Browse > Article
http://dx.doi.org/10.5229/JKES.2010.13.2.138

Characteristics and Preparation of Manganese Oxide Electrode by Using Pulse Voltammetry Electrodeposition for Electrolysis  

Yang, Jeong-Jin (Dept. of Industrial Engineering Chemistry, Chungbuk National University)
Lee, Mi-Young (Dept. of Industrial Engineering Chemistry, Chungbuk National University)
Kim, Jeong-Sik (Techwin Co. Ltd.)
Shin, Hyun-Soo (Techwin Co. Ltd.)
Park, Soo-Gil (Dept. of Industrial Engineering Chemistry, Chungbuk National University)
Publication Information
Journal of the Korean Electrochemical Society / v.13, no.2, 2010 , pp. 138-144 More about this Journal
Abstract
In order to investigate the electrochemical propertied of titanium electrode for electrolysis, manganese oxide was electrodeposited on surface of mesh titanium by pulse voltammetry. The morphological changes and impedance results of manganese oxide electrodeposited electrode were analyzed by SEM and EDX. The size of electrodeposited manganese oxide on mesh titanium was increased with first cycle pulse time increase, and approximately 100 non-uniform manganese oxide was grown at 10 ms pulse polarization time. Charge transfer resistance($R_{ct}$) of near the overpotential was analyzed by EIS measurement and the feasibility of prepared electrode was evaluated by the overpotential calculated from Tafel plots.
Keywords
Pulse electrodeposition; Manganese oxide; Differential Pulse Voltammetry; Tafell Pot; Electrochemical Impedance Spectroscope;
Citations & Related Records
연도 인용수 순위
  • Reference
1 D. Landolt and A. Marlot, ‘Microstructure and composition of pulse-plated metals and alloys’ Surf. Coat. Technol. 169-170, 8 (2003).   DOI
2 H. Adelkhani, M. Ghaemi, and S. M. Jafari, ‘Cycle life improvement of alkaline batteries via optimization of pulse current deposition of manganese dioxide under low bath temperatures’ J. Power Source, 163, 1091 (2007).   DOI   ScienceOn
3 A. F. Zimmerman, D. G. Clark, K. T. Aust, and U. Erb, ‘Pulse electrodeposition of Ni-SiC nanocomposite’ Mater. Lett. 52, 85 (2002).   DOI
4 S. Jouanneau, S. Sarciaux, A. Le Gal La Salle, and D. Guyomard, ‘Influence of structural defects on the insertion behavior of -$MnO_2$: comparison of $H^+$ and $Li^+$’ Solid State Ionics, 140, 223 (2001).   DOI
5 J. F. E. Gootzen, P. G. J. M. Peeters, J. M. B. Dukers, L. Lefferts, W. Visscher, and J. A. R. van veen, ‘The Electrocatalytic Reduction of Nitrate on Pt, Pd, and Pt+Pd Electrode Activated with Ge’ J. Electroanal. Chem., 434, 171 (1997).   DOI
6 A. C. A. de Vooys, R. A. van Santen, and J. A. R. van Veen, ‘Electrocatalytic Reduction of Nitrate on Palladium/Copper Electrodes’ J Molecular Catalysis A; Chemical, 154, 203 (2002).   DOI
7 K.W. Kim, S. M. Kim, and E. H. Lee, ‘Characteristics of Ti Platinization for Fabrication Sn-modified Platinized Ti Electrode’ Koran Chem. Eng. Res., 45, 124 (2007).
8 R. Clift, J. R. Grace, and M. E. Weber, ‘Bubbles, Drops, and Particles’ Academic Press, New York, (1978).
9 O. R. Camara and S. Trasatti, ‘Surface electrochemical properties of Ti/($RuO_2+ZrO_2$) electrodes’ Electrochimica Acta, 41, 419 (1996).   DOI
10 Hadi Adelkhani and Mehdi Ghaemi, ‘Nano-structural tailoring of manganese dioxide by using pulse current electrodeposition’ Solid Static Ionics, 179, 2278 (2008).   DOI
11 J. Winkler, Jr., ‘Electrodeposition of metal alloys’ U.S. Patent, 1,951, 893 (1934).
12 M. E. Bahrololoom and R. Sani, ‘The influence of pulse plating parameters on the hardness and wear resistance of nickel-alumina composite coatings’ Surf. Coat. Technol. 192, 154 (2005).   DOI   ScienceOn
13 N. Ibl, J. Cl. Puippe, and H. Angerer, ‘Electrocrystallization in pulse electrolysis’ Surface Technology, 6, 287 (1978).   DOI
14 J. Cl. Puippe, N. Ibl, and J. Appl. ‘Some theoretical aspects of pulse electrolysis’ Surface Technology, 10, 81 (1980).   DOI
15 E. Lamy-Pitara and J. Barbier, ‘Platinum Modified by Electrochemical Deposition of Adatoms’ Applied Catalysis A: General, 149, 49 (1997).   DOI
16 Kerkeni, S. Lamy-Pitara, and E. J. Barbier, ‘Copper-Platinum Catalysts Prepared and Characterized by Electrochemical Methods for the Reduction of Nitrate and Nitrite’ Chemical Today, 75, 35 (2002).   DOI