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http://dx.doi.org/10.5229/JKES.2007.10.2.116

Synthesis and Characterisation of Mixed Conducting Perovskite Type Oxide and Its Electrochemical Application to Electrode Material for Solid Oxide Fuel Cell  

Kim, Yu-Mi (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Pyun, Su-Il (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Lee, Gyoung-Ja (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Kim, Ju-Sik (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Publication Information
Journal of the Korean Electrochemical Society / v.10, no.2, 2007 , pp. 116-125 More about this Journal
Abstract
This article is concerned with synthesis, characterisation and electrochemical application of the mixed conducting perovskite type oxide to electrode materials for solid oxide fuel cell. First, this review provides a comprehensive survey of the various synthetic methods such as solid state reaction, Pechini, glycine nitrate process and sol-gel methods for the preparation of perovskite type oxide powders. Subsequently, the electrical and microstructural properties of the mixed conducting oxides were discussed in detail. Finally, as electrochemical applications of the mixed conducting perovskite type oxides to electrode materials for solid oxide fuel cell, fundamentals of theoretical ac-impedance model for porous mixed conducting electrodes were introduced. Furthermore, the ac-impedance behaviour of porous and dense mixed conducting electrodes prepared by various synthetic methods was discussed.
Keywords
Mixed conducting oxide; Perovskite structure; Solid oxide fuel cell; Ac-impedance spectra; Oxygen reduction reaction;
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