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http://dx.doi.org/10.5229/JKES.2006.9.4.158

An Overview of Chemically/Surface Modified Cubic Spinel LiMn2O4 Electrode for Rechargeable Lithium Batteries  

Jung, Kyu-Nam (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Pyun, Su-Il (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
Publication Information
Journal of the Korean Electrochemical Society / v.9, no.4, 2006 , pp. 158-169 More about this Journal
Abstract
The present article is concerned with the overview of the chemically/surface modified cubic spinel $LiMn_2O_4$ as a cathode electrode far lithium ion secondary batteries. Firstly, this article presented a comprehensive survey of the cubic spinel structure and its correlated electrochemical behaviour of $LiMn_2O_4$. Subsequently, the various kinds of the chemically/surface modified $LiMn_2O_4$ and their electrochemical characteristics were discussed in detail. Finally, this article reviewed our recent research works published on the mechanism of lithium transport through the chemically/surface modified $Li_{1-\delta}Mn_2O_4$ electrode from the kinetic view point by the analyses of the experimental potentiostatic current transients and ac-impedance spectra.
Keywords
$LiMn_2O_4$ Electrode; Cubic Spinel Structure; Chemically/Surface Modified Electrode; Cell-impedance-controlled Lithium Transport; Lithium Batteries;
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