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http://dx.doi.org/10.5229/JKES.2006.9.4.137

Enhanced Behaviors of Ionic-Polymer Metal Composite (IPMC) Actuator Coupled with Polymeric Anion-doped Polypyrrole Thin Film  

Hong, Chan (Department of Chemical Engineering, Inha University)
Nam, Jae-Do (Department of Polymer Science and Engineering, Sungkyunkwan University)
Tak, Yong-Sug (Department of Chemical Engineering, Inha University)
Publication Information
Journal of the Korean Electrochemical Society / v.9, no.4, 2006 , pp. 137-140 More about this Journal
Abstract
In order to overcome the weak actuation and relaxation problems during the deformation of IPMC actuator, polymeric anion (polystyrenesulfonate)-doped polypyrrole(Ppy(PSS)) was electrodeposited onto IPMC actuator. Electrochemical quartz crystal microbalance study showed that hydrated cations were instilled into Ppy(PSS) film and polymeric-anion dopants introduced during polymerization were not expelled. Ppy(PSS)-coated IPMC actuator formed two electrode/electrolyte interfaces, Pt/nafion and Ppy(PSS)/bulk solution, and additive volume expansion phenomena at interfaces induced the large deformation compensating the relaxation of actuation by back diffusion of water.
Keywords
Ionic polymer metal composite; Actuator; Conducting polymer; Polypyrrole; Dopant;
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