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http://dx.doi.org/10.5229/JKES.2012.15.3.154

Improved Cycling Ability of Si-SiO2-graphite Composite Battery Anode by Interfacial Stabilization  

Min, Jeong-Hye (Graduate School of Green Energy Technology, Chungnam National University)
Bae, Young-San (Dept. of Fine Chemical Engineering & Applied Chemistry, Chungnam National University)
Kim, Sung-Su (Graduate School of Green Energy Technology, Chungnam National University)
Song, Seung-Wan (Graduate School of Green Energy Technology, Chungnam National University)
Publication Information
Journal of the Korean Electrochemical Society / v.15, no.3, 2012 , pp. 154-159 More about this Journal
Abstract
Structural volume change occurring on the Si-based anode battery materials during alloying/dealloying with lithium is noticed to be a major drawback responsible for a limited cycle life. Silicon monoxide has been reported to show relatively improved cycling performance compared to Si-containing materials for rechargeable lithium batteries, due to the structural buffering role of in-situ formed $Li_2O$ and lithium silicate during the reaction of silicon monoxide and lithium. Here we report improved cycling ability of interfacially stabilized Si-$SiO_2$-graphite composite anode using silane-based electrolyte additive for rechargeable lithium batteries, which includes low cost silicon dioxide for structural stabilization and graphite for enhanced conductivity.
Keywords
Si-$SiO_2$-graphite composite anode; Rechargeable lithium batteries; Interfacial stabilization;
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Times Cited By KSCI : 1  (Citation Analysis)
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