. Brodd, and A. Kozawa, 'Lithium-ion Batteries' 413, Springer, New York (2009).
3 J. MacCallum and C. Vincent, 'Polymer Electrolyte Reviews-1' 69, Elsevier Applied Science, New York (1987).
4 S. Zhang, L. Yang, and Q. Liu, 'Single-ion conductivity and carrier generation of polyelectrolytes' Solid State Ionics, 76, 121 (1995).   DOI
5 F. Dias, L. Plomp, and J. Veldhuis, 'Trends in polymer electrolytes for secondary lithium batteries' J. Power Sources, 88, 169 (2000).   DOI
6 A. Nishimoto, M. Watanabe, Y. Ikeda, and S. Kohjiya, 'High ionic conductivity of new polymer electrolytes based on high molecular weight polyether comb polymers' Electrochimica Acta, 43, 1177 (1998).   DOI
7 Y. Ikeda, Y. Wada, Y. Matoba, S. Murakami, and S. Kohjiya, 'Characterization of comb-shaped high molecular weight poly(oxyethylene) with tri(oxyethylene) side chains for a polymer solid electrolyte' Electrochimica Acta, 45, 1167 (2000).   DOI
8 P. Jannasch, 'Ion conducting electrolytes based on aggregating comblike poly(propylene oxide)' Polymer, 42, 8629 (2001).   DOI
9 H. Katz, "Preparation of soluble poly(carbonyldioxyglyceryl methacrylate)" Macromolecules, 20, 2026 (1987).   DOI
10 N. Kihara, T. Endo, "Synthesis and reaction of polymethacrylate bearing cyclic carbonate moieties in the side chain" Makromol. Chem., 193, 1481 (1992).   DOI
11 T. Miyata, K. Matsumoto, T. Endo, S. Yonemori, S. Watanabe, "Synthesis and radical polymerization of styrene-based monomer having a five-membered cyclic carbonate structure" J. Polym. Sci. A: Polym. Chem., 50, 3046 (2012).   DOI
12 T. Nishikubo, A. Kameyama, M. Sasano, "Synthesis of functional polymers bearing cyclic carbonate groups from (2-oxo-1,3 -dioxolan-4-yl)methyl vinyl ether" J. Polym. Sci. A: Polym. Chem., 32, 301 (1994).   DOI
13 X. Haung, X. Ma, J. Gao, B. Tan, K. Yang, G. Wang, Z. Deng, "Preparation, characterization, conductivity studies of novel solid polymer electrolytes based on blend of poly (AN-co-VEC) and EVA" Solid State Ionics, 215, 7 (2012).   DOI
14 S. Kim, Y. Kim, H. Lee, D. Yoon, B. Song, "Lipasecatalyzed synthesis of glycerol carbonate from renewable glycerol and dimethyl carbonate through transes terification" J. of Molecular Catalysis B: Enzymatic, 49, 75 (2007).   DOI
15 S. Benyahya, M. Desroches, "Synthesis of glycerin carbonate-based intermediates using thiol-ene chemistry and isocyanate free polyhydroxyurethanes thereform" Polymer Chemistry, 2, 2661 (2011).   DOI
16 C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, 2nd ed, Wiley-VCH, Weinheim (1988).
17 J. Li, C. Daniel and D. Wood, "Materials processing for lithium-ion batteries" J. of Power Sources, 196, 2452 (2011).   DOI   ScienceOn
18 J. Goodenough and Y. Kim, "Challenges for rechargeable Li batteries" Chem. Mater., 22, 587 (2010).   DOI   ScienceOn
19 G. Rokicki, "Aliphatic cyclic carbonates and spiroorthocarbonates as monomers" Prog. Polym. Sci., 25, 259 (2000).   DOI