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http://dx.doi.org/10.5229/JKES.2008.11.2.095

Preparation and Electrochemical Characterization of ZrO2/Ti Electrode by ESD Coating Method  

Kim, Han-Joo (Energy Storage of Research Center, Chungbuk Nat'l. Univ.)
Hong, Kyeong-Mi (R&D Center, PureEChem. Co. Ltd.)
Sung, Bo-Kyung (R&D Center, MaDenTech. Co.)
Park, Soo-Gil (Energy Storage of Research Center, Chungbuk Nat'l. Univ.)
Publication Information
Journal of the Korean Electrochemical Society / v.11, no.2, 2008 , pp. 95-99 More about this Journal
Abstract
This study has made the electrode that is coated zirconium oxide on the titanium by ESD(Electrostatic spray deposition) coating methode. It has investigated the effects of the etching method of a Ti substrate as the preparation, making of zirconium oxide film and electrochemical characteristics of the electrode that is etched on the titanium. The HCl etching develops a fine and homogeneous roughness on the Ti substrate. Fabrication and material properties of the metal oxide electrode, which is known to be so effective to generate ozone and hypochlorous acid (HOCl) as power oxidant, were studied. A proper metal oxide material is focus zirconium oxide through reference. A coating method to enhance the fabrication reproducibility of the zirconium oxide electrode was used ESD coating method by zirconium oxychloride. Zirconium oxide films on the Ti substrate were tested using SEM, XRD, Cyclic voltammetry.
Keywords
Zirconium oxide; HCl etching method; ESD (Electrostatic spray deposition) coating methode;
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